Organozinc chemistry is the study of the physical properties, synthesis, and reactions of organozinc compounds, which are organometallic compounds that...
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organocobalt chemistry, organonickel chemistry, organocopper chemistry, organozinc chemistry, organogallium chemistry, organogermanium chemistry, organoarsenic...
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Zinc (section Compounds and chemistry)
of zinc. Organozinc compounds are those that contain zinc–carbon covalent bonds. Diethylzinc ((C 2H5) 2Zn) is a reagent in synthetic chemistry. It was...
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diethylborane, is the transmetallation of the organoboron compounds to form organozinc compounds. Some diaryl and dialkylboranes are well known. Dimesitylborane...
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research at Kazan was primarily concerned with the development of organozinc chemistry and the synthesis of alcohols. The first of these reactions had been...
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Zinc chloride (section Organozinc precursor)
and lacking acidic protons, this complex is used in the synthesis of organozinc compounds. A related 1:2 complex is ZnCl2(NH2OH)2 (zinc dichloride di(hydroxylamine))...
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Tirado (1999). "Copper-catalyