• Thumbnail for Rhodium(III) chloride
    Rhodium(III) chloride refers to inorganic compounds with the formula RhCl3(H2O)n, where n varies from 0 to 3. These are diamagnetic red-brown solids....
    19 KB (1,917 words) - 17:56, 26 July 2024
  • Thumbnail for Wilkinson's catalyst
    saturated Ir(III) complex that is not catalytically active. Wilkinson's catalyst is usually obtained by treating rhodium(III) chloride hydrate with an...
    13 KB (1,208 words) - 21:25, 19 August 2024
  • Thumbnail for Iridium(III) chloride
    iridium(III) chloride. Hydrated iridium trichloride is obtained by heating hydrated iridium(III) oxide with hydrochloric acid. Like the related rhodium compound...
    10 KB (784 words) - 12:54, 5 November 2024
  • Thumbnail for Dichlorotetrakis(pyridine)rhodium(III) chloride
    Dichlorotetrakis(pyridine)rhodium(III) chloride is the chloride salt of the coordination complex with the formula [RhCl2(pyridine)4]+. Various hydrates...
    3 KB (191 words) - 14:50, 19 August 2024
  • Thumbnail for Rhodium
    available in an anhydrous form, which is somewhat refractory. Other rhodium(III) chlorides include sodium hexachlororhodate, Na3RhCl6, and pentaamminechlororhodium...
    32 KB (3,845 words) - 09:55, 6 November 2024
  • Thumbnail for Rhodium carbonyl chloride
    Rhodium carbonyl chloride is an organorhodium compound with the formula Rh2Cl2(CO)4. It is a red-brown volatile solid that is soluble in nonpolar organic...
    5 KB (490 words) - 17:19, 18 June 2024
  • Thumbnail for Cobalt(II) chloride
    Cobalt(II) chloride is an inorganic compound, a salt of cobalt and chlorine, with the formula CoCl 2. The compound forms several hydrates CoCl 2·nH 2O...
    21 KB (2,143 words) - 21:25, 19 November 2024
  • – ReF6 Rhodium hexafluoride – RhF6 Rhodium pentafluoride – Rh4F20 Rhodium(III) chloride – RhCl3 Rhodium(III) hydroxide – Rh(OH)3 Rhodium(III) iodide...
    119 KB (8,735 words) - 18:51, 11 November 2024
  • Thumbnail for Rhodium(III) perchlorate
    rhodium(III) chloride and perchloric acid at elevated temperatures: [Rh(H2O)6]Cl3 + 3 HClO4 → [Rh(H2O)6](ClO4)3 + 3 HCl The reaction of rhodium(III)...
    2 KB (151 words) - 23:05, 18 March 2024
  • Thumbnail for Rhodium(III) bromide
    prepare rhodium bromide complexes. Rhodium bromides are similar to the chlorides, but have attracted little academic or commercial attention. Rhodium(III) bromide...
    3 KB (220 words) - 06:40, 17 July 2024
  • Thumbnail for Ruthenium(III) chloride
    Ruthenium(III) chloride is the chemical compound with the formula RuCl3. "Ruthenium(III) chloride" more commonly refers to the hydrate RuCl3·xH2O. Both...
    17 KB (1,662 words) - 06:08, 30 January 2024
  • Thumbnail for Pentamethylcyclopentadienyl rhodium dichloride dimer
    produced by a side reaction. This rhodium(III) dimer can be reduced with zinc in the presence of CO to produce the rhodium(I) complex [Cp*Rh(CO)2]. Reductive...
    10 KB (739 words) - 05:31, 22 June 2024
  • Thumbnail for Rhodium(II) acetate
    transition metal carboxylate complex. Rhodium(II) acetate is usually prepared by the heating of hydrated rhodium(III) chloride in a methanol-acetic acid mixture...
    5 KB (378 words) - 18:56, 5 July 2024
  • Thumbnail for Cyclooctadiene rhodium chloride dimer
    Cyclooctadiene rhodium chloride dimer is the organorhodium compound with the formula Rh2Cl2(C8H12)2, commonly abbreviated [RhCl(COD)]2 or Rh2Cl2(COD)2...
    5 KB (333 words) - 17:18, 18 June 2024
  • containing functional groups via hydrogenolysis. An aqueous solution of rhodium chloride, chloroplatinic acid, and sodium nitrate is evaporated and then fused...
