Organozinc chemistry is the study of the physical properties, synthesis, and reactions of organozinc compounds, which are organometallic compounds that...
33 KB (3,394 words) - 06:05, 9 December 2023
organocobalt chemistry, organonickel chemistry, organocopper chemistry, organozinc chemistry, organogallium chemistry, organogermanium chemistry, organoarsenic...
31 KB (3,157 words) - 20:03, 24 September 2024
Zinc (section Compounds and chemistry)
of zinc. Organozinc compounds are those that contain zinc–carbon covalent bonds. Diethylzinc ((C 2H5) 2Zn) is a reagent in synthetic chemistry. It was...
143 KB (16,230 words) - 16:55, 27 October 2024
diethylborane, is the transmetallation of the organoboron compounds to form organozinc compounds. Some diaryl and dialkylboranes are well known. Dimesitylborane...
30 KB (2,992 words) - 19:24, 18 August 2024
research at Kazan was primarily concerned with the development of organozinc chemistry and the synthesis of alcohols. The first of these reactions had been...
8 KB (896 words) - 15:29, 31 October 2024
Zinc chloride (section Organozinc precursor)
and lacking acidic protons, this complex is used in the synthesis of organozinc compounds. A related 1:2 complex is ZnCl2(NH2OH)2 (zinc dichloride di(hydroxylamine))...
39 KB (3,996 words) - 14:15, 17 October 2024
cross-coupling reaction. The reaction couples organic halides or triflates with organozinc compounds, forming carbon-carbon bonds (C-C) in the process. A palladium...
34 KB (3,954 words) - 20:12, 15 June 2024
Tirado (1999). "Copper-catalyzed Conjugate Addition of Functionalized Organozinc Reagents to α,β-Unsaturated Ketones: Ethyl 5-(3-oxocyclohexyl)pentanoate"...
6 KB (633 words) - 14:48, 23 October 2024
tetraalkoxides, or mixtures thereof with organolithium, organomagnesium, and organozinc compounds. Such compounds find occasional use as stoichiometric reagents...
18 KB (1,866 words) - 09:45, 4 November 2023
place by: hydrolysis of a nitrile to form an amide or a carboxylic acid organozinc nucleophiles in the Blaise reaction alcohols in the Pinner reaction. the...
8 KB (910 words) - 13:13, 26 August 2024
Diethylzinc (category Organozinc compounds)
reactive organozinc compound consisting of a zinc center bound to two ethyl groups. This colourless liquid is an important reagent in organic chemistry. It...
12 KB (1,156 words) - 22:49, 26 August 2024
Metalation (category Organometallic chemistry)
Grignard reagents. However, other organometallic compounds — such as organozinc compounds — also experience common use in both laboratory and industrial...
11 KB (722 words) - 10:04, 16 October 2024
thioesters is the Fukuyama coupling, in which the thioester is coupled with an organozinc halide by a palladium catalyst to give a ketone. Thioesters are common...
13 KB (1,388 words) - 20:22, 15 September 2024
Mercury (element) (redirect from Mercurial chemistry)
usually two-coordinate and linear geometry. Unlike organocadmium and organozinc compounds, organomercury compounds do not react with water. They usually...
120 KB (12,762 words) - 01:30, 1 November 2024
of studies have been disclosed. Mechanistic proposals generally invoke organozinc intermediates, sometimes including zinc carbenoids, either as discrete...
12 KB (1,072 words) - 02:09, 24 October 2024
secondary nitro compounds ( Nef reaction) Alkylation of thioester with organozinc compounds (Fukuyama coupling). Alkylation of acid chloride with organocadmium...
24 KB (2,895 words) - 09:31, 2 November 2024
coupling is a coupling reaction taking place between a thioester and an organozinc halide in the presence of a palladium catalyst. The reaction product is...
9 KB (905 words) - 17:54, 26 September 2024
Simmons–Smith reaction is an organic cheletropic reaction involving an organozinc carbenoid that reacts with an alkene (or alkyne) to form a cyclopropane...
27 KB (2,906 words) - 19:24, 9 October 2024
at elevated temperatures, whereas the corresponding organocadmium and organozinc compounds (and most metal alkyls in general) hydrolyze rapidly. The difference...
16 KB (1,406 words) - 15:11, 28 October 2024
Grignard reagent (category Organometallic chemistry)
method to synthesize Grignard reagents involves reaction of Mg with an organozinc compound. This method has been used to make adamantane-based Grignard...
24 KB (2,752 words) - 01:37, 23 October 2024
Rieke metal (category Reagents for organic chemistry)
corresponding polythiophene. Rieke-Zn also reacts with bromoesters to give organozinc reagents of value for the Reformatsky reaction. Rieke magnesium reacts...
9 KB (1,128 words) - 01:19, 15 June 2024
main group organometallic chemistry (if one considers Zn to be a main group element) involved the synthesis of organozinc compounds diethyl zinc by Frankland...
6 KB (627 words) - 18:24, 11 September 2024
organocadmium reagent, an ate complex. The same salt effect can be observed with organozinc compounds. Dimethylcadmium has been used to synthesize colloidal nanocrystals...
6 KB (721 words) - 10:53, 16 November 2023
Ashley M. (2005-07-01). "Nickel-Catalyzed Electrophilic Amination of Organozinc Halides". Synlett. 2005 (11): 1799–1801. doi:10.1055/s-2005-871567. Quasdorf...
7 KB (574 words) - 16:22, 9 August 2024
Organolithium reagent (redirect from Organolithium chemistry)
transmetalation with n-BuLi. Organolithium can also be used in to prepare organozinc compounds through transmetalation with zinc salts. Lithium diorganocuprates...
55 KB (5,971 words) - 20:35, 22 July 2024
they are often called, are aggregates with the formula [i-PrMgCl·LiCl]2 Organozinc-LiCl complexes Li-Yuan Bao, Robert; Zhao, Rong; Shi, Lei (2015). "Progress...
9 KB (1,020 words) - 00:52, 17 February 2024
benzoquinone and bicyclo[2.2.0]hexene. Elimination of H–Br and addition of an organozinc compound installs the alkyl alcohol. A hydrazine-mediated deoxygenation...
16 KB (1,892 words) - 15:02, 9 August 2024
Na2CO3 → ZnCO3 + 2 NaNO3 Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 455. ISBN 978-0-08-037941-8...
5 KB (394 words) - 13:43, 19 June 2024
Tert-Butanesulfinamide (category Reagents for organic chemistry)
amine (ketone precursor). Typical nucleophiles are Grignard reagents, organozinc compounds, organolithium compounds, and enolates. Chiral sulfinimines...
7 KB (440 words) - 14:39, 27 October 2023
Zinc dithiophosphate (section Structural chemistry)
(Google Books excerpt). In Leslie R. Rudnick (ed.). Lubricant Additives: Chemistry and Applications. CRC Press. ISBN 9780824747404. T. Ito; T. Igarashi;...
8 KB (909 words) - 14:34, 4 January 2024