• Thumbnail for (2.2)Paracyclophane
    [2.2]Paracyclophane is a cyclophane that is applied in bio- and materials science. It was first synthesized by Brown and Farthing in 1949 by pyrolyzing...
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  • Cyclophane (redirect from Paracyclophane)
    '[6]paracyclophane' shows that the aromatic bridgehead carbon atom makes an angle of 20.5° with the plane. The benzyl carbons deviate by another 20.2°....
    17 KB (1,857 words) - 20:24, 10 June 2024
  • Thumbnail for Parylene
    Carbide. He deposited parylene films by the thermal decomposition of [2.2]paracyclophane at temperatures exceeding 550 °C and in vacuum below 1 Torr. This...
    39 KB (4,773 words) - 00:29, 19 March 2024
  • unless the substitution pattern is regarded in the name like in [2.2]paracyclophane. In the current systematic nomenclature, o-, m- and p- are often replaced...
    21 KB (2,421 words) - 20:00, 4 June 2024
  • Thumbnail for Propargyl bromide
    (1990). "Diels-Alder Reaction of 1,2,4,5-Hexatetraene: Tetramethyl[2.2]paracyclophane-4,5,12,13-tetracarboxylate". Organic Syntheses. 60: 41{{cite journal}}:...
    4 KB (378 words) - 08:55, 29 January 2023
  • Die diastereomeren 12,15-Bis(dimethylamino) - [2](2,5) - p -benzochinono[2]paracyclophane". Angewandte Chemie. 90 (5): 385–386. Bibcode:1978AngCh...
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  • Thumbnail for Phanephos
    Phanephos can be prepared in two steps from [2.2]paracyclophane. In the first step, [2.2]paracyclophane is dibrominated to give a pseudo-para dibromide...
    3 KB (209 words) - 18:19, 25 June 2024
  • Thumbnail for 4-Methylbenzyltrimethylammonium hydroxide
    form [2.2]Paracyclophane. Paracycloheterophanes can be obtained by heating it with other quaternary ammonium hydroxides (e.g. with (5-methyl-2...
    2 KB (132 words) - 22:42, 24 November 2023
  • Thumbnail for Ladderane
    each other, only allowing [2 + 2] cycloadditions to occur. A common spacer used in these reactions is the [2.2]paracyclophane system. This is sufficiently...
    16 KB (1,892 words) - 04:14, 26 February 2024
  • Thumbnail for Xylylene
    molecule that has a triplet ground-state. H. E. Winberg, F. S. Fawcett "[2.2]Paracyclophane" Organic Syntheses, Coll. Vol. 5, p.883 (1973); Vol. 42, p.83 (1962)...
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  • Thumbnail for Diphosphine ligands
    vol.2.; Pergamon Press: Oxford, UK, 1987; p. 993. ISBN 0-08-035945-0 Gareth J. Rowlands "Planar Chiral Phosphines Derived from [2.2]Paracyclophane" Israel...
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  • Thumbnail for Seyferth–Gilbert homologation
    Hinrichs; Henning Hopf (2004). "Cyclophanes. Part LII:1 Ethynyl[2.2]paracyclophanes – New Building Blocks for Molecular Scaffolding". Synthesis. 2004...
    6 KB (529 words) - 03:16, 22 March 2024
  • Thumbnail for N-Formylpiperidine
    Hinrichs; Henning Hopf (2004). "Cyclophanes. Part LII:1 Ethynyl[2.2]paracyclophanes – New Building Blocks for Molecular Scaffolding". Synthesis. 2004...
    3 KB (157 words) - 20:03, 27 December 2022
  • Thumbnail for Cycloparaphenylene
    Aromaticity: Molecular and Electronic Structures of [0n]Paracyclophanes" (PDF). Molecular Modeling Annual. 6 (2): 226–233. doi:10.1007/s0089400060226. ISSN 0949-183X...
    24 KB (2,667 words) - 21:06, 26 February 2024
  • Thumbnail for Poly(p-phenylene vinylene)
    catalyst. A modification of the ROMP route to PPV used a silyl-substituted paracyclophane derivative. Transformation into PPV could be achieved by elimination...
    10 KB (1,115 words) - 22:53, 31 July 2024
  • subsequently dimerized to yield [2,2]paracyclophane 58. Scheme 11. Pericyclic sequence for the synthesis of [2,2]paracyclophanes Transition-metal-catalyzed cascade...
    26 KB (2,826 words) - 18:23, 28 May 2024
  • serving as the adviser on his dissertation on "Syntheses and reactions of 2-(ketoalkyl)-3-hydroxy-1,4-naphthoquinones" From 1942 to 1945, Cram worked...
    16 KB (1,320 words) - 23:32, 28 May 2024
  • di- or poly-substituted metallocenes, and certain monosubstituted paracyclophanes. Nature rarely provides planar chiral molecules, cavicularin being...
    9 KB (1,062 words) - 05:36, 27 December 2023
  • Thumbnail for Inherent chirality
    within a given molecules across which the molecule is dissymmetric. Paracyclophanes often contain chiral planes if the bridge across the phenylene unit...
    8 KB (964 words) - 09:21, 16 December 2023
  • Computational Chemistry. 19 (2). John Wiley & Sons, Inc.: vi–ix. doi:10.1002/(SICI)1096-987X(19980130)19:2<VII::AID-JCC2>3.0.CO;2-G. S2CID 97243792. Johnson...
    9 KB (894 words) - 23:36, 15 April 2024
  • Thumbnail for John A. Gladysz
    Kusefoglu, S. H.; Gladysz, J. A. (1977). "A convenient synthesis of [3.3]paracyclophane". The Journal of Organic Chemistry. 42 (16): 2787–2788. doi:10.1021/jo00436a033...
    30 KB (3,004 words) - 03:35, 22 July 2023