    4 KB (404 words) - 15:02, 17 June 2023
  • Thumbnail for Pentaamminechlororhodium dichloride
    purification of rhodium from its ores. As shown by X-ray crystallography, the salt consists of the octahedral complex [RhCl(NH3)5]2+ and two chloride counterions...
    3 KB (239 words) - 17:16, 23 August 2024
  • meitnerium, the GSI attempted sublimation of the rhodium compounds rhodium(III) oxide (Rh2O3) and rhodium(III) chloride (RhCl3). However, macroscopic amounts of...
    32 KB (6,933 words) - 17:00, 18 November 2024
  • Thumbnail for Iron(III) acetate
    [Fe2CoO(OAc)6(H2O)3]. Chromium(III), ruthenium(III), vanadium(III), manganese(III) and rhodium(III) form analogous compounds. Iron(III) acetate (lacking the oxo...
    6 KB (605 words) - 02:11, 22 October 2024
  • Thumbnail for Organorhodium chemistry
    bis(triphenylphosphine)rhodium carbonyl chloride, chlorobis(ethylene)rhodium dimer, cyclooctadiene rhodium chloride dimer, chlorobis(cyclooctene)rhodium dimer,...
    10 KB (1,125 words) - 13:44, 11 October 2023
  • hexachlororhodate(III) is an inorganic chemical compound with the chemical formula (NH4)3RhCl6. Evaporation of solutions of rhodium trichloride and excess...
    3 KB (154 words) - 13:34, 23 October 2024
  • Thumbnail for Rhodium(III) iodide
    Rhodium(III) iodide is an inorganic compound with the formula RhI3. It is a black solid. Rhodium(III) iodide can be synthesised by the reaction of aqueous...
    3 KB (200 words) - 20:04, 20 May 2023
  • Thumbnail for Cyclooctadiene iridium chloride dimer
    [(C8H12)IrL2]+. Chlorobis(cyclooctene)iridium dimer Cyclooctadiene rhodium chloride dimer J. Hartwig, "Organotransition Metal Chemistry: From Bonding to...
    5 KB (445 words) - 08:14, 25 June 2024
  • rhodium(III) chloride 10049–07–7 RhF3 rhodium(III) fluoride 60804–25–3 RhF4 rhodium(IV) fluoride 60617–65–4 RhF5 rhodium(V) fluoride 41517–05–9 RhF6 rhodium(VI)...
    139 KB (120 words) - 17:07, 15 July 2024
  • Thumbnail for Iridium(III) bromide
    aluminum(III) chloride or chromium(III) chloride type, where the monoclinic unit cell contains four formula units. As with rhenium(III) chloride, rhenium(III)...
    4 KB (365 words) - 03:12, 10 July 2023
  • Thumbnail for Pentamethylcyclopentadiene
    prior to reaction with the hydrate of either iridium(III) chloride or rhodium(III) chloride. Complexes of pentamethylcyclopentadienyl differ in several...
    11 KB (841 words) - 19:37, 13 November 2024
  • A chloride sulfite or sulfite chloride is a chemical compound that contains chloride and sulfite anions (SO32− Cl−). The known compounds of this type are...
    11 KB (576 words) - 16:06, 12 August 2024
  • Thumbnail for Chlorobis(ethylene)rhodium dimer
    the dimerization of ethylene to 1-butene. Carbonylation affords rhodium carbonyl chloride. Treatment with acetylacetone and aqueous KOH gives Rh(acac)(C2H4)2...
    3 KB (260 words) - 17:18, 18 June 2024
  • Thumbnail for Group 9 element
    and rhodium. Of these, palladium dissolved in aqua regia but rhodium did not, and the rhodium was precipitated by the addition of sodium chloride as Na...
    21 KB (2,191 words) - 17:34, 6 November 2024
  • Nitrate chlorides are mixed anion compounds that contain both nitrate (NO3−) and chloride (Cl−) ions. Various compounds are known, including amino acid...
    63 KB (3,736 words) - 12:04, 2 November 2024
  • Thumbnail for Salt (chemistry)
    structure has been referred to in references as yttrium(III) chloride and chromium(III) chloride, but both are now known as the RhBr3 structure type. The...
    63 KB (6,942 words) - 00:48, 22 October 2024