Benzyl chloroformate, also known as benzyl chlorocarbonate or Z-chloride, is the benzyl ester of chloroformic acid. It can be also described as the chloride...
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methyl chloroformate, which is commercially available. Chloroformates are used as reagents in organic chemistry. For example, benzyl chloroformate is used...
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Chloroformic acid (category Chloroformates)
Important chloroformate esters include 4-nitrophenyl chloroformate, fluorenylmethyloxycarbonylchloride, benzyl chloroformate and ethyl chloroformate. Chloroacetic...
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IUPAC nomenclature, the prefix benzyl refers to a C6H5CH2 substituent, for example benzyl chloride or benzyl benzoate. Benzyl is not to be confused with phenyl...
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Leonidas Zervas in the early 1930s and usually added via reaction with benzyl chloroformate. It is removed under harsh conditions using HBr in acetic acid, or...
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ester of carbamic acid (O=C(OH)(NH2)) and benzyl alcohol, although it is produced from benzyl chloroformate with ammonia. It is a white solid that is...
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hydrogen chloride side-product. Phosgene is used to produce chloroformates such as benzyl chloroformate: R−OH + COCl2 → R−O−C(=O)−Cl + HCl In these syntheses...
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common amine protecting groups, such as BOC, FMOC, benzyl chloroformate and trichloroethyl chloroformate are carbamates. Urethane (ethyl carbamate) was once...
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reagent in the installation of the carboxybenzyl (Cbz) group using benzyl chloroformate in EtOAc for the N-protection of amines and amides. Doping MgO (about...
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1021/jo702006z. ISSN 0022-3263. PMC 2652699. PMID 18171075. Reagents: benzyl chloroformate protects amine as Cbz group, Achmatowitz reaction with m-CPBA, complexation...
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Chloromethyl chloroformate Dibenzoxazepine (CR) Ethyl iodoacetate Ortho-chlorobenzylidene malononitrile (Super tear gas; CS) Trichloromethyl chloroformate Xylyl...
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g/mol, exact mass: 170.0135 u) may refer to: Anisoyl chloride Benzyl chloroformate, or benzyl chlorocarbonate This set index page lists chemical structure...
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as an inorganic compound) Chloroformic acid forms chloroformate esters, e.g. methyl chloroformate (Cl−C(=O)−O−CH3) (if one classifies chloroformic acid...
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Benzimidazole, 4,5-dichloro-2-(trifluoromethyl)- Benzotrichloride Benzyl chloride Benzyl cyanide Bicyclo(2.2.1)heptane-2-carbonitrile Bis(chloromethyl) ketone...
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Pyridine (1) is reduced with sodium borohydride in presence of benzyl chloroformate to the Cbz protected dihydropyridine 2. The asymmetric Diels-Alder...
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chloride UN 1737 6.1 Benzyl bromide UN 1738 6.1 Benzyl chloride or Benzyl chloride unstabilized UN 1739 8 Benzyl chloroformate UN 1740 8 Hydrogen difluorides...
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carboxybenzyl group discovered by Zervas is introduced by reaction with benzyl chloroformate, originally in aqueous sodium carbonate solution at 0 °C: The protecting...
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acid 1878-68-8 C8H7ClO benzeneacetyl chloride 103-80-0 C8H7ClO2 benzyl chloroformate 501-53-1 C8H7F2NO difluoroacetanilide 404-17-1 C8H7F7O3 ethyl...
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Lacosamide (category Benzyl compounds)
acid. The product is treated first with N-methylmorpholine, isobutyl chloroformate, and benzylamine, next with methyl iodide and silver oxide, forming...
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a benzyl ester on the carboxyl group, a fluorenylmethylenoxy carbamate on the amine group, and a tert-butyl ether on the phenol group. The benzyl ester...
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hydride affords 4-Benzyl-2-({2-[(thiophen-2-yl)methyl]phenoxy}methyl)morpholine [62473-77-2] (5). Treatment with Ethyl chloroformate [541-41-3] (6) gives...
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groups such as the benzyloxycarbonyl, 9-fluorenylmethoxycarbonyl, O- and S-benzyl and t-butylthio groups. The synthesis of 6-acetyl-1,2,3,4-tetrahydropyridine...
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then protected as its ethyl carbamate by acylation with ethyl chloroformate (6). The benzyl carbamate function on nitrogen at the 4 position is next removed...
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H2O The diphenoxide (Na2(OC6H4)2CMe2) reacts with phosgene to give a chloroformate, which subsequently is attacked by another phenoxide. The net reaction...
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Both Benzyl bromide 1915 Lachrymatory Central Powers Chloromethyl chloroformate 1915 Irritant – Eyes, skin, lungs Both Trichloromethyl chloroformate 1916...
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carbonyls are urea and the carbamates, the derivatives of acyl chlorides chloroformates and phosgene, carbonate esters, thioesters, lactones, lactams, hydroxamates...
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halogenated, the amide is prepared, and reduced. (a) (1) 1-chloroethyl chloroformate, 1,2-dichloroethane, reflux; (2) MeOH reflux; (b) p-toluenesulfonyl...
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were combined in an amine-carbonyl condensation followed by methyl chloroformate quench to triene 3 which was then reacted in a Diels–Alder reaction...
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chloride 33631-63-9 C7H13ClO heptanoyl chloride 2528-61-2 C7H13ClO2 hexyl chloroformate 6092-54-2 C7H13LiO2 lithium heptanoate 16761-13-0 C7H13N diethylpropargylamine...
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substantial minor product. Certain electrophiles also elicit nitriles: chloroformates, strongly-activated alkynes, or methyl iodide and a hindered base. Methyl...
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