In organic chemistry, hydroboration refers to the addition of a hydrogen-boron bond to certain double and triple bonds involving carbon (C=C, C=N, C=O...

Hydroboration–oxidation reaction is a two-step hydration reaction that converts an alkene into an alcohol. The process results in the syn addition of...

many chemical transformations in organic chemistry — most importantly, hydroboration and carboboration. Most reactions transfer a nucleophilic boron substituent...

In chemistry, metal-catalysed hydroboration is a reaction used in organic synthesis. It is one of several examples of homogeneous catalysis. In 1975,...

It is a colorless waxy solid that is used in organic synthesis for hydroboration–oxidation reactions. Like most dialkyl boron hydrides, it has a dimeric...

ammonia borane as byproduct. The ratio depends on the conditions. In the hydroboration reaction, diborane also reacts readily with alkenes to form trialkylboranes...

Diborane reacts with alkenes to give alkylboranes, a process known as hydroboration: B2H6 + 2 CH2=CHR → 2 BH2(CH2CH2R) B2H6 + 4 CH2=CHR → 2 BH(CH2CH2R)2...

with B-H-B bridges. Diisopinocampheylborane was originally prepared by hydroboration of excess α-pinene with borane, but it is now more commonly generated...

borane–tetrahydrofuran may also be used. Hydroboration can be coupled with oxidation to give the hydroboration-oxidation reaction. In this reaction, the...

organoborane compound. This colourless solid is used in organic chemistry as a hydroboration reagent. The compound exists as a hydride-bridged dimer, which easily...

and, less rapidly, alkynes. Pinacolborane also affects catalyst-free hydroboration of aldehydes, ketones, and carboxylic acids. Pinacolborane is used in...

substitution with acids is not possible. In this case, one has to use the hydroboration–oxidation reaction, wherein the first step, the boron atom acts as electrophile...

align anti or outside of the orbitals depending on the reaction. The hydroboration reaction is a useful reaction to functionalize alkenes to alcohols....

be oxidized to form an alcohol. This two-step reaction is now called hydroboration-oxidation and is a reaction that converts alkenes into anti-Markovnikov...

drive the trans-hydroboration of alkynes. In 2016, McGough et al. were able to successfully accomplish metal-free trans-hydroboration with a variety of...

known and many are useful in organic synthesis. Many are produced from hydroboration, which employs diborane, B2H6, a simple borane chemical, or carboboration...

boron carbonitride ceramics from the borazine derivative copolymer via hydroboration". Inorganic Chemistry. 43 (16): 4796–8. doi:10.1021/ic035254a. PMID 15285647...

addition with same regiospecificity as a direct hydration reaction. Alkene hydroboration-oxidation Stereospecific: Can only be syn addition – hydrogen and hydroxyl...

reported acyclic amido germylene hydride was found to catalyze the hydroboration of a variety of aldehydes and ketones with the mild borane reagent HBpin...

catalyst and a base. The organoboron species is usually synthesized by hydroboration or carboboration, allowing for rapid generation of molecular complexity...

hydrofunctionalization reactions including hydroacylation, hydroboration, and hydrosilylation of alkenes. Hydroborations have been studied with catecholborane and pinacolborane...

secondary alcohol via alkene reduction and hydration is shown: The hydroboration-oxidation and oxymercuration-reduction of alkenes are more reliable...

complexes with Li+, Mg2+, and boranes. It is a popular solvent for hydroboration reactions and for organometallic compounds such as organolithium and...

alternative routes are available for producing alcohols, including the hydroboration–oxidation reaction, the oxymercuration–reduction reaction, the Mukaiyama...

These solutions, which are colorless, are used for reductions and hydroboration, reactions that are useful in synthesis of organic compounds. The use...

a range of applications, including biosensors. Her interests lie in hydroboration, organometallic chemistry, chiral materials and persistent carbenes...

molecule (S(CH3)2). It is a complexed borane reagent that is used for hydroborations and reductions. The advantages of BMS over other borane reagents, such...

across C≡C is general for silanes, boranes, and related hydrides. The hydroboration of alkynes gives vinylic boranes which oxidize to the corresponding...

Criegee rearrangement reactions, and also the oxidation step of the hydroboration–oxidation process. In 2009, an acidified bentonite clay was proven to...

behavior of diborane and its adducts, higher boranes participate in hydroboration. When boron hydrides add an alkyne, the carbon becomes incorporated...