The thionyl group is SO, a sulfur atom plus an oxygen atom. It occurs in compounds such as thionyl fluoride, SOF2. Thionyl chloride, SOCl2, is a common...
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Thionyl chloride is an inorganic compound with the chemical formula SOCl2. It is a moderately volatile, colourless liquid with an unpleasant acrid odour...
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Carboxylic acid (redirect from Carboxyl group)
nitrile, and halide moieties. The hydroxyl group on carboxylic acids may be replaced with a chlorine atom using thionyl chloride to give acyl chlorides. In nature...
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Acyl chloride (category Functional groups)
treating carboxylic acids with thionyl chloride (SOCl2). The reaction is catalyzed by dimethylformamide and other additives. Thionyl chloride is a well-suited...
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Lithium metal battery (redirect from Lithium thionyl chloride battery)
cobalt content within the cell), rupture, and even an explosion. Lithium-thionyl chloride batteries are particularly susceptible to this type of discharge...
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the second stereocenter. The carboxylate is esterified by reaction with thionyl chloride to form the acyl chloride, which is reacted with ethanol. The...
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from its rapid hydrolysis. Sulfuryl chloride is commonly confused with thionyl chloride, SOCl2. The properties of these two sulfur oxychlorides are quite...
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phosphorus pentachloride (PCl5), sulfuryl chloride (SO2Cl2), phosgene, or thionyl chloride (SOCl2). However, these methods usually give acetyl chloride contaminated...
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Acyl halide (category Functional groups)
chlorides also entail the reaction of carboxylic acids with phosgene, thionyl chloride, and phosphorus trichloride Phosphorus pentabromide is used for...
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aromatic substitution. To drive the equilibrium, dehydrating agents such as thionyl chloride can be added. C6H6 + H2SO4 + SOCl2 → C6H5SO3H + SO2 + 2 HCl Chlorosulfuric...
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Sulfonic acid (redirect from Sulfo group)
R′OH → RSO2OR′ + HCl Sulfonyl halide groups (R−SO2−X) are produced by chlorination of sulfonic acids using thionyl chloride. Sulfonyl fluorides can be...
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clindamycin, is derived from lincomycin by using thionyl chloride to replace the 7-hydroxy group with a chlorine atom with inversion of chirality. It...
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Dimethylcarbamoyl chloride (category IARC Group 2A carcinogens)
acids with thionyl chloride to the corresponding acyl chloride. The tendency towards DMCC formation depends on the chlorination reagent (thionyl chloride...
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Oxohalide (section Main group elements)
state +4, such as thionyl chloride, SOCl2 and oxidation state +6, such as sulfuryl fluoride (SO2F2), sulfuryl chloride (SO2Cl2), and thionyl tetrafluoride...
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Bis(2-chloroethyl)sulfide (category IARC Group 1 carcinogens)
(HCl) is used instead of PCl3: (HOC2H4)2S + 2 HCl → (ClC2H4)2S + 2 H2O Thionyl chloride and phosgene, the latter of which is also a choking agent, have...
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reacted with thionyl chloride, the resulting acid chloride is then esterified with 2-diethylaminoethanol to give Nitrocaine. Finally, the nitro group is reduced...
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diverse organic chemistry. The hydroxymethyl group gives the chloromethyl derivative upon treatment with thionyl chloride. Kojic acid may be weakly carcinogenic...
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of ammonium chloride under high vacuum, or by heating with an excess of thionyl chloride for three hours. The anhydrous halide may alternatively be prepared...
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anisoyl chloride. Ring closure can be accomplished in the presence of thionyl chloride. Aniracetam is available by prescription in Greece (brand names...
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1-Chlorohexane can be obtained by reacting hexyl alcohol with hydrochloric acid or thionyl chloride. 1-Chlorohexane is a colorless liquid with an aromatic odor that...
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Nitrile (redirect from Nitrile group)
amides. Common reagents for this include phosphorus pentoxide (P2O5) and thionyl chloride (SOCl2). In a related dehydration, secondary amides give nitriles...
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Molecular symmetry (redirect from Point symmetry group)
a group. In mathematics, a group is a set with a binary operation that satisfies the four properties listed below. In a symmetry group, the group elements...
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(4-Chlorophenyl)-phenylmethanol is halogenated with thionyl chloride before adding acetylpiperazine. The acetyl group is cleaved with diluted sulfuric acid. An...
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Sulfamoyl fluoride (category Functional groups)
dimethylsulfamoyl fluoride Methyl (CH3) Methyl (CH3) N-sulfinylsulfamoyl fluoride Thionyl (S=O) none chloro(trifluoro-methyl)sulfamoyl fluoride Chlorine (Cl) Trifluoromethyl...
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Alcohol (chemistry) (redirect from Tertiary hydroxyl groups)
secondary alcohols are converted to the corresponding chlorides using thionyl chloride and various phosphorus chloride reagents. Primary and secondary...
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from α-chlorocodide, which is itself obtained by treating codeine with thionyl chloride. By catalytic reduction, α-chlorocodide gives dihydrodesoxycodeine...
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with gold carbonyl chloride or carbon monoxide at room temperature in thionyl chloride. Au2(CO)Cl4 + Au2Cl6 → COCl2 + Au4Cl8 2 Au2Cl6 + 2 CO → Au4Cl8...
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reagents exist for and introducing halogens into diverse substrates, e.g. thionyl chloride. Several pathways exist for the halogenation of organic compounds...
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the synthesis of acyl chlorides from carboxylic acids using oxalyl or thionyl chloride. The catalytic mechanism entails reversible formation of an imidoyl...
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Chloride (category Leaving groups)
covalently-bonded chlorides are phosphorus trichloride, phosphorus pentachloride, and thionyl chloride, all three of which are reactive chlorinating reagents that have...
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