Fulvalene (bicyclopentadienylidene) is the member of the fulvalene family with the molecular formula C10H8. It is of theoretical interest as one of the...
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A fulvalene is a hydrocarbon obtained by formally cross-conjugating two rings through a common exocyclic double bond. The name is derived from the similarly...
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Bis(fulvalene)diiron is the organoiron complex with the formula (C5H4-C5H4)2Fe2. Structurally, the molecule consists of two ferrous centers sandwiched...
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Thermoelectric battery (section Fulvalene diruthenium)
Telluride based batteries convert 15 to 20 percent of heat to energy. Fulvalene diruthenium promises greater efficiency, but is too expensive for commercial...
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Pauson and Thomas J. Kealy at Duquesne University attempted to prepare fulvalene ((C5H4)2) by oxidative dimerization of cyclopentadiene (C5H6). To that...
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exact mass: 128.0626 u) may refer to: Azulene Bicyclo[6.2.0]decapentaene Fulvalene Naphthalene This set index page lists chemical structure articles associated...
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at 237 to 254 nm forms small amounts of fulvene along with benzvalene. Fulvalene Methylenecyclopropene Nomenclature of Organic Chemistry : IUPAC Recommendations...
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development of molecular electronics. TTF is related to the hydrocarbon fulvalene, (C5H4)2, by replacement of four CH groups with sulfur atoms. Over 10...
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in the presence of ligands; in the presence of benzene, a fulvalene complex, μ(η5:η5-fulvalene)-di-(μ-hydrido)-bis(η5-cyclopentadienyltitanium), can be...
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stabilizing ligands, the Cp2ZrII fragment is unstable and dimerizes to form a fulvalene complex. In 1954, Wilkinson and Birmingham described zirconocene dihalides...
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of dichlorocarbene. Some other notable work include the synthesis of fulvalene, the discoveries of the Doering-LaFlamme allene synthesis and the Parikh-Doering...
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Calicene (category Fulvalenes)
Calicene or triapentafulvalene is a hydrocarbon of the fulvalene class with chemical formula C8H6, composed of a cyclopentadiene ring and a cyclopropene...
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Sesquifulvalene (category Fulvalenes)
Sesquifulvalene or pentaheptafulvalene is a hydrocarbon in the fulvalene class with chemical formula C12H10. It is composed of linked cyclopentadiene...
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substitution reactions of bimetallic coordination complexes with the fulvalene ligand. Tolman graduated with a Ph.D. in chemistry in 1987. He then conducted...
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cyclopentadienyl rings are coupled. Formally, biferrocene is derived from one fulvalene ligand, and biferrocenylene is derived from two. Biferrocene can easily...
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allene: Attempted synthesis of "titanocene", i.e. Ti(C5H5)2, produces a fulvalene complex. The titanocene dimer was recognised in the 1970s but not structurally...
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titanocene by reduction of titanocene dichloride affords complexes of fulvalene ligands. Bent metallocenes derived from pentamethylcyclopentadiene can...
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Pauson, and Miller et al. Kealy and Pauson were attempting to synthesize fulvalene through the oxidation of a cyclopentadienyl salt with anhydrous FeCl3...
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Triafulvalene (category Fulvalenes)
Triafulvalene or cyclopropenylidenecyclopropene is a fulvalene hydrocarbon with chemical formula C6H4, composed of two linked cyclopropene rings. Triafulvalene...
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commonly involves conversion between a naphthalene-like structure into a fulvalene-like structure, that is, two rings that share an edge vs two separate...
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dioxynaphthyl unit (in green) when the fulvalene unit is oxidized by application of a current. When the fulvalene is reduced back a metastable high conductance...
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(1986), "Synthetic and NMR spectroscopic investigations of fulvenes and fulvalenes" (PDF), Pure Appl. Chem., 58 (1): 55–66, doi:10.1351/pac198658010055 IUPAC...
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celebrates Bill Doering's well-known nickname and was chosen to rhyme with fulvalene, a molecule of great interest to the research group. Addison Ault (2001)...
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Ni(tmdt)2, Pt(tmdt)2, Pd(tmdt)2, Au(tmdt)2, The tmdt2− ion is based on fulvalene, but with the four atoms adjacent to the bridging double bond replaced...
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discovered the compound ferrocene by accident, while trying to prepare fulvalene. Their discovery revolutionized chemistry and created organometallic chemistry...
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[Fe(C5H5)2], was first synthesised in 1951 during an attempt to prepare the fulvalene (C 10H 8) by oxidative dimerization of cyclopentadiene; the resultant...
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