In organosulfur chemistry, a thioketal is the sulfur analogue of a ketal (R2C(OR)2), with one of the oxygen replaced by sulfur (as implied by the thio-...
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The Mozingo reduction, also known as Mozingo reaction or thioketal reduction, is a chemical reaction capable of fully reducing a ketone or aldehyde to...
3 KB (318 words) - 13:33, 1 March 2022
reaction, gives the synthetic equivalent of an acyl anion. Mozingo reduction Thioketal IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997)...
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15227/orgsyn.021.0036. S. R. Wilson, G. M. Georgiadis (1990). "Mecaptans from Thioketals: Cyclododecyl Mercaptan". Organic Syntheses; Collected Volumes, vol. 7...
35 KB (3,886 words) - 02:58, 4 July 2024
compounds of type R1R2C(SR)(SR') (R,R' ≠ H, also known as thioacetal and thioketals. Hemiaminal Orthoformate IUPAC, Compendium of Chemical Terminology, 2nd...
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intermediate shown at lower left in the figure, which has the form of a hemi thioketal. In the next step, as TPP departs as a leaving group, taking electrons...
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involves a 1,2 nucleophilic addition. This reaction, the formation of a thioketal, transforms the enzyme from its inactive to active state. Inhibition of...
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reduction can be employed when formation of the hydrazone fail, including thioketal reduction with Raney nickel or reaction with sodium triethylborohydride...
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by action of elemental sulfur and aluminium chloride. Thioacetals and thioketals feature C−S−C−S−C bond sequence. They represent a subclass of sulfides...
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involves the cleavage of benzyl ethers: R−OCH2C6H5 + H2 → R−OH + CH3C6H5 Thioketals undergo hydrogenolysis using Raney nickel in the Mozingo reduction. Laboratory...
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influenced the organosulfur chemistry by the synthesis of thioacetals and thioketals. These substances were subsequently used by other scientists, for example...
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15227/orgsyn.070.0240. Wilson, S. R.; Georgiadis, G. M. (1983). "Mercaptans from Thioketals: Cyclododecyl Mercaptan". Organic Syntheses. 61: 74. doi:10.15227/orgsyn...
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species (ROS). Bonds that are able to be cleaved by ROS are generally thioketals, ketals, and diselenides. Enzyme responsive gated materials are another...
19 KB (2,398 words) - 04:01, 24 March 2024