Biphenylene is an organic compound with the formula (C6H4)2. It is a pale, yellowish solid with a hay-like odor. Despite its unusual structure, it behaves...
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2,2′-Biphenylene phosphorochloridite is the name for a polycyclic organophosphorus compound with the formula C12H8O2PCl. It is a precursor to diphosphite...
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spectroscopy. Examples of antiaromatic compounds are pentalene (A), biphenylene (B), cyclopentadienyl cation (C). The prototypical example of antiaromaticity...
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0626 u) may refer to: Acenaphthylene, a polycyclic aromatic hydrocarbon Biphenylene, an alternant, polycyclic hydrocarbon This set index page lists chemical...
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Seitz, A. H.; Friedman, L. (1968). "Benzenediazonium-2-carboxy- and Biphenylene". Organic Syntheses. 48: 12. Atkinson, E. R.; Lawler, H. J. (1927). "Diphenic...
13 KB (1,057 words) - 18:06, 15 August 2023
substructures locally while avoiding anti-aromatic ones (see Clar sextet and biphenylene). A maximum of eight valence electrons is strict for the Period 2 elements...
42 KB (5,094 words) - 06:04, 25 June 2024
layer carbon material with biphenylene-like subunits as basis in its hexagonal lattice structure. It is also known as biphenylene-carbon. Carbophene is a...
48 KB (5,635 words) - 12:34, 27 August 2024
yield by oxidation with lead(IV) acetate, which rapidly dimerizes to biphenylene in good yields. Electron deficient heterocycles, such as tetrazole, can...
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reactive intermediates, benzyne must be trapped, otherwise it dimerises to biphenylene. Early routes to benzyne involved dehydrohalogenation of aryl halides:...
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amine with lead(IV) acetate affords benzyne, which rapidly dimerises to biphenylene. Benzotriazole has been known for its great versatility. It has already...
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SR6. One of the few all-carbon persulfuranes has two methyl and two biphenylene ligands: It is prepared from the corresponding sulfurane 1 with xenon...
26 KB (3,035 words) - 15:33, 11 July 2024
Seitz, A. H.; Friedman, L. (1968). "Benzenediazonium-2-carboxy- and Biphenylene". Org. Synth. 48: 12. doi:10.15227/orgsyn.048.0012. Reinhard Bruckner...
32 KB (3,277 words) - 09:54, 9 September 2024
benzenehexacarboxylic acid 517-60-2 C12H8 acenaphthylene 208-96-8 C12H8 biphenylene 259-79-0 C12H8Cl6 aldrin 309-00-2 C12H8Cl6O endrin 72-20-8 C12H8N2 phenazine...
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Union Carbide, it has become a standard ligand in hydroformylation. 2,2'-Biphenylene phosphorochloridite (C12H8O2PCl) precursor to BiPhePhos. Gual, Aitor;...
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University. Her thesis at Perdue, "A Study of the Direct Synthesis of Biphenylene Silanes", was supervised by Professor Grant Urry. Kuck worked at Lucent...
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3-naphthoquinonoid heterocycles. A synthetic route to derivatives of naphtho[2,3-b]biphenylene and anthra[b]cyclobutene". The Journal of Organic Chemistry. 34 (3):...
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Structure of 2,2'-biphenylene phosphorochloridite....
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3-naphthoquinonoid heterocycles. A synthetic route to derivatives of naphtho[2,3-b]biphenylene and anthra[b]cyclobutene", Journal of Organic Chemistry. Org. Chem.,...
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the Heck reaction, the Hiyama coupling, and the Sonogashira coupling. Biphenylenes had been obtained before with reasonable yields using 2,2-diiodobiphenyl...
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nodes at the 9-position (Sb). Thus, Lewis bases bind towards trans to biphenylene and its fluoride adducts are asymmetric: 8·F− has two enantiomers and...
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Dithymoquinone (category Biphenylenes)
Dithymoquinone is a bioactive isolate of Nigella sativa. Chemically, it is a dimer of thymoquinone. PubChem. "Dithymoquinone". pubchem.ncbi.nlm.nih.gov...
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other. Both mechanisms are shown as follows for the ring contraction of biphenylene: The first involves a 1,2-hydrogen shift to a carbene followed by a 1...
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XXXVI.1 The Synthesis of Two Isomers of Bisdehydro[12]annulene and Biphenylene from 1,5-Hexadiyne Reuven Wolovsky, Franz Sondheimer J. Am. Chem. Soc...
5 KB (741 words) - 12:57, 25 September 2024