Diimines are organic compounds containing two imine (RCH=NR') groups. Common derivatives are 1,2-diimines and 1,3-diimines. These compounds are used as...
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Diimide, also called diazene or diimine, is a compound having the formula HN=NH. It exists as two geometric isomers, E (trans) and Z (cis). The term diazene...
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to a variety of bulky ligands. Condensation with glyoxal gives the 1,2-diimine ligands. An example is glyoxal-bis(mesitylimine), a yellow solid that is...
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discovered in the 1980-1990s. Nickel(II) and palladium(II) complexes of α-diimine ligands were known to efficiently catalyze polymerization of alkenes. They...
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some cases, HNacNacs also serve as charge-neutral 1,3-diimine ligands. NacNac ligands are diimine analogues of acetylacetonate ligands. An intermediate...
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molecules condense with the two carbonyl groups to give a diimine: In the second stage, this diimine condenses with the aldehyde: However, the actual reaction...
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a cyclic [3,3]-sigmatropic rearrangement occurs producing a diimine. The resulting diimine forms a cyclic aminoacetal (or aminal), which under acid catalysis...
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horseradish peroxidase. The resulting one-electron oxidation product is a diimine-diamine complex, which causes the solution to take on a blue colour, and...
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post-metallocene catalyst designs Catalyst supported by charge-neutral alpha-diimine ligands. Catalyst supported by highly electron-withdrawing substituted...
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the diamine condenses with 4-Trifluoromethylbenzaldehyde to give to the diimine. The salen ligands, some of which are used in catalysis, are derived from...
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The enol is about 1 kcal/mol more stable than the diketo form. Numerous diimine and dioxime ligands have been prepared from this diketone. It also condenses...
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1,1'-Diaminoferrocene has been incorporated into various diamide and diimine ligands, which form catalysts that exhibit redox switching. Fabbrizzi,...
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multiple names: authors list (link). Mashima, Kazushi (2020). "Redox-Active α-Diimine Complexes of Early Transition Metals: From Bonding to Catalysis". Bulletin...
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synthesized by condensation of 2,4,6-trimethylaniline and glyoxal to give the diimine. In the presence of acid, the resulting glyoxal-bis(mesitylimine) condenses...
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Quinone imine – where one O is replaced by N, illustrated by NAPQI Quinone diimine – where both O's are replaced by N's, illustrated by the antiseptic ambazone...
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are chemical compounds of the formula S(NR)2. Structurally, they are the diimine of sulfur dioxide. The parent member, S(NH)2, is of only theoretical interest...
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Paul J. (2018). "Synthesis and Electronic Structure Diversity of Pyridine(diimine)iron Tetrazene Complexes". Inorganic Chemistry. 57 (16): 9634–9643. doi:10...
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n-butyllithium is a Stork enamine / 1,2-addition cascade reaction: Iron[pyridine(diimine)] catalysts contain a redox active ligand in which the central iron atom...
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4-diaminobenzene derivative to the quinone state. 2) Reaction of this diimine with a coupler compound (more detail below). 3) Oxidation of the resulting...
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of monomer was added (5). α-diimine chelate initiators α-diimine chelate initiators are characterized by having a diimine chelating ancillary ligand structure...
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of the spectroscopy, photochemistry and electrochemistry of [M(CO)4(α-diimine)] complexes, M=Cr, Mo, W" Antonín Vlcek Coord. Chem. Rev. 230 (2002) 225-242...
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1,1'-Diaminoferrocene has been incorporated into various diamide and diimine ligands, which form catalysts that exhibit redox switching. Shafir, Alexandr;...
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aminoxyl radicals and was first thought to degrade only to the quinone diimine, but has since been understood to continue to oxidize to quinones, amongst...
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coordination chemistry. Oxidation of metal-phenylenediamine complexes affords the diimine derivatives. OPD condenses with salicylaldehyde to give chelating Schiff...
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Amidines are also prepared by the addition of organolithium reagents to diimines, followed by protonation or alkylation. Amidines are much more basic than...
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yellow solid that is soluble in organic solvents. It is classified as a diimine ligand. It is used in coordination chemistry and homogeneous catalysis...
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Diiminopyridines (DIP, also known a pyridine diimines, PDIs) are a class of diimine ligands. They featuring a pyridine nucleus with imine sidearms appended...
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subsequently undergoes elimination of p-toluenesulfinic acid and decomposes via a diimine intermediate 3 to the corresponding hydrocarbon. A slight variation of...
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Volumes, vol. 7, p. 41. Park, C. H.; Simmons, H. E. (1974). "Macrocyclic Diimines: 1,10-Diazacyclooctadecane". Organic Syntheses. 54: 88; Collected Volumes...
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sodium acetate solution produces primary sulfonamides in very good yields. Diimine can formed in situ from hydroxylamine-O-sulfonic acid respectively...
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