• Thumbnail for Biphenylene
    Biphenylene is an organic compound with the formula (C6H4)2. It is a pale, yellowish solid with a hay-like odor. Despite its unusual structure, it behaves...
    13 KB (1,308 words) - 23:18, 30 April 2024
  • Thumbnail for 2,2'-Biphenylene phosphorochloridite
    2,2′-Biphenylene phosphorochloridite is the name for a polycyclic organophosphorus compound with the formula C12H8O2PCl. It is a precursor to diphosphite...
    2 KB (130 words) - 10:31, 12 January 2024
  • spectroscopy. Examples of antiaromatic compounds are pentalene (A), biphenylene (B), cyclopentadienyl cation (C). The prototypical example of antiaromaticity...
    19 KB (2,236 words) - 04:00, 23 April 2024
  • 0626 u) may refer to: Acenaphthylene, a polycyclic aromatic hydrocarbon Biphenylene, an alternant, polycyclic hydrocarbon This set index page lists chemical...
    300 bytes (63 words) - 19:33, 5 November 2022
  • Thumbnail for Anthranilic acid
    Seitz, A. H.; Friedman, L. (1968). "Benzenediazonium-2-carboxy- and Biphenylene". Organic Syntheses. 48: 12. Atkinson, E. R.; Lawler, H. J. (1927). "Diphenic...
    13 KB (1,057 words) - 18:06, 15 August 2023
  • substructures locally while avoiding anti-aromatic ones (see Clar sextet and biphenylene). A maximum of eight valence electrons is strict for the Period 2 elements...
    42 KB (5,094 words) - 06:04, 25 June 2024
  • Thumbnail for Allotropes of carbon
    layer carbon material with biphenylene-like subunits as basis in its hexagonal lattice structure. It is also known as biphenylene-carbon. Carbophene is a...
    48 KB (5,635 words) - 12:34, 27 August 2024
  • Thumbnail for Hydroxylamine-O-sulfonic acid
    yield by oxidation with lead(IV) acetate, which rapidly dimerizes to biphenylene in good yields. Electron deficient heterocycles, such as tetrazole, can...
    17 KB (1,606 words) - 08:39, 27 August 2024
  • reactive intermediates, benzyne must be trapped, otherwise it dimerises to biphenylene. Early routes to benzyne involved dehydrohalogenation of aryl halides:...
    28 KB (3,128 words) - 23:01, 27 July 2024
  • Thumbnail for Benzotriazole
    amine with lead(IV) acetate affords benzyne, which rapidly dimerises to biphenylene. Benzotriazole has been known for its great versatility. It has already...
    13 KB (1,065 words) - 22:56, 21 September 2024
  • SR6. One of the few all-carbon persulfuranes has two methyl and two biphenylene ligands: It is prepared from the corresponding sulfurane 1 with xenon...
    26 KB (3,035 words) - 15:33, 11 July 2024
  • Thumbnail for Diazonium compound
    Seitz, A. H.; Friedman, L. (1968). "Benzenediazonium-2-carboxy- and Biphenylene". Org. Synth. 48: 12. doi:10.15227/orgsyn.048.0012. Reinhard Bruckner...
    32 KB (3,277 words) - 09:54, 9 September 2024
  • benzenehexacarboxylic acid 517-60-2 C12H8 acenaphthylene 208-96-8 C12H8 biphenylene 259-79-0 C12H8Cl6 aldrin 309-00-2 C12H8Cl6O endrin 72-20-8 C12H8N2 phenazine...
    27 KB (28 words) - 20:19, 6 February 2024
  • Thumbnail for BiPhePhos
    Union Carbide, it has become a standard ligand in hydroformylation. 2,2'-Biphenylene phosphorochloridite (C12H8O2PCl) precursor to BiPhePhos. Gual, Aitor;...
    3 KB (202 words) - 15:40, 19 August 2022
  • University. Her thesis at Perdue, "A Study of the Direct Synthesis of Biphenylene Silanes", was supervised by Professor Grant Urry. Kuck worked at Lucent...
    6 KB (651 words) - 04:24, 27 September 2023
  • Thumbnail for Sulfolene
    3-naphthoquinonoid heterocycles. A synthetic route to derivatives of naphtho[2,3-b]biphenylene and anthra[b]cyclobutene". The Journal of Organic Chemistry. 34 (3):...
    17 KB (1,848 words) - 03:18, 18 September 2024
  • Structure of 2,2'-biphenylene phosphorochloridite....
    3 KB (276 words) - 16:15, 25 July 2023
  • Thumbnail for 1,3-Diphenylisobenzofuran
    3-naphthoquinonoid heterocycles. A synthetic route to derivatives of naphtho[2,3-b]biphenylene and anthra[b]cyclobutene", Journal of Organic Chemistry. Org. Chem.,...
    20 KB (1,956 words) - 10:07, 11 January 2024
  • the Heck reaction, the Hiyama coupling, and the Sonogashira coupling. Biphenylenes had been obtained before with reasonable yields using 2,2-diiodobiphenyl...
    15 KB (1,596 words) - 18:24, 26 September 2024
  • nodes at the 9-position (Sb). Thus, Lewis bases bind towards trans to biphenylene and its fluoride adducts are asymmetric: 8·F− has two enantiomers and...
    23 KB (2,302 words) - 16:32, 7 June 2023
  • Thumbnail for Dithymoquinone
    Dithymoquinone (category Biphenylenes)
    Dithymoquinone is a bioactive isolate of Nigella sativa. Chemically, it is a dimer of thymoquinone. PubChem. "Dithymoquinone". pubchem.ncbi.nlm.nih.gov...
    2 KB (56 words) - 17:18, 18 June 2024
  • Thumbnail for Thermal rearrangement of aromatic hydrocarbons
    other. Both mechanisms are shown as follows for the ring contraction of biphenylene: The first involves a 1,2-hydrogen shift to a carbene followed by a 1...
    16 KB (1,690 words) - 10:56, 28 May 2022
  • Thumbnail for Annulyne
    XXXVI.1 The Synthesis of Two Isomers of Bisdehydro[12]annulene and Biphenylene from 1,5-Hexadiyne Reuven Wolovsky, Franz Sondheimer J. Am. Chem. Soc...
    5 KB (741 words) - 12:57, 25 September 2024