• Thumbnail for Fulvene
    Fulvene (pentafulvene) is a hydrocarbon with the formula (CH=CH)2C=CH2. It is a prototype of a cross-conjugated hydrocarbon. Fulvene is rarely encountered...
    3 KB (193 words) - 22:12, 3 September 2024
  • Thumbnail for Fulvenes
    Fulvenes are the class of hydrocarbon obtained by formally cross-conjugating one ring and methylidene through a common exocyclic double bond. The name...
    5 KB (464 words) - 08:14, 12 October 2024
  • exocyclic double bond attached. Methylenecyclopropene is the smallest of the fulvenes (a family of unstable, cyclic molecules, conjugated transversally with...
    3 KB (288 words) - 19:19, 27 October 2022
  • Benzene Benzvalene Bicyclopropenyl 1,2,3-Cyclohexatriene Dewar benzene Fulvene Prismane [3]Radialene 3-Methylidenepent-1-en-4-yne Hexadiyne 1,3-Hexadiyne...
    888 bytes (104 words) - 12:57, 3 June 2023
  • Thumbnail for Thermodynamic versus kinetic reaction control
    They were re-investigating a reaction between maleic anhydride and a fulvene first reported in 1929 by Otto Diels and Kurt Alder. They observed that...
    21 KB (2,751 words) - 02:06, 9 November 2023
  • Thumbnail for Benzvalene
    diethyl ether at −45 °C. It can also be formed in low yield (along with fulvene and Dewar benzene) by irradiation of benzene at 237 to 254 nm. The hydrocarbon...
    5 KB (404 words) - 13:47, 24 April 2023
  • Thumbnail for Tuck-in complex
    η4- and η6-fulvene complexes....
    4 KB (425 words) - 21:38, 27 September 2020
  • Thumbnail for Annulene
    ([22]-annulene) Wikimedia Commons has media related to Annulenes. Annulyne Circulene Fulvenes IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997)...
    5 KB (541 words) - 22:53, 14 October 2024
  • Thumbnail for Diels–Alder reaction
    die Anlagerung von Maleinsäure-anhydrid an arylierte Diene, Triene und Fulvene (Mitbearbeitet von Paul Pries)". Berichte der Deutschen Chemischen Gesellschaft...
    62 KB (7,092 words) - 16:10, 26 September 2024
  • been employed in the reaction include tropone and tropone derivatives, fulvenes, and cycloheptatriene cobalt complexes. [6+4] Cycloaddition is a thermally...
    9 KB (1,075 words) - 20:53, 22 July 2024
  • phenylthio radical 4985-62-0 C6H6 benzene 71-43-2 C6H6 benzvalene 659-85-8 C6H6 fulvene 497-20-1 C6H6Cl2Si phenyldichlorosilane 1631-84-1 C6H6Cl6 lindane 58-89-9...
    26 KB (28 words) - 18:13, 13 February 2024
  • macrocylic and acyclic triynes with Group 6 metal carbonyls. The formation of fulvene and benzene". J. Am. Chem. Soc. 106 (26): 8315. doi:10.1021/ja00338a063...
    18 KB (1,925 words) - 02:15, 18 April 2024
  • This is in contrast to non-alternant hydrocarbons, such as azulene and fulvene that have large dipole moments. The Hückel theory is more accurate for...
    45 KB (7,291 words) - 04:03, 23 June 2023
  • rDA are described below: Diene: furan, pyrrole > benzene > naphthalene > fulvene > cyclopentadiene > anthracene > butadiene Dienophile: N2 > CO2 > naphthalene...
    13 KB (1,538 words) - 22:24, 27 September 2024
  • Thumbnail for Mycena leaiana
    Anke T, Scherer A, Steglich W. (1990). "Leaianafulvene, a sesquiterpenoid fulvene derivative from cultures of Mycena leaiana". Phytochemistry 12: 3942–3944...
    9 KB (848 words) - 16:02, 10 January 2024
  • Thumbnail for Fulvalenes
    exocyclic double bond. The name is derived from the similarly structured fulvenes which lack one ring. Pentafulvalene (2) is also called simply fulvalene...
    2 KB (292 words) - 22:11, 3 September 2024
  • dienes, the larger ketene substituent is placed in the endo position. Fulvenes typically react in the ring, leaving the double bond intact. (6) Ketenes...
    9 KB (1,180 words) - 00:32, 24 August 2024
  • Thumbnail for Triafulvalene
    Neuenschwander, Markus (1986), "Synthetic and NMR spectroscopic investigations of fulvenes and fulvalenes" (PDF), Pure Appl. Chem., 58 (1): 55–66, doi:10.1351/pac198658010055...
    2 KB (152 words) - 17:13, 14 September 2024
  • Thumbnail for Fulvalene
    Perchlorofulvalene (C4Cl4C)2 is quite stable in contrast to fulvalene itself. Fulvenes, (CH=CH)2C=CH2 and substituted derivatives Tetrathiafulvalene, C2H2S2C=CS2C2H2...
    4 KB (320 words) - 15:47, 5 September 2023
  • Thumbnail for Rosenthal's reagent
    Complexes with Diaminoacetylenes: Formation of Unusual Metallacycles and Fulvene Complexes". Organometallics. 33 (7): 1774–1786. doi:10.1021/om500121p....
    45 KB (4,277 words) - 03:12, 23 October 2024
  • Thumbnail for Sesquifulvalene
    the π-Electronic Structure of Singlet, Triplet, and Quintet States of Fulvenes and Fulvalenes Using the Electron Localization Function". The Journal of...
    2 KB (184 words) - 16:52, 29 March 2023
  • of gem-dihalocyclopropanes—VI A novel synthesis of cyclopentadienes and fulvenes L. Skattebøl Tetrahedron Volume 23, Issue 3, 1967, Pages 1107-1117 doi:10...
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  • Thumbnail for Titanocene Y
    Particularly, lipophilic titanocene dichloride derivatives derived from fulvenes were synthesised in structural diversity and this led to the development...
    10 KB (1,111 words) - 20:25, 6 August 2024
  • Thumbnail for Johannes Thiele (chemist)
    condensation of ketones and aldehydes with cyclopentadiene as a route to fulvenes. He also recognized that these deeply colored species were related to but...
    6 KB (517 words) - 01:38, 31 August 2023