Α,β-Unsaturated carbonyl compound (redirect from Enone)
compounds with the general structure (O=CR)−Cα=Cβ-R. Such compounds include enones and enals, but also carboxylic acids and the corresponding esters and amides...
10 KB (1,119 words) - 23:33, 23 March 2024
In organic chemistry, enone–alkene cycloadditions are a version of the [2+2] cycloaddition. This reaction involves an enone and alkene as substrates....
9 KB (1,024 words) - 06:19, 29 April 2024
Enolate (section Synthesis of enones using regiospecific enolate formation and masked functionality)
2-ethanedithiol protected ketone). An enone can also serve as a precursor for regiospecific formation of an enolate, here the enone is a "masked functionality"...
21 KB (2,467 words) - 22:07, 14 August 2024
Norethisterone (category Enones)
Norethisterone, also known as norethindrone and sold under many brand names, is a progestin medication used in birth control pills, menopausal hormone...
92 KB (9,328 words) - 04:45, 11 July 2024
which makes the compound an α,β-unsaturated carbonyl compound (either an enone or an enal), or R" may be any electron withdrawing group. As originally...
27 KB (2,825 words) - 08:27, 20 March 2024
intermolecular [2+2] cycloadditions of activated olefins: particularly enones and styrenes. Enones, or electron-poor olefins, were discovered to react via a radical-anion...
50 KB (6,218 words) - 23:10, 8 February 2024
aza-equivalent of the Paternò–Büchi reaction Enone–alkene cycloadditions - photochemical reaction of an enone with an alkene to give a cyclobutene ring unit...
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Hosomi-Sakurai reaction is also applicable for other functional groups such as enones, where conjugate addition is usually seen. In figure 2, the Hosomi- Sakurai...
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Testosterone (category Enones)
Testosterone is the primary male sex hormone and androgen in males. In humans, testosterone plays a key role in the development of male reproductive tissues...
149 KB (15,717 words) - 14:45, 15 September 2024
condensation). The product is often an α,β-unsaturated ketone (a conjugated enone). In this reaction the carbonyl group is an aldehyde or a ketone. The catalyst...
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a key aromatization step in the synthesis of estrogen. It converts the enone ring of androgen precursors such as testosterone, to a phenol, completing...
21 KB (2,051 words) - 06:17, 13 January 2024
reaction), and this is then followed by dehydration to give a conjugated enone. The overall reaction equation is as follows (where the Rs can be H) Aldol...
17 KB (1,679 words) - 06:32, 22 March 2024
Clostebol (category Enones)
Clostebol (INNTooltip International Nonproprietary Name; also known as 4-chlorotestosterone) usually as the ester clostebol acetate, is a synthetic anabolic–androgenic...
13 KB (1,034 words) - 01:13, 30 August 2024
Chalcone (category Enones)
Chalcone is the organic compound C6H5C(O)CH=CHC6H5. It is an α,β-unsaturated ketone. A variety of important biological compounds are known collectively...
8 KB (669 words) - 23:03, 27 June 2023
Chlorodehydromethyltestosterone (category Enones)
Chlorodehydromethyltestosterone (CDMT; brand name Oral Turinabol), also known as 4-chloro-17β-hydroxy17α-methylandrosta-1,4-dien-3-one, is an anabolic–androgenic...
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Methyl vinyl ketone (category Enones)
with the formula CH3C(O)CH=CH2. It is a reactive compound classified as an enone, in fact the simplest example thereof. It is a colorless, flammable, highly...
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Nandrolone (category Enones)
Nandrolone, also known as 19-nortestosterone, is an endogenous androgen. It is also an anabolic steroid (AAS) which is medically used in the form of esters...
48 KB (4,571 words) - 14:08, 8 September 2024
probable mechanisms are thus two possibilities: The phenoxide attacks the enone at the beta position, and the alkene directly attacks hydrogen peroxide...
2 KB (214 words) - 08:11, 18 July 2024
Cadiot–Chodkiewicz coupling and the Sonogashira coupling. Conjugate addition to enones and carbocupration of alkynes can also be achieved with organocopper compounds...
122 KB (13,880 words) - 03:24, 5 September 2024
Isotretinoin (category Enones)
Isotretinoin, also known as 13-cis-retinoic acid and sold under the brand name Accutane among others, is a medication used to treat skin diseases like...
75 KB (7,798 words) - 15:27, 1 September 2024
esters, whereas relatively unpolarized reactants (e.g. an alkyl halide or enone) give sulfones.: 682 Sulfinates react with Grignard reagents to give sulfoxides...
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with palladium(II) acetate and benzoquinone to yield the corresponding enone. The original publication noted its utility for regeneration of unsaturation...
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Dienone (category Enones)
–C(=O)– group .", resulting in "a conjugated structure". They are a kind of enone. The class includes some heterocyclic compounds. There is no evidence that...
3 KB (276 words) - 14:01, 13 September 2024
Budesonide (category Enones)
Budesonide, sold under the brand name Pulmicort, among others, is a steroid medication. It is available as an inhaler, nebulization solution, pill, nasal...
41 KB (3,282 words) - 05:55, 27 May 2024
Levonorgestrel (category Enones)
Levonorgestrel is a hormonal medication which is used in a number of birth control methods. It is combined with an estrogen to make combination birth control...
83 KB (7,907 words) - 06:09, 14 July 2024
eliminate water following the monooxidation by Fétizon's reagent to form an enone. Under differing structural conditions, [1,2] diols can form diketones in...
16 KB (1,734 words) - 08:59, 29 August 2023
Aldosterone (category Enones)
Aldosterone is the main mineralocorticoid steroid hormone produced by the zona glomerulosa of the adrenal cortex in the adrenal gland. It is essential...
32 KB (3,377 words) - 13:20, 24 January 2024
In the Saegusa–Ito oxidation, certain silyl enol ethers are oxidized to enones with palladium(II) acetate. Reacting a silyl enol ether with PhSCl, a good...
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isomerize via a [3,3]-sigmatropic reaction and following oxidation yield an enone, in a reaction known as the Babler oxidation: This type of oxidative transposition...
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Asymmetric nucleophilic epoxidation (section Enones)
(E)-enones have been most commonly epoxidized using either lanthanide/BINOL systems or a magnesium tartrate catalyst. (6) For alkyl aryl (E)-enones, both...
14 KB (1,634 words) - 16:11, 7 March 2021