Transition metal thiolate complexes are metal complexes containing thiolate ligands. Thiolates are ligands that can be classified as soft Lewis bases....

Metal nitrosyl complexes are complexes that contain nitric oxide, NO, bonded to a transition metal. Many kinds of nitrosyl complexes are known, which vary...

reaction is important in nature. With metal ions, thiolates behave as ligands to form transition metal thiolate complexes. The term mercaptan is derived from...

Transition metal phosphate complexes are coordination complexes with one or more phosphate ligands. Phosphate binds to metals through one, two, three...

Transition metal amino acid complexes are a large family of coordination complexes containing the conjugate bases of the amino acids, the 2-aminocarboxylates...

Fe2(SCH3)2(CO)6. It is a red volatile solid that is classified as a transition metal thiolate complex. It exists as air-stable red crystals with two isomers, where...

predicting the relative stabilities of transition metal complexes. A recent study of metal-thiolate complexes indicates that an interplay between covalent...

reaction of alkali metal salts of 1,2-alkenedithiolates with metal halides. A thiolate is the conjugate base of a thiol, so alkenedithiolate is, formally...

Especially important are the imidazole substituent in histidine residues, thiolate substituents in cysteine residues, and carboxylate groups provided by aspartate...

Superatom complexes are a special group of superatoms that incorporate a metal core which is stabilized by organic ligands. In thiolate-protected gold...

these magic clusters corresponds to the closing of atomic shells. Certain thiolated clusters such as Au25(SR)18, Au38(SR)24, Au102(SR)44 and Au144(SR)60 also...

single Type I copper ion coordinated by two histidine N-donors, a cysteine thiolate S-donor and a methionine thioether S-donor. In the oxidized state, the...

commonly used in catalysis, synthesis of main group complexes, and synthesis of transition metal complexes. There are two main types of transmetalation,...

functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one...

{RS-SR + 2 Na -> 2 NaSR,}}} followed by protonation of the resulting metal thiolate: NaSR + HCl ⟶ HSR + NaCl {\displaystyle {\ce {NaSR + HCl -> HSR + NaCl}}}...

Thiolate-protected gold clusters are a type of ligand-protected metal cluster, synthesized from gold ions and thin layer compounds that play a special...

et al. (2009). "Solid-State Chlorine NMR of Group IV Transition Metal Organometallic Complexes". Journal of the American Chemical Society. 131 (9): 3317–3330...

chemical reactions with unique regioselectivity compared to other transition-metal-catalyzed allylic substitutions such as the Tsuji-Trost reaction. They...

of thiolates on noble metals are a special case because the metal-metal bonds become reversible after the formation of the thiolate-metal complex. This...

scissions. This is the first example for a coordination compound of (phenylazo)thiolate ligand. The mechanism of formation of orthometalated azobenzene derivative...

was introduced by Georg Wittig in 1958. Ate complexes are common for metals, including the transition metals (groups 3-11), as well as the metallic or semi-metallic...

so in transition metal chemistry, where numerous experiments have been done to determine the relative ordering of ligands and transition metal ions in...

properties can be introduced. Thiolated cellulose derivatives (see thiomers) exhibit also high binding properties for metal ions. Cellulose for industrial...

metallodithiolate donors and metal receivers, a vast collection of thiolate-bridged multimetallic complexes can be prepared with different magnetic communication strengths...

soft, malleable, and ductile metal. Chemically, gold is a transition metal, a group 11 element, and one of the noble metals. It is one of the least reactive...

related anhydrides. Xanthates bind to transition metal cations as bidentate ligands. The charge-neutral complexes are soluble in organic solvents. Xanthates...

the reactivity of the resulting transition-metal complexes. Kovacs has also studied the activity of meta-stable thiolate-ligated manganese peroxo intermediates...

that contain carbon directly bonded to metals or metalloids. The importance of main-group and transition-metal centers has long been recognized as important...

Metallopeptides (also called metal-peptides or metal peptide complexes) are peptides that contain one or more metal ions in their structure. This specific...

carbon is directly bound to metal atoms. Ligand layer can consist of a single type of ligands, like in the case of thiolate-protected gold clusters, or...