common nonclassical ion structure in the form of a bicyclobutonium ion. Brown, H. C. (with commentary by P. v. R. Schleyer) The Nonclassical Ion Problem;...
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2-Norbornyl cation (section Non-classical ions)
Prakash, G. K. S.; Saunders, M. (1983). "Conclusion of the classical-nonclassical ion controversy based on the structural study of the 2-norbornyl cation"...
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reactions. The discovery of hypercoordinated carbocations fueled the nonclassical ion controversy of the 1950s and 60s. Due to the slow timescale of 1H-NMR...
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Particularly fast reactions can occur by neighbour group participation, with nonclassical ions as intermediates or transition states. For certain nucleophiles, solvolysis...
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trivalent (classical) carbenium ions from three-center bound penta- or tetracoordinated (nonclassical) carbonium ions. Role of carbocations in electrophilic...
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trivalent (classical) carbenium ions from three-center bound penta- of tetracoordinated (nonclassical) carbonium ions. Role of carbocations in electrophilic...
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Carbocation (section Carbonium ions)
trivalent (classical) carbenium ions from three-center bound penta- of tetracoordinated (nonclassical) carbonium ions. Role of carbocations in electrophilic...
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carbonium ion is a cation that has a pentacoordinated carbon atom. They are a type of carbocation. In older literature, the name "carbonium ion" was used...
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the leaving group. Corresponding intermediates are referred to a nonclassical ions, with the 2-norbornyl system as the most well known case. IUPAC definition...
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ion control scheme that maps quantum information between two co-trapped ion species. Quantum logic operations allow desirable properties of each ion species...
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Education. pp. 183–184. ISBN 81-7758-296-8. Brown, Herbert C. (1977). The Nonclassical Ion Problem. New York: Springer. ISBN 978-1-4613-4120-8. Olah, G. A.; Liang...
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molecule of ethane (C 2H 6) minus one hydride ion (H− ). It is a carbocation; more specifically, a nonclassical carbocation. Ethenium has been observed in...
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Congenital adrenal hyperplasia due to 21-hydroxylase deficiency (section Late onset (nonclassical) CAH)
that from the clinician's perspective, nonclassical CAH is not an intersex condition. Including nonclassical CAH in intersex prevalence estimates has...
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Herbert C. Brown, a Nobel laureate at Purdue University, researching on Nonclassical Ion Problem, one of the favorite topics of Brown. On his return to India...
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is a type of atomic clock with laser cooled single ions confined together in an electromagnetic ion trap. Developed in 2010 by physicists at the U.S. National...
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thermal equilibrium ground states; therefore they are described below as nonclassical states of matter. Solids can be transformed into liquids by melting,...
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Secretion (section Nonclassical secretion)
ER-Golgi pathway. These are secreted through various nonclassical pathways. At least four nonclassical (unconventional) protein secretion pathways have been...
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automata. Physics portal Atomic, molecular, and optical physics Attophysics Nonclassical light Optomechanics Quantum control Optical phase space Optical physics...
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although systems that involve electron-deficient bonding, including nonclassical carbocations, lithium and boron clusters, and hypervalent centers require...
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39.691. Diedrich, Frank; Walther, Herbert (1987). "Nonclassical Radiation of a Single Stored Ion". Phys. Rev. Lett. 58 (3): 203–206. Bibcode:1987PhRvL...
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{\displaystyle g^{(2)}(0)} . Sub-Poissonian fields violate this, and hence are nonclassical in the sense that there can be no underlying positive definite probability...
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Figueiredo, Renata Marcia; Suppo, Jean-Simon; Campagne, Jean-Marc (2016). "Nonclassical Routes for Amide Bond Formation". Chemical Reviews. 116 (19): 12029–12122...
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groups are bonded to the boron atoms, causing the compound to adopt a nonclassical, delocalized structure. As the name suggests, trishomoaromatics are defined...
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include singlet oxygen (1O2), hydroxyl radicals (•OH) and superoxide (O2−) ions. They can interact with cellular components including unsaturated lipids...
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name (help); |journal= ignored (help) Nickel, W (2003). "The Mystery of nonclassical protein secretion, a current view on cargo proteins and potential export...
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sub-shot-noise[clarification needed] quantum correlations. Negative energy Nonclassical light Optical phase space Quantum optics Squeeze operator Loudon, Rodney...
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= Fe, Ru, Os). Nonclassical describes those carbonyl complexes where νCO is higher than that for free carbon monoxide. In nonclassical CO complexes, the...
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structurally related to THC, but endocannabinoids are fatty acid derivatives. Nonclassical synthetic cannabinoids (cannabimimetics) include aminoalkylindoles, 1...
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visualized. Excess heme is converted in macrophages to Biliverdin and ferrous ions by the enzyme HO-1. Biliverdin formed further gets converted to Bilirubin...
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2nd ed. (Wiley 1987), p.113 Nikonov, G. I. (2005). "Recent advances in nonclassical interligand SiH interactions". Adv. Organomet. Chem. 53: 217–309. doi:10...
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