• Hydrosilylation, also called catalytic hydrosilation, describes the addition of Si-H bonds across unsaturated bonds. Ordinarily the reaction is conducted...
    8 KB (972 words) - 07:48, 27 August 2024
  • Thumbnail for Organosilicon chemistry
    chlorosilanes. Another major method for the formation of Si-C bonds is hydrosilylation (also called hydrosilation). In this process, compounds with Si-H bonds...
    25 KB (2,547 words) - 00:08, 6 April 2024
  • Thumbnail for Trichlorosilane
    process, which is a type of chemical vapor deposition process. Via hydrosilylation, trichlorosilane is a precursor to other useful organosilicon compounds:...
    8 KB (573 words) - 09:24, 28 September 2024
  • alkenylboranes and phosphines are beneficial for asymmetric Piers-type hydrosilylations of 1,2-dicarbonyl compounds and alpha-keto esters, giving high yield...
    23 KB (2,669 words) - 14:31, 20 September 2024
  • Thumbnail for Karstedt's catalyst
    divinyl-containing disiloxane. This coordination complex is widely used in hydrosilylation catalysis. It is a colorless solid that is generally assumed to be...
    5 KB (451 words) - 06:10, 24 February 2024
  • complexes with silanes produces metal nanoparticle that catalyze the hydrosilylation reaction. BINAP-functionalized palladium nanoparticles and gold nanoparticles...
    21 KB (2,337 words) - 10:50, 25 October 2023
  • Thumbnail for Chloroplatinic acid
    Corning, it catalyzes the addition of hydrosilanes to olefins, i.e. hydrosilylation. Early demonstration reactions used isopropanol solutions of trichlorosilane...
    11 KB (903 words) - 01:37, 11 August 2024
  • to their application for aziridination. Another common reaction is hydrosilylation, which dates back to the first use of PyBOX ligands. Other niche applications...
    20 KB (2,222 words) - 03:01, 9 February 2024
  • Thumbnail for Rhodium
    involving hydrogen gas and hydrosilanes. These include hydrogenations and hydrosilylations of alkenes. Rhodium metal, but not rhodium complexes, catalyzes the...
    32 KB (3,845 words) - 11:30, 30 October 2024
  • Thumbnail for Triethylsilane
    liquid at room temperature, triethylsilane is often used in studies of hydrosilylation catalysis. Richard T. Beresis, Jason S. Solomon, Michael G. Yang, Nareshkumar...
    3 KB (244 words) - 10:10, 6 July 2022
  • Thumbnail for Allyl glycidyl ether
    elaborated. Rather than polymerization, the alkene group can undergo a hydrosilylation reaction with siloxanes in the presence of chloroplatinic acid as catalyst...
    10 KB (930 words) - 13:44, 19 January 2024
  • Thumbnail for Imine
    borohydride. The asymmetric reduction of imines has been achieved by hydrosilylation using a rhodium-DIOP catalyst. Many systems have since been investigated...
    23 KB (2,633 words) - 01:56, 2 September 2024
  • laboratory-scale reactions. These including deoxygenation, hydrosilylation, and ionic hydrogenation. SIn hydrosilylation, the Si-H bond adds across multiple bonds in...
    8 KB (786 words) - 10:02, 17 May 2023
  • Thumbnail for Catalysis
    processes requiring a homogeneous catalyst include hydroformylation, hydrosilylation, hydrocyanation. For inorganic chemists, homogeneous catalysis is often...
    46 KB (5,235 words) - 10:42, 26 September 2024
  • Thumbnail for Cobalt
    ferrocene. Cobalt carbonyl (Co2(CO)8) is a catalyst in carbonylation and hydrosilylation reactions. Vitamin B12 (see below) is an organometallic compound found...
    116 KB (11,882 words) - 02:46, 30 October 2024
  • Thumbnail for 1-Methylcyclohexene
    sp2-carbon atoms differ. The regioselectivity and stereoselectivity of hydrosilylation of 1-methylcyclohexene with chloro(methyl)silanes depends on the number...
    6 KB (418 words) - 00:36, 6 September 2024
  • Thumbnail for Wilkinson's catalyst
    and hydrosilylation of alkenes. Hydroborations have been studied with catecholborane and pinacolborane. It is also active for the hydrosilylation of alkenes...
    13 KB (1,208 words) - 21:25, 19 August 2024
  • Thumbnail for Trimethylsilyl group
    tributyltin compounds. The reagent is employed in radical reductions, hydrosilylation and consecutive radical reactions. In organic synthesis, TMS group...
    9 KB (1,016 words) - 00:04, 19 July 2024
  • Thumbnail for Triethoxysilane
    HSi(OC2H5)3. It is a colourless liquid used in precious metal-catalysed hydrosilylation reactions. The resulting triethoxysilyl groups are often valued for...
    2 KB (160 words) - 02:28, 26 August 2023
  • Thumbnail for Ferrocene-containing dendrimers
    either olefin metathesis or by hydrosilylation. As an example, tetraallylsilane undergoes Pt-catalyzed hydrosilylation to form the core. This core was...
    3 KB (349 words) - 19:36, 14 November 2020
  • such as esterifications with anhydrides, the Baylis-Hillman reaction, hydrosilylations, tritylation, the Steglich rearrangement, Staudinger synthesis of β-lactams...
    8 KB (671 words) - 22:48, 5 August 2024
  • Thumbnail for Hydride
    cycles. Important examples include hydrogenation, hydroformylation, hydrosilylation, hydrodesulfurization catalysts. Even certain enzymes, the hydrogenase...
    21 KB (2,283 words) - 16:04, 30 September 2024
  • non-coordinating anions have been used to catalyze hydrogenation, hydrosilylation, oligomerization, and the living polymerization of alkenes. The popularization...
    9 KB (898 words) - 14:31, 25 August 2024
  • acceptor). Related reactions entail "HX additions" where X = silyl (hydrosilylation) and CN (hydrocyanation). Most large-scale industrial hydrogenations...
    8 KB (888 words) - 13:28, 23 July 2024
  • Thumbnail for Polymethylhydrosiloxane
    1002/047084289X.rn00062 Revunova, K., & Nikonov, G. I. (2014). Base-Catalyzed Hydrosilylation of Ketones and Esters and Insight into the Mechanism. Chemistry-a European...
    3 KB (270 words) - 20:06, 21 October 2023
  • A hydrosilylation reaction, in which Si–H is added to an unsaturated substrate...
    42 KB (5,607 words) - 22:19, 30 May 2024
  • cycles. Recently, Krossing and coworkers reported a Ga(I) initiated hydrosilylation reaction, which opens up new windows for main group catalysis. Finally...
    9 KB (1,063 words) - 21:41, 27 January 2023
  • Thumbnail for Trimethylplatinum iodide
    en route to the synthesis of other organoplatinum compound, such as hydrosilylation catalysts. It is also used as a precursor for forming platinum layers...
    13 KB (1,206 words) - 12:08, 1 June 2024
  • vinylorganometallic. Examples are hydroboration, hydroalumination, hydrosilylation and hydrozirconation. Elschenbroich, C. ”Organometallics” (2006) Wiley-VCH:...
    955 bytes (102 words) - 10:27, 7 February 2020
  • in the Heck olefination chloroarenes is a success story. Asymmetric hydrosilylation of ketones to chiral secondary alcohols with good yields and excellent...
    11 KB (1,172 words) - 05:31, 25 July 2022