In organic chemistry, the Kumada coupling is a type of cross coupling reaction, useful for generating carbon–carbon bonds by the reaction of a Grignard...
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Japanese footballer and manager Kumada coupling, a cross coupling reaction This page lists people with the surname Kumada. If an internal link intending...
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Suzuki reaction Negishi coupling Kumada coupling Transmetalation Sonogashira, K. (2002), "Development of Pd-Cu catalyzed cross-coupling of terminal acetylenes...
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a cross-coupling reaction is a reaction where two different fragments are joined. Cross-couplings are a subset of the more general coupling reactions...
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Suzuki reaction (redirect from Suzuki coupling)
Chan-Lam coupling Heck reaction Hiyama coupling Kumada coupling Negishi coupling Petasis reaction Sonogashira coupling Stille reaction List of organic reactions...
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process for the synthesis of acetic acid from methyl iodide. Many cross coupling reactions proceed via oxidative addition as well. Electrophilic alkylating...
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of organosilicon was not actually first reported by Hiyama, as Kumada reported a coupling reaction using organofluorosilicates shown below. Organosilanes...
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butylmagnesium bromide was one of the first demonstrations of the Kumada coupling using nickel diphosphine catalysts. This mild and efficient process...
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In organic chemistry, a coupling reaction is a type of reaction in which two reactant molecules are bonded together. Such reactions often require the aid...
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Kumada's group reported nickel-catalyzed cross coupling reactions nearly concurrently with the Corriu group working in France. The Kumada coupling now...
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Hydrosilylation Iodination Isomerisation Jones oxidation Kulinkovich reaction Kumada coupling Lemieux–Johnson oxidation Ley oxidation Ligand association Ligand dissociation...
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activation. Ni(II) N,N,N pincer complexes are active in Kumada, Sonogashira, and Suzuki-Miyaura coupling reactions with unactivated alkyl halides. The pincer...
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synthesis Kucherov reaction Kuhn–Winterstein reaction Kulinkovich reaction Kumada coupling Larock indole synthesis Lawesson's reagent Lebedev process Lehmstedt–Tanasescu...
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chemicals. Prominent coupling reactions include the Heck, Suzuki, Sonogashira coupling, Stille reactions, and the Kumada coupling. Palladium(II) acetate...
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use Kumada coupling and related reactions Regioregular PTs have been prepared by lithiation 2-bromo-3-alkylthiophenes using Kumada cross-coupling. This...
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propagation step is based on organic cross coupling reactions (i.e. Kumada coupling, Sonogashira coupling, Negishi coupling) top form carbon carbon bonds between...
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interactions are: Heck reaction Hiyama coupling Kumada coupling Negishi coupling Petasis reaction Sonogashira coupling Suzuki reaction. π–metal interactions...
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NiCl2(dppp) + 6 H2O NiCl2(dppp) in an effective catalyst for coupling reactions such as the Kumada coupling and Suzuki reactions (example below). It also catalyzes...
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Organonickel chemistry (section Coupling reactions)
cause the coupling reaction between allyl and aryl halides. Other coupling reactions involving nickel in catalytic amounts are the Kumada coupling and the...
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and certain metal cleaning applications. Both isomers participate in Kumada coupling reactions. trans-1,2-Dichloroethylene participates in cycloaddition...
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chloride hexahydrate. This nickel complex serves as a catalyst for the Kumada coupling reaction. Dppp is also used as a ligand for palladium(II) catalysts...
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complex dichloro(1,3-bis(diphenylphosphino)propane)nickel is useful in Kumada coupling. Hartwig, J. F. Organotransition Metal Chemistry, from Bonding to Catalysis;...
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various palladium cross-coupling reactions including Negishi coupling, Suzuki coupling, Sonogashira coupling, Kumada coupling, and the Buchwald–Hartwig...
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Limmert, Michael E.; Roy, Amy H.; Hartwig, John F. (2005-11-01). "Kumada Coupling of Aryl and Vinyl Tosylates under Mild Conditions". The Journal of...
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Hiyama coupling Suzuki reaction Negishi coupling Petasis reaction Stille reaction Sonogashira coupling Kumada coupling Giannerini, M.; Fañanás-Mastral, M.;...
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Grignard reagent (category Coupling reactions)
lithium chloride (LiCl) and copper(II) chloride (CuCl2) in THF. The Kumada-Corriu coupling gives access to [substituted] styrenes. Treatment of a Grignard...
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triflates. Chan-Lam coupling Heck reaction Hiyama coupling Kumada coupling Negishi coupling Petasis reaction Sonogashira coupling Stille reaction Suzuki...
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Palladium–NHC complex (redirect from NHC-Palladium Complexes in Cross-Coupling)
effective in Suzuki-Miyaura, Negishi, Sonogashira, Kumada-Tamao-Corriu, Hiyama, and Stille cross-coupling. Compared to the corresponding Pd-phosphine catalysts...
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substrate an aryl, alkenyl (vinyl), or acyl organohalide. In the related Kumada coupling the catalysts are based on palladium and nickel. Complexes derived...
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Sonogashira coupling in 1975. Sonogashira was later a professor at Osaka City University and retired in 2004. Richard F. Heck Makoto Kumada Ei-ichi Negishi...
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