Desymmetrization is a chemical reaction that converts prochiral substrates into chiral products. Desymmetrisations are so pervasive that they are rarely...

ion pairs. In one example, they are used to catalyze the asymmetric desymmetrization by monohydrolysis of a diester. Klussmann, Martin; Ratjen, Lars; Hoffmann...

Weinheim. doi:10.1002/14356007.a04_455.pub2 Nugent, William A. (1998). "Desymmetrization of Meso Epoxides with Halides: A New Catalytic Reaction Based on Mechanistic...

Jean-Marc; Bressy, Cyril (May 2017). "Catalytic Enantioselective Desymmetrization of Meso Compounds in Total Synthesis of Natural Products: Towards an...

Chênevert R, Morin P (2009). "Synthesis of (−)-lobeline via enzymatic desymmetrization of lobelanidine". Bioorg. Med. Chem. 17 (5): 1837–9. doi:10.1016/j...

S. Simpkins, and Fengzhi Zhang (2007). "Chiral Lithium Amide Base Desymmetrization of a Ring Fused Imide: Formation of (3aS,7aS)-2[2-(3,4-Dimethoxyphenyl)-ethyl]-1...

three stereoisomers of this pheromone is employing lipase-catalyzed desymmetrization or enantiomer separation of syn- or anti-2,4-dimethylpentane-1,5-diol...

symproportionation. More generally, the term can be applied to any desymmetrizing reaction where two molecules of one type react to give one each of two...

Wolstenholme D, Zambon A (May 2007). "Chiral polycyclic ketones via desymmetrization of dihaloolefins". The Journal of Organic Chemistry. 72 (11): 4272–5...

corresponds to a desymmetrization reaction. For instance, mevalonolactone may be synthesized rapidly from a symmetric diester via desymmetrizing hydrolysis...

Lomberget, T.; Bragg, R.; Poulard, C.; Bernardinelli, G. (2004). "Desymmetrization of a meso-Diol Complex Derived from [Cr(CO)3(η6-5,8-Naphthoquinone)]:...

isophthalic acid route, which involves catalytic hydrogenation and enzymatic desymmetrization.[citation needed] In 2006 the group of E.J. Corey published a novel...

Alzahra University Thesis Enantioselective Synthesis of Natural Products Via Enzymatic Desymmetrizations (2000) Doctoral advisor Thérèse Di Paolo-Chênevert...

carbapenem biosynthesis. 6-oxo camphor hydrolase, which catalyses the desymmetrization of bicyclic beta-diketones to optically active keto acids. The alpha...

this context. An interesting application of IMHR is group-selective desymmetrization (enantiotopic group selection), in which the chiral palladium aryl...

Working Papers in Linguistics. 17: 348–359. Richards, Marc D. (2008). "Desymmetrization: Parametric variation at the PF-Interface". The Canadian Journal of...

PhCH(OH)CH(OH)Ph (R,R isomer) This transformation is an example of desymmetrization, the symmetric molecule benzil is converted to the dissymmetric product...

catalysts for asymmetric epoxidation, hydrolytic kinetic resolution and desymmetrization of epoxides, asymmetric pericyclic reactions, and asymmetric additions...

"Single-Crystal-to-Single-Crystal (SCSC) Linear Polymerization of a Desymmetrized Anthraphane". Chemistry - A European Journal. 24 (56): 15003–15012....

3-disubstituted Isoindolines from Selective Catalytic Fragmentation of Original Desymmetrized Rigid Overbred Template, Org. Biomol. Chem., DOI: 10.1039/C5OB00229J...

electrostatic and dipole-dipole interactions in proline-catalyzed asymmetric desymmetrization of pro-chiral ketones with nitrosobenzene. He has also examined the...

oxidations are typically either kinetic resolutions of chiral alcohols or desymmetrization reactions. These oxidations may be facilitated through the use of chiral...

Simpkins, Nigel S.; Zhang, Fengzhi (2007). "Chiral Lithium Amide Base Desymmetrization of a Ring Fused Imide: Formation of (3aS,7aS)-2-[2-(3,4-Dimethoxyphenyl)-ethyl]-1...

D (November 2017). "Synthesis of (+)-Pancratistatins via Catalytic Desymmetrization of Benzene". Journal of the American Chemical Society. 139 (44): 15656–15659...

the first highly selective acylation of racemic diols (as well as desymmetrization of meso diols). With low catalyst loading of 1%, enantioenriched diol...

Roberts GA, Bougioukou D, Turner NJ, Flitsch SL (April 2001). "The desymmetrization of bicyclic beta -diketones by an enzymatic retro-Claisen reaction...

Yamauchi M, et al. (July 2014). "C5-symmetric chiral corannulenes: desymmetrization of bowl inversion equilibrium via "intramolecular" hydrogen-bonding...

Delphine; Wang, Qian; Zhu, Jieping (2014). "Phosphoric Acid Catalyzed Desymmetrization of Bicyclic Bislactones Bearing an All-Carbon Stereogenic Center: Total...

Hupp, Florian; Radacki, Krzysztof; Trumpp, Alexandra (2016-08-12). "Desymmetrizing Electron-Deficient Diboranes(4): Diverse Products and Their Reactivity"...

convenient access to chiral epoxyquinone building blocks through enzymatic desymmetrization. Tetrahedron Lett. 2004, 45, 3611-3615. Rodriguez, A.; Nomen, M.; Spur...