Hydrosilylation, also called catalytic hydrosilation, describes the addition of Si-H bonds across unsaturated bonds. Ordinarily the reaction is conducted...

chlorosilanes. Another major method for the formation of Si-C bonds is hydrosilylation (also called hydrosilation). In this process, compounds with Si-H bonds...

process, which is a type of chemical vapor deposition process. Via hydrosilylation, trichlorosilane is a precursor to other useful organosilicon compounds:...

alkenylboranes and phosphines are beneficial for asymmetric Piers-type hydrosilylations of 1,2-dicarbonyl compounds and alpha-keto esters, giving high yield...

divinyl-containing disiloxane. This coordination complex is widely used in hydrosilylation catalysis. It is a colorless solid that is generally assumed to be...

complexes with silanes produces metal nanoparticle that catalyze the hydrosilylation reaction. BINAP-functionalized palladium nanoparticles and gold nanoparticles...

Corning, it catalyzes the addition of hydrosilanes to olefins, i.e. hydrosilylation. Early demonstration reactions used isopropanol solutions of trichlorosilane...

to their application for aziridination. Another common reaction is hydrosilylation, which dates back to the first use of PyBOX ligands. Other niche applications...

involving hydrogen gas and hydrosilanes. These include hydrogenations and hydrosilylations of alkenes. Rhodium metal, but not rhodium complexes, catalyzes the...

liquid at room temperature, triethylsilane is often used in studies of hydrosilylation catalysis. Richard T. Beresis, Jason S. Solomon, Michael G. Yang, Nareshkumar...

elaborated. Rather than polymerization, the alkene group can undergo a hydrosilylation reaction with siloxanes in the presence of chloroplatinic acid as catalyst...

borohydride. The asymmetric reduction of imines has been achieved by hydrosilylation using a rhodium-DIOP catalyst. Many systems have since been investigated...

laboratory-scale reactions. These including deoxygenation, hydrosilylation, and ionic hydrogenation. SIn hydrosilylation, the Si-H bond adds across multiple bonds in...

processes requiring a homogeneous catalyst include hydroformylation, hydrosilylation, hydrocyanation. For inorganic chemists, homogeneous catalysis is often...

ferrocene. Cobalt carbonyl (Co2(CO)8) is a catalyst in carbonylation and hydrosilylation reactions. Vitamin B12 (see below) is an organometallic compound found...

sp2-carbon atoms differ. The regioselectivity and stereoselectivity of hydrosilylation of 1-methylcyclohexene with chloro(methyl)silanes depends on the number...

and hydrosilylation of alkenes. Hydroborations have been studied with catecholborane and pinacolborane. It is also active for the hydrosilylation of alkenes...

tributyltin compounds. The reagent is employed in radical reductions, hydrosilylation and consecutive radical reactions. In organic synthesis, TMS group...

HSi(OC2H5)3. It is a colourless liquid used in precious metal-catalysed hydrosilylation reactions. The resulting triethoxysilyl groups are often valued for...

either olefin metathesis or by hydrosilylation. As an example, tetraallylsilane undergoes Pt-catalyzed hydrosilylation to form the core. This core was...

such as esterifications with anhydrides, the Baylis-Hillman reaction, hydrosilylations, tritylation, the Steglich rearrangement, Staudinger synthesis of β-lactams...

cycles. Important examples include hydrogenation, hydroformylation, hydrosilylation, hydrodesulfurization catalysts. Even certain enzymes, the hydrogenase...

non-coordinating anions have been used to catalyze hydrogenation, hydrosilylation, oligomerization, and the living polymerization of alkenes. The popularization...

acceptor). Related reactions entail "HX additions" where X = silyl (hydrosilylation) and CN (hydrocyanation). Most large-scale industrial hydrogenations...

1002/047084289X.rn00062 Revunova, K., & Nikonov, G. I. (2014). Base-Catalyzed Hydrosilylation of Ketones and Esters and Insight into the Mechanism. Chemistry-a European...

A hydrosilylation reaction, in which Si–H is added to an unsaturated substrate...

cycles. Recently, Krossing and coworkers reported a Ga(I) initiated hydrosilylation reaction, which opens up new windows for main group catalysis. Finally...

en route to the synthesis of other organoplatinum compound, such as hydrosilylation catalysts. It is also used as a precursor for forming platinum layers...

vinylorganometallic. Examples are hydroboration, hydroalumination, hydrosilylation and hydrozirconation. Elschenbroich, C. ”Organometallics” (2006) Wiley-VCH:...

in the Heck olefination chloroarenes is a success story. Asymmetric hydrosilylation of ketones to chiral secondary alcohols with good yields and excellent...