A carbocation is an ion with a positively charged carbon atom. Among the simplest examples are the methenium CH+ 3, methanium CH+ 5, acylium ions RCO+...
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Reaction intermediate (section Carbocations)
isolated. Cations, often carbocations, serve as intermediates in various types of reactions to synthesize new compounds. Carbocations are formed in two major...
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accurately described using steady-state kinetics. The reaction involves a carbocation intermediate and is commonly seen in reactions of secondary or tertiary...
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Tertiary carbon (section Carbocation Stability)
density with the central carbocation to stabilize it. Additionally, the surrounding sp3 hybridized carbons can stabilize the carbocation through hyperconjugation...
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with water in an additional reaction to form an alcohol that involves carbocation formation. The hydroxyl group (OH) bonds to the carbon that has the greater...
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phenyl carbocation > hydride > tertiary carbocation (if formed by migration) > secondary carbocation (if formed by migration) > methyl carbocation. {Why...
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at McMaster University, and has been used by George Olah to stabilise carbocations and hypercoordinated carbonium ions in liquid media. Magic acid and other...
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A pyramidal carbocation is a type of carbocation with a specific configuration. This ion exists as a third class, besides the classical and non-classical...
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alkylating agents (ones for which carbocation rearrangement is degenerate), or alkylating agents that yield stabilized carbocations (e.g., benzylic or allylic...
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stabilize the charge on the carbocation through resonance and distribution of charge. In this case, tertiary carbocation will react faster than a secondary...
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open to this oxocarbenium intermediate are: in blue: capture of the carbocation by water or any suitable nucleophile through 5 to the 1,3-adduct 6. in...
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Carbenium ion (category Carbocations)
of carbocations, which is a general term for diamagnetic carbon-based cations. In parallel with carbenium ions is another subset of carbocations, the...
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Rearrangement reaction (redirect from Carbocation rearrangement)
In organic chemistry, a rearrangement reaction is a broad class of organic reactions where the carbon skeleton of a molecule is rearranged to give a structural...
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tert-butanol is a tertiary alcohol, the relative stability of the tert-butyl carbocation in the step 2 allows the SN1 mechanism to be followed, whereas a primary...
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Polyvinyl chloride (PVC), a particular vinyl polymer Vinyl cation, a type of carbocation Vinyl group, a broad class of organic molecules in chemistry Vinyl polymer...
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Carbonium ion (category Carbocations)
a cation that has a pentacoordinated carbon atom. They are a type of carbocation. In older literature, the name "carbonium ion" was used for what is today...
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stabilizing carbocation formation, the fragmentation becomes a viable reaction pathway. The reaction generates a nitrile and a carbocation, which is quickly...
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involved, whether a reactive intermediate involved in the reaction is a carbocation, a carbanion or a free radical, and whether the substrate is aliphatic...
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often initialised by the formation of a reactive intermediate such as: a carbocation by heterolysis in a nucleophilic rearrangement or anionotropic rearrangement...
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Nonclassical ion (redirect from Non-classical carbocation)
27, 374-379 [8] 2-Norbornyl cation Neighbouring group participation Carbocation Steric effects Solvation Scholz, F.; Himmel, D.; Heinemann, F. W.; Schleyer...
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(proton) attacks the double bond forming a carbocation, which then reacts with the nucleophile (bromine). The carbocation can be formed on either side of the...
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Triphenylcarbenium (redirect from Trityl carbocation)
2019-07-25. Naidu, Veluru Ramesh; Ni, Shengjun; Franzén, Johan (2015). "The Carbocation: A Forgotten Lewis Acid Catalyst". ChemCatChem. 7 (13): 1896–1905. doi:10...
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the first transition state in a SN1 reaction. The stabilities of the carbocations formed by this dissociation are known to follow the trend tertiary >...
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of the corresponding carbocations. Tertiary carbocations are far more stable than secondary carbocations, and primary carbocations are the least stable(due...
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stability of the carbocation, and steric effects. As brief examples, the formation of a sterically unencumbered, stabilized carbocation favors the AdE2...
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limonene is formed from geranyl pyrophosphate, via cyclization of a neryl carbocation or its equivalent as shown. The final step involves loss of a proton...
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deprotonation of the α-carbon. This results in the formation of a carbocation intermediate. The carbocation is then deprotonated resulting in the formation of a new...
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leaving a carbocation on the tertiary carbon attached to the ring. A 1,3-hydride shift then takes place to give a more stable allylic carbocation. The final...
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Acylium ions (category Carbocations)
cations with the formula RCO+, where R = alkyl or aryl. They are a kind of carbocation. In acylium ions, the C-C-O linkage is linear. The oxygen and the central...
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leaving group, this generates the carbocation. In the second step, the chloride nucleophile attacks the carbocation to form the product. 2-Chlorobutane...
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