• Thumbnail for Pentamethylcyclopentadiene
    1,2,3,4,5-Pentamethylcyclopentadiene is a cyclic diene with the formula C5(CH3)5H, often written C5Me5H, where Me is CH3. It is a colorless liquid. 1,2...
    11 KB (841 words) - 13:04, 24 August 2024
  • refer to: Adamantane Camphene Carene Limonene Myrcene Ocimene Pentamethylcyclopentadiene Phellandrene Pinenes alpha-Pinene beta-Pinene Sabinene Syntin...
    479 bytes (68 words) - 08:41, 4 October 2023
  • Cyclopentadienone Di-tert-butylcyclopentadiene Methylcyclopentadiene Pentamethylcyclopentadiene Pentacyanocyclopentadiene Most of these substituted cyclopentadienes...
    13 KB (1,040 words) - 05:40, 13 August 2024
  • Thumbnail for Decamethyltitanocene dichloride
    with the formula Cp*2TiCl2 (where Cp* is C5(CH3)5, derived from pentamethylcyclopentadiene). It is a red solid that is soluble in nonpolar organic solvents...
    3 KB (274 words) - 20:10, 6 August 2024
  • Thumbnail for Cyclopentadienyl complex
    have been commercialized for the production of polypropylene. Pentamethylcyclopentadiene gives rise to pentamethylcyclopentadienyl (Cp*) complexes. These...
    8 KB (881 words) - 20:56, 19 February 2024
  • Thumbnail for Decamethylzirconocene dichloride
    with the formula Cp*2ZrCl2 (where Cp* is C5(CH3)5, derived from pentamethylcyclopentadiene). It is a pale yellow, moisture sensitive solid that is soluble...
    3 KB (197 words) - 20:10, 6 August 2024
  • Thumbnail for Methylcyclopentadiene
    spectra of some [(η5-C5H4Me)Fe(CO)(L)I] complexes". J. Organomet. Chem. 339 (3): 339–343. doi:10.1016/S0022-328X(00)99395-1. Pentamethylcyclopentadiene...
    5 KB (285 words) - 08:55, 2 September 2024
  • unusual rearrangement reaction with hydrohalic acids to form a pentamethylcyclopentadiene derivative, and consequently can be used as a starting material...
    16 KB (1,593 words) - 20:34, 24 September 2024
  • Thumbnail for Decamethylsilicocene
    as [HOEt 2][B(C 6F 5) 4]. Upon protonation, one equivalent of pentamethylcyclopentadiene is eliminated to produce the pentamethylcyclopentadienylsilicon(II)...
    10 KB (1,185 words) - 20:57, 22 April 2024
  • Thumbnail for Dewar benzene
    potassium tetrachloroplatinate results in the formation of a pentamethylcyclopentadiene complex, [(η4-Cp*H)PtCl2], indicating that the rhodium and iridium...
    21 KB (1,785 words) - 16:41, 21 October 2022
  • Thumbnail for Rhodium(III) chloride
    produced. For example, treating hydrated rhodium trichloride with pentamethylcyclopentadiene in hot methanol leads to the precipitation of solid pentamethylcyclopentadienyl...
    19 KB (1,917 words) - 17:56, 26 July 2024
  • Thumbnail for Pentamethylcyclopentadienyl iridium dichloride dimer
    prepared by the reaction of hydrated iridium trichloride and pentamethylcyclopentadiene in hot methanol, from which the product precipitates 2 Cp*H +...
    6 KB (405 words) - 01:46, 22 June 2024
  • complexes of fulvalene ligands. Bent metallocenes derived from pentamethylcyclopentadiene can undergo reactions involving the methyl groups. For example...
    9 KB (944 words) - 02:38, 16 December 2023
  • Thumbnail for Decamethylferrocene
    Decamethylferrocene is prepared in the same manner as ferrocene from pentamethylcyclopentadiene. This method can be used to produce other decamethylcyclopentadienyl...
    7 KB (603 words) - 09:15, 29 June 2024
  • Thumbnail for Pentamethylcyclopentadienyl ruthenium dichloride dimer
    prepared by the reaction of hydrated ruthenium trichloride with pentamethylcyclopentadiene. 2 Cp*H + 2 RuCl3·3H2O → [Cp*RuCl2]2 + 2 HCl + 6 H2O The reaction...
    7 KB (536 words) - 17:18, 18 June 2024
  • molecule. AlCp*, consisting of aluminium (I) bonded with the pentamethylcyclopentadiene anion ((CCH3)5−), was first synthesized in 1991 by Dohmier et...
    16 KB (1,776 words) - 09:41, 11 April 2024
  • For this superatom, a mixture of aluminium atoms complexed with pentamethylcyclopentadiene (Cp*) and copper atoms complexed with mesitylene (Mes) were combined...
    4 KB (477 words) - 12:30, 9 December 2022
  • Thumbnail for Jaqueline Kiplinger
    coordination polymers can be formed. (C5Me5)2Th(N3)2 utilizes pentamethylcyclopentadiene to form polymers with two bridging azide groups, while...
    15 KB (1,486 words) - 07:19, 6 May 2024
  • Thumbnail for Pentamethylcyclopentadienyl rhodium dichloride dimer
    prepared by the reaction of rhodium trichloride trihydrate and pentamethylcyclopentadiene in hot methanol, from which the product precipitates: 2 C5(CH3)5H...
    10 KB (739 words) - 05:31, 22 June 2024
  • stable trivalent state. When Sm(III) is complexed with C 5Me 5 (pentamethylcyclopentadiene) to give the compound (C 5Me 5) 3Sm, this trivalent species has...
    5 KB (663 words) - 21:51, 12 June 2022
  • such as the reaction of europium and pentamethylcyclopentadiene to generate light orange bis(pentamethylcyclopentadiene) europium; and the reaction between...
    42 KB (4,438 words) - 16:44, 19 February 2024
  • Thumbnail for Organotantalum chemistry
    Cp2TaH3. More soluble and better developed are derivatives of pentamethylcyclopentadiene such as Cp*TaCl4, Cp*2TaCl2, and Cp*2TaH3. Reduction of TaCl5...
    11 KB (1,150 words) - 14:13, 22 June 2024
  • complex followed by further functionalization. Derivatives of pentamethylcyclopentadiene are also known, such as (C5Me5)2NbH3. Niobium carbonyls supported...
    9 KB (906 words) - 09:57, 20 June 2022
  • Thumbnail for Germylene
    stabilization of this p-orbital is usually realized by coordination of a pentamethylcyclopentadiene (Cp*) ligand or of nitrogen (N), oxygen (O) or phosphorus (P)...
    31 KB (3,022 words) - 10:38, 24 August 2023
  • Thumbnail for Rhodocene
    tris(acetone) complex [(η5-C5Me5)Rh(Me2CO)3](BF4)2 by reaction with pentamethylcyclopentadiene, and the analogous iridium synthesis is also known. Decaisopropylrhodicnium...
    76 KB (7,181 words) - 14:16, 20 September 2024
  • phosphaalumens and arsaalumens with Al(I) precursors, [Al(I)Cp*]4 (Cp* = pentamethylcyclopentadiene). Reacting [Al(I)Cp*]4 with DipTer-AsPMe3 or DipTer-AsPMe3 at...
    30 KB (3,100 words) - 04:52, 22 April 2024