• Thumbnail for Nucleophilic aromatic substitution
    A nucleophilic aromatic substitution (SNAr) is a substitution reaction in organic chemistry in which the nucleophile displaces a good leaving group, such...
    11 KB (1,298 words) - 19:19, 30 July 2024
  • Radical-nucleophilic aromatic substitution or SRN1 in organic chemistry is a type of substitution reaction in which a certain substituent on an aromatic...
    4 KB (454 words) - 19:31, 27 October 2022
  • Thumbnail for Radical substitution
    In organic chemistry, a radical-substitution reaction is a substitution reaction involving free radicals as a reactive intermediate. The reaction always...
    3 KB (351 words) - 01:58, 22 March 2024
  • Thumbnail for Aromatic compound
    due to high C:H ratio Undergo electrophilic substitution reactions and nucleophilic aromatic substitutions Arenes are typically split into two categories...
    21 KB (2,098 words) - 10:35, 24 July 2024
  • substitution include, nucleophilic acyl substitution, and nucleophilic aromatic substitution. Acyl substitution occurs when a nucleophile attacks a carbon that...
    12 KB (1,456 words) - 21:30, 14 April 2024
  • Sandmeyer reaction (category Substitution reactions)
    salts as reagents or catalysts. It is an example of a radical-nucleophilic aromatic substitution. The Sandmeyer reaction provides a method through which...
    16 KB (1,738 words) - 23:46, 1 December 2023
  • Nucleophilic acyl substitution (SNAcyl) describes a class of substitution reactions involving nucleophiles and acyl compounds. In this type of reaction...
    25 KB (3,012 words) - 11:17, 17 April 2024
  • oxygen radical and a carboxylate. Another example is Kolbe electrolysis. Radical-nucleophilic aromatic substitution is a special case of nucleophilic aromatic...
    5 KB (677 words) - 00:02, 31 January 2024
  • Thumbnail for Aromaticity
    chemistry of the molecule. Aromatic compounds undergo electrophilic aromatic substitution and nucleophilic aromatic substitution reactions, but not electrophilic...
    22 KB (2,764 words) - 21:10, 20 June 2024
  • as instances of nucleophilic aromatic substitution,[citation needed] because generating the aryl radical requires a strong (radical) leaving group.: 686–687 ...
    10 KB (893 words) - 21:11, 23 April 2024
  • Thumbnail for Meerwein arylation
    Meerwein arylation (category Substitution reactions)
    view ranks as a radical-nucleophilic aromatic substitution. In a general scope a Meerwein arylation is any reaction between an aryl radical and an alkene...
    5 KB (540 words) - 11:53, 30 June 2023
  • Jun-An; Cahard, Dominique (September 2007). "Strategies for nucleophilic, electrophilic, and radical trifluoromethylations". Journal of Fluorine Chemistry....
    43 KB (4,064 words) - 06:38, 27 April 2024
  • are nucleophilic in nature. This character is also seen in amino radicals, which can be considered to be nucleophilic species. The amino radical only...
    10 KB (1,051 words) - 07:47, 25 July 2024
  • Thumbnail for Nitro compound
    of nitro groups in aromatic compounds retards electrophilic aromatic substitution but facilitates nucleophilic aromatic substitution. Nitro groups are...
    17 KB (1,766 words) - 02:42, 22 May 2024
  • Thumbnail for Chemical reaction
    hydrocarbons, and rarely in aromatic hydrocarbon. The latter have high electron density and enter nucleophilic aromatic substitution only with very strong electron...
    66 KB (8,031 words) - 09:58, 12 July 2024
  • hovercraft SR N1 class, a class of locomotives Radical-nucleophilic aromatic substitution (SRN1), a type of substitution reaction in organic chemistry This disambiguation...
    260 bytes (67 words) - 01:39, 9 May 2011
  • Thumbnail for Smiles rearrangement
    after British chemist Samuel Smiles. It is an intramolecular, nucleophilic aromatic substitution of the type: where X in the arene compound can be a sulfone...
    3 KB (372 words) - 23:41, 28 January 2023
  • Thumbnail for Nitroxide-mediated radical polymerization
    consisting of a one-electron reduction of a nitroxide radical in metallic sodium to yield a nucleophilic nitroxide. The nitroxide nucleophile is then added...
    11 KB (1,636 words) - 08:50, 30 December 2023
  • Thumbnail for Pyridine
    Pyridine (category Aromatic bases)
    resembles nitrobenzene. Correspondingly pyridine is more prone to nucleophilic substitution, as evidenced by the ease of metalation by strong organometallic...
    76 KB (7,637 words) - 04:04, 15 July 2024
  • Thumbnail for Functional group
    compounds, haloalkanes readily undergo nucleophilic substitution reactions or elimination reactions. The substitution on the carbon, the acidity of an adjacent...
    31 KB (1,230 words) - 05:51, 9 August 2024
  • named reaction in organic chemistry. It is a nucleophilic radical substitution to an electron deficient aromatic compound, most commonly the introduction...
    7 KB (786 words) - 03:24, 15 September 2023
  • Thumbnail for Organic reaction
    (2) radical, and (3) pericyclic. Polar reactions are characterized by the movement of electron pairs from a well-defined source (a nucleophilic bond...
    14 KB (1,182 words) - 20:28, 22 July 2024
  • the transformation. K. C. Nicolaou labels the cascades as nucleophilic/electrophilic, radical, pericyclic or transition-metal-catalyzed, based on the mechanism...
    26 KB (2,826 words) - 18:23, 28 May 2024
  • used in Vietnam SR.N6, a longer SR.N5 SRN1 mechanism, a radical-nucleophilic aromatic substitution in organic chemistry Salem Radio Network, a United States-based...
    1 KB (183 words) - 01:24, 23 March 2022
  • Thumbnail for Ether
    intramolecular nucleophilic substitution of a halohydrin. Many ethers, ethoxylates and crown ethers, are produced from epoxides. Nucleophilic displacement...
    19 KB (1,835 words) - 03:40, 19 May 2024
  • Thumbnail for Isatin
    reactions, such as N-substitutions, electrophilic aromatic substitution at positions C-5 and C-7 of the phenyl ring, nucleophilic additions onto the C-3...
    17 KB (1,619 words) - 02:17, 13 July 2024
  • Thumbnail for Haloalkane
    alkylation, Gabriel synthesis and Delepine reaction, by undergoing nucleophilic substitution with potassium phthalimide or hexamine respectively, followed...
    20 KB (2,413 words) - 13:06, 14 April 2024
  • Thumbnail for Carbon nanotube chemistry
    with trimethoxysilane and hexaphenyldisilane. Hirsch et al. conducted nucleophilic additions with organolithium and organomagnesium compounds onto carbon...
    34 KB (3,689 words) - 19:31, 12 April 2024
  • have high pKa's and react with weak Lewis acids. with regards to nucleophilic substitution reactions, electron-rich species are relatively strong nucleophiles...
    4 KB (421 words) - 17:13, 29 March 2024
  • Thumbnail for Tolyl group
    coupling reactions. Tolyl sulfonates are excellent leaving groups in nucleophilic substitutions, for this reason, they are commonly generated as intermediaries...
    2 KB (157 words) - 21:24, 7 January 2023