Organoaluminium chemistry is the study of compounds containing bonds between carbon and aluminium. It is one of the major themes within organometallic...
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organosodium chemistry, organomagnesium chemistry, organoaluminium chemistry, organosilicon chemistry Period 4 elements: organocalcium chemistry, organoscandium...
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cyclotrimerization of butadiene with titanium tetrachloride and an organoaluminium co-catalyst: Cyclotrimerization of formaldehyde affords 1,3,5-Trioxane:...
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as pink, bonded to carbon in black, and hydrogen as white in Organoaluminium chemistry Fatty acids made of long chains of carbon Carbon source (biology)...
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Karl Ziegler (category Nobel laureates in Chemistry)
1898 – 12 August 1973) was a German chemist who won the Nobel Prize in Chemistry in 1963, with Giulio Natta, for work on polymers. The Nobel Committee...
23 KB (2,670 words) - 13:41, 15 December 2024
Dimerization (redirect from Dimerization (chemistry))
In chemistry, dimerization is the process of joining two identical or similar molecular entities by bonds. The resulting bonds can be either strong or...
12 KB (1,298 words) - 04:28, 1 January 2025
aluminium hydride is a powerful reducing agent used in organic chemistry. Organoaluminiums are used as Lewis acids and co-catalysts. Methylaluminoxane is...
137 KB (14,842 words) - 07:50, 30 December 2024
RSnCl3 A related method involves redistribution of tin halides with organoaluminium compounds.: 45–47 In principle, alkyltin halides can be formed from...
24 KB (2,623 words) - 18:21, 19 September 2024
Useful redistribution reactions are found in organoaluminium, organoboron, and organosilicon chemistry. BCl3 + 2 B(C2H5)3 → 3 BCl(C2H5)2 In another example...
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ZACA reaction (category Organometallic chemistry)
sterically hindered double bond is attacked selectively. Organoaluminium chemistry Organozirconium chemistry Indenyl effect Negishi, Ei-ichi (2010). "Discovery...
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Gallium (section Aqueous chemistry)
not form bridged dimers as organoaluminium compounds do. Organogallium compounds are also less reactive than organoaluminium compounds. They do form stable...
76 KB (9,063 words) - 00:57, 23 December 2024
Triethylaluminium (category Organoaluminium compounds)
Triethylaluminium is one of the simplest examples of an organoaluminium compound. Despite its name the compound has the formula Al2(C2H5)6 (abbreviated...
12 KB (1,018 words) - 18:30, 26 August 2024
Trimethylaluminium (category Organoaluminium compounds)
Trimethylaluminium is one of the simplest examples of an organoaluminium compound. Despite its name it has the formula Al2(CH3)6 (abbreviated as Al2Me6...
11 KB (883 words) - 13:36, 19 October 2024
Diisobutylaluminium hydride (category Organoaluminium compounds)
formula (i-Bu2AlH)2, where i-Bu represents isobutyl (-CH2CH(CH3)2). This organoaluminium compound is a reagent in organic synthesis. Like most organoaluminum...
8 KB (618 words) - 16:37, 4 December 2024
Olefin metathesis (category Organometallic chemistry)
often prepared by in-situ activation of a metal halide (MClx) using organoaluminium or organotin compounds, e.g. combining MClx–EtAlCl2. A typical catalyst...
39 KB (4,095 words) - 18:54, 28 November 2024
respectively. Lithium aluminium hydride (LAH) is widely used in organic chemistry as a reducing agent. It is more powerful than the related reagent sodium...
35 KB (3,057 words) - 14:36, 12 July 2024
Triisobutylaluminium (category Organoaluminium compounds)
Triisobutylaluminium (TiBA) is an organoaluminium compound with the formula Al(CH2CH(CH3)2)3. This colorless pyrophoric liquid is mainly used to make...
4 KB (344 words) - 18:36, 26 August 2024
These catalysts are activated with special co-catalysts containing an organoaluminium compound such as Al(C2H5)3 and the second type of a modifier. The catalysts...
50 KB (5,823 words) - 13:26, 2 December 2024
Methylaluminoxane (category Polymer chemistry)
Methylaluminoxane, commonly called MAO, is a mixture of organoaluminium compounds with the approximate formula (Al(CH3)O)n. It is usually encountered...
7 KB (627 words) - 21:56, 1 December 2024
Aluminium acetate (category Set index articles on chemistry)
Emeléus HJ, Nyholm R (1973). The Chemistry of Aluminium, Gallium, Indium and Thallium : Comprehensive Inorganic Chemistry. Saint Louis: Elsevier Science...
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ethylaluminium sesquichloride, a precursor to polymers and other useful organoaluminium compounds. Chloroethane is used to convert cellulose to ethylcellulose...
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these catalysts are prepared by treating titanium chlorides with organoaluminium compounds, such as triethylaluminium. In some cases, the catalyst is...
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catalysis. The precatalysts, e.g. titanium trichloride, are activated by organoaluminium compounds, which function as catalyst activators. Metal oxides are...
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the synthesis of decamethyltitanocene dichloride. In the presence of organoaluminium compounds and other additives, it catalyzes the polymerization of alkenes...
3 KB (200 words) - 23:34, 20 February 2023
coordination complexes such as vanadium(III) acetylacetonate with organoaluminium activators. Synthesis of Organometallic Compounds: A Practical Guide...
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acetylacetonate with organoaluminium activators. Titanium compounds Chromium compounds Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements...
16 KB (1,842 words) - 09:59, 21 June 2024
Aluminylene (category Organoaluminium compounds)
demonstrated that the N-aluminylene could act as an important precursor to organoaluminium compounds. In these reactions, the aluminylene performs cycloaddition...
16 KB (1,789 words) - 09:21, 16 July 2024
C14H10E2. Electrophiles include ketones, CO2, organotin chlorides, and organoaluminium chlorides. Ethylene inserts into one Mg-C bond. Hydrogen induces release...
3 KB (198 words) - 00:59, 25 September 2023
Tributyltin azide (category Reagents for organic chemistry)
tributyltin azide has been replaced by the less toxic trioctyltin azide and organoaluminium azides. Tributyl tin compounds are highly toxic and have penetrating...
4 KB (182 words) - 01:15, 4 May 2024
Ethylaluminium sesquichloride (category Organoaluminium compounds)
Ethylaluminium sesquichloride, also called EASC, is an industrially important organoaluminium compound used primarily as a precursor to triethylaluminium and as...
5 KB (466 words) - 18:38, 26 August 2024