The Cannizzaro reaction, named after its discoverer Stanislao Cannizzaro, is a chemical reaction which involves the base-induced disproportionation of...

famous for the Cannizzaro reaction and for his influential role in the atomic-weight deliberations of the Karlsruhe Congress in 1860. Cannizzaro was born in...

aldehyde slowly to the said reaction mixture. Using too concentrated base could lead to a competing Cannizzaro reaction. The Aldox process, developed...

for a base-catalyzed self-condensation (Cannizzaro reaction) to occur. A general scheme of the Cannizzaro reaction is depicted below. There have been a series...

aluminium alkoxides are effective catalysts for the reaction. In the related Cannizzaro reaction, the base is sodium hydroxide and then the oxidation...

for the reaction, consisting of the following steps: The reaction exhibits an induction period, during which only the nonproductive Cannizzaro disproportionation...

Cannizzaro reaction, an aldehyde is converted into an alcohol and a carboxylic acid. In the related Tishchenko reaction, the organic redox reaction product...

can still result in substantial byproducts. Examples include the Cannizzaro reaction, in which approximately 50% of the reactant aldehyde becomes the...

(e.g., benzaldehyde), addition of strong base induces the Cannizzaro reaction. This reaction results in disproportionation, producing a mixture of alcohol...

quinoline synthesis Cannizzaro reaction Carbohydrate acetalisation Carbonyl reduction Carbonylation Carbylamine reaction Carroll reaction Castro–Stephens...

For laboratory use, Grignard reaction of phenylmagnesium bromide (C6H5MgBr) with formaldehyde and the Cannizzaro reaction of benzaldehyde also give benzyl...

syn- or anti-1,3-diols. The resulting carbonyl is reduced using the Cannizzaro reaction or by catalytic hydrogenation: RC(O)CH3 + CH2O → RC(O)CH2CH2OH RC(O)CH2CH2OH...

undergoes disproportionation upon treatment with concentrated alkali (Cannizzaro reaction): one molecule of the aldehyde is reduced to the benzyl alcohol and...

mainly of academic interest. Disproportionation of an aldehyde in the Cannizzaro reaction Rearrangement of diketones in the benzilic acid rearrangement Involving...

hydroxypivaldehyde, which can be converted to neopentyl glycol by either a Cannizzaro reaction with excess formaldehyde, or by hydrogenation using palladium on...

pentaerythritol synthesis and in the crossed Cannizzaro reaction of formaldehyde with the aldol reaction product trimethylol acetaldehyde [3-hydroxy-2...

difficult to produce. Aldol addition Acyloin condensation Cannizzaro reaction Stetter reaction Umpolung Menon, Rajeev S.; Biju, Akkattu T.; Nair, Vijay...

hydrogenation catalyst then reduces to the alcohol. The Cannizzaro reaction is a competing reaction when two aldehyde molecules react by disproportionation...

multiple-addition reaction between acetaldehyde and 3 equivalents of formaldehyde to give pentaerythrose (CAS: 3818-32-4), followed by a Cannizzaro reaction with a...

plane and automobile designer Stanislao Cannizzaro (1826–1910), Italian chemist remembered for the Cannizzaro reaction and the Karlsruhe Congress of 1860 Stanisław...

cyclization reaction Elimination reaction Beta elimination Cope elimination E1cB elimination reaction Hofmann elimination Organic redox reaction Cannizzaro reaction...

m-phenoxytoluene over selenium dioxide provides m-phenoxybenzaldehyde. Third, a Cannizzaro reaction of the benzaldehyde in formaldehyde and potassium hydroxide affords...

α-keto aldehydes can be transformed into α-hydroxy acids through the Cannizzaro reaction. R−C(O)CHO + 2OH− → R−CH(OH)CO−2 + H2O α-Hydroxy acids, such as glycolic...

expansion of a cyclopentane to a cyclohexane ring as an example reaction. Cannizzaro reaction Pinacol rearrangement Liebig, J. (1838). "Ueber Laurent's Theorie...

methanol. In the Cannizzaro reaction, formaldehyde and base react to produce formic acid and methanol, a disproportionation reaction. Formaldehyde reacts...

hydrolysis, the Cannizzaro reaction, nucleophilic aliphatic substitution, nucleophilic aromatic substitution, and in elimination reactions. The reaction medium...

OCHCO2H ⇌ OCHCO− 2 + H+ Heated glyoxylic acid disproportionates in a Cannizzaro reaction, forming hydroxyacetic acid and oxalic acid: 2 OCHCO2H + H2O → HOCH2CO2H...

Majorana fermions. Sicily's famous scientists also include Stanislao Cannizzaro (chemist), Giovanni Battista Hodierna and Niccolò Cacciatore (astronomers)...

Candaules, Lydian king – candaulism Stanislao Cannizzaro (1826–1910), Italian chemist – Cannizzaro reaction Georg Cantor, German mathematician – Cantor...

Calvin–Benson cycle) – Melvin Calvin (and Andy Benson) Cannizzaro reaction – Stanislao Cannizzaro Cardan angles (a.k.a. Tait–Bryan angles) – Gerolamo Cardano...