In stereochemistry, a chiral auxiliary is a stereogenic group or unit that is temporarily incorporated into an organic compound in order to control the...

temporarily appending a chiral oxazolidinone auxiliary to create a chiral enolate. The pre-existing chirality from the auxiliary is then transferred to...

BINAP/diamine-Ru, widens the scope to α,β-alkenes and aromatic chemicals. A chiral auxiliary is an organic compound which couples to the starting material to form...

chemistry, a chiral derivatizing agent (CDA), also known as a chiral resolving reagent, is a derivatization reagent that is a chiral auxiliary used to convert...

encompassed include the use of chiral starting materials (chiral pool synthesis), the use of chiral auxiliaries and chiral catalysts, and the application...

before aza-MBH ring closure catalyzed by a chiral amine base. Oppolzer's sultam can be used as a chiral auxiliary for an asymmetric MBH reaction. When an...

called chiral auxiliaries. In external asymmetric induction chiral information is introduced in the transition state through a catalyst of chiral ligand...

reaction. The chiral information is introduced by chiral auxiliaries from the diazo compound. In 2010, the Feng group developed a chiral Sc-catalyzed enantioselective...

commercially available and are used in asymmetric synthesis as chiral auxiliaries, often as chiral ammonia equivalents for the synthesis of amines. tert-Butanesulfinamide...

carbon-carbon bond formation reaction facilitated by pyrrolidine chiral auxiliaries. It was pioneered by E. J. Corey and Dieter Enders in 1976, and was...

performed in the presence of a chiral auxiliary. The selection of dihydroquinidine (DHQD) or dihydroquinine (DHQ) as a chiral auxiliary dictates the facial selectivity...

replacing ammonia with (S)-alpha-phenylethylamine as chiral auxiliary the ultimate reaction product was chiral alanine. Catalytic asymmetric Strecker reaction...

followed by chiral chromatographic separation of the enantiomers. An early enantioselective route to atorvastatin made use of an ester chiral auxiliary to set...

of modified sugars. Acetals also find application as chiral auxiliaries. Indeed acetals of chiral glycols like, e.g. derivatives of tartaric acid can be...

placement of a chiral auxiliary on the starting material whose configuration is unaffected by the reaction, and the use of a chiral base. The relative...

alkylated by alkyl halides. The hydrazines SAMP and RAMP function as chiral auxiliary. Several methods are known to recover carbonyl compounds from N,N-dialkylhydrazones...

(RAMP), a class of protein (R)-1-amino-2-methoxymethylpyrrolidine, a chiral auxiliary used in the Enders SAMP/RAMP hydrazone-alkylation reaction Airport...

by use of a chiral auxiliary, and the Nazarov reaction has been performed catalytically using chiral Lewis acids, Brønsted acids and chiral amines. IUPAC...

The chiral pool is a "collection of abundant enantiopure building blocks provided by nature" used in synthesis. In other words, a chiral pool would be...

known as bornanesultam, is a crystalline solid primarily used as a chiral auxiliary in the synthesis of other chemicals with a specific desired stereoselectivity...

process is that D-menthol becomes inexpensively available for use as a chiral auxiliary, along with the more usual L-antipode. Menthol is included in many...

as a chiral auxiliary in organic synthesis. The related sulfinamides (R(S=O)NHR) are amides of sulfinic acids (R(S=O)OH) (see sulfinyl). Chiral sulfinamides...

that end, several variations have been developed utilizing chiral auxiliaries and chiral catalysts. Diastereoselective cyclizations are also known, in...

is used in broad variety of chemical reactions as chiral ligand, chiral catalyst or chiral auxiliary reagent in the Hajos–Parrish–Eder–Sauer–Wiechert reaction...

synthesis of chiral amino acids. The method was established in 1981 by Ulrich Schöllkopf. In it glycine is a substrate, valine a chiral auxiliary and the reaction...

to provide the crucial chiral environment. The strategy is to make these variables to interact with a chiral auxiliary (chiral selector, CS) whereby it...

directed towards anthracyclinone syntheses: The use of d-glucose as a chiral auxiliary in asymmetric Diels–Alder reactions". J. Saudi Chem. Soc. 17: 29–42...

organic synthesis is an illustration of asymmetric synthesis via a chiral auxiliary. The reaction centers around an imine - lithium enolate cycloaddition...

situ from K2OsO2(OH)4 (an Os(VI) species) due to safety concerns. Chiral Auxiliary: This is usually some kind of cinchona alkaloid. Stoichiometric Oxidant:...

In chemical synthesis, ephedrine is used in bulk quantities as a chiral auxiliary group. In saquinavir synthesis, the half-acid is resolved as its salt...