Tributyltin oxide (TBTO) is an organotin compound chiefly used as a biocide (fungicide and molluscicide), especially a wood preservative. Its chemical...
4 KB (171 words) - 06:30, 27 April 2024
atoms in organic synthesis. The compound is produced by reduction of tributyltin oxide with polymethylhydrosiloxane: 2 "[MeSi(H)O]n" + (Bu3Sn)2O → "[MeSi(OH)O]n"...
5 KB (425 words) - 22:34, 23 August 2024
Illustrative of its use, PMHS is used for in situ conversion of tributyltin oxide to tributyltin hydride: 2 MeSiH + (Bu3Sn)2O → Me2Si2O + 2 Bu3SnH J. M. Lavis...
3 KB (270 words) - 20:06, 21 October 2023
of organic substituents. Tributyltin hydride is used as a source of hydride radical in some organic reactions. Organotin oxides and hydroxides are common...
24 KB (2,623 words) - 18:21, 19 September 2024
difficult to remove from the reaction mixture. One alternative is tributyltin oxide as the radical source and poly(methylhydridesiloxane) (PMHS) as the...
8 KB (749 words) - 06:50, 9 September 2024
temperatures. The reaction can also be effected through radical reaction with tributyltin hydride and a radical initiator, AIBN as an example. Aliphatic nitro...
14 KB (1,485 words) - 13:12, 20 July 2023
organozinc compounds such as diethylzinc (Et2Zn), organotin compounds such as tributyltin hydride (Bu3SnH), organoborane compounds such as triethylborane (Et3B)...
31 KB (3,157 words) - 20:03, 24 September 2024
antifouling agent. In the United States, copper-based paint replaced tributyltin, which was banned due to its toxicity, as a way for boats to control...
25 KB (2,685 words) - 04:02, 20 June 2024
described a reaction between several aryl bromides and N,N-diethylamino-tributyltin using 1 mol% PdCl2[P(o-tolyl)3]2. Though several aryl bromides were tested...
31 KB (3,483 words) - 01:36, 25 April 2024
28911-01-5 S,S,S-Tributyl phosphorotrithioate (Tribufos, DEF) 78-48-8 Tributyltin methacrylate 2155-70-6 Trichlormethine (Trimustine hydrochloride) 817-09-4...
48 KB (211 words) - 18:08, 25 April 2024
alkylation. An IL based on tetraalkylphosphonium iodide is a solvent for tributyltin iodide, which functions as a catalyst to rearrange the monoepoxide of...
43 KB (4,706 words) - 07:07, 9 August 2024
alcohol 2.8 it was possible to remove the phenylsulfide group in with a tributyltin hydride and AIBN(see Barton-McCombie deoxygenation) to alcohol 2.9. Palladium...
11 KB (1,349 words) - 21:47, 16 July 2024
oxidation – commonly with DDQ. p,m‑Dimethoxybenzyl ether — Removed via oxidation with DDQ or ceric ammonium chloride Acetals: Dimethoxytrityl, [bis...
57 KB (6,755 words) - 23:19, 9 April 2024