Transition metal carboxylate complexes are coordination complexes with carboxylate (RCO2−) ligands. Reflecting the diversity of carboxylic acids, the inventory...

Transition metal carboxylate complex Oxalatonickelate Krishnamurty, Kotra V.; Harris, Gordon M. (1961). "The Chemistry of the Metal Oxalato Complexes"...

lacking direct metal-carbon bonds. Metal β-diketonates, metal alkoxides, metal dialkylamides, transition metal carboxylate complexes, metal acetylacetonates...

In coordination chemistry, a transition metal NHC complex is a metal complex containing one or more N-heterocyclic carbene ligands. Such compounds are...

In chemistry, a transition metal chloride complex is a coordination complex that consists of a transition metal coordinated to one or more chloride ligand...

cyclopropanation of alkenes. It is a widely studied example of a transition metal carboxylate complex. Rhodium(II) acetate is usually prepared by the heating of...

Transition metal amino acid complexes are a large family of coordination complexes containing the conjugate bases of the amino acids, the 2-aminocarboxylates...

hemoglobin, hemerythrin, and hemocyanin. Several transition metals form complexes with O2, and many of these complexes form reversibly. The binding of O2 is the...

Transition metal phosphate complexes are coordination complexes with one or more phosphate ligands. Phosphate binds to metals through one, two, three...

classified as CMD, the transition state does not need to involve the carboxylate as a ligand on the metal. Common sources of carboxylate include pivalate,...

A transition metal imidazole complex is a coordination complex that has one or more imidazole ligands. Complexes of imidazole itself are of little practical...

The Das cubane is a transition metal carboxylate complex with the formula [CoO(OAc)py]4 where OAc is acetate and py is pyridine. The compound is named...

In organometallic chemistry, transition metal complexes of nitrite describes families of coordination complexes containing one or more nitrite (−NO2) ligands...

Carboxylate–based metal–organic frameworks are metal–organic frameworks that are based on organic molecules comprising carboxylate functional groups. The...

intramolecular variant of this reaction was first reported in 1961. Rhodium carboxylate complexes, such as dirhodium tetraacetate, are common catalysts. Enantioselective...

pores. The most common transition metals employed in carboxylate-based frameworks are Cu2+ and Zn2+. Lighter main-group metal ions have also been explored...

Metal carbon dioxide complexes are coordination complexes that contain carbon dioxide ligands. Aside from the fundamental interest in the coordination...

of complex: compounds formed by the interaction of a metal ion with a ligand and supramolecular complexes, such as host–guest complexes and complexes of...

Saponification is a process of cleaving esters into carboxylate salts and alcohols by the action of aqueous alkali. Typically aqueous sodium hydroxide...

2-Succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate synthase (EC 4.2.99.20), also known as SHCHC synthase is encoded by the menH gene in Escherichia...

Tolstikov, S. E.; Ovcharenko, V. I. (2019). "Mononuclear Transition Metal Adamantane-1-Carboxylates". Russian Chemical Bulletin. 68 (9): 1669–1674. doi:10...

functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one...

functional group: Transition metal salts, especially copper compounds, facilitate decarboxylation via carboxylate complex intermediates. Metals that catalyze...

iconic example of a compound with a metal-metal quadruple bond. Like several other transition metal carboxylate complexes, Mo2(O2CCH3)4 adopts a Chinese lantern...

the complex since octahedral d3 ions give kinetically robust complexes. Overall, the complex's structure is unusual compared to other transition metal carboxylate...

to alkynes in carbocyanation: Nitriles are precursors to transition metal nitrile complexes, which are reagents and catalysts. Examples include...

known as ferrioxalate. Other carboxylate sources, e.g., citrate and tartrate, bind as well to give carboxylate complexes. The affinity of iron(III) for...

white, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. Silver is found...

the inert pair effect yields a plethora of organometallic bismuth-transition metal compounds and clusters with interesting electronics and 3D structures...

For most transition metals, DOTA functions as a hexadentate ligand, binding through the four nitrogen and two carboxylate centres. The complexes have octahedral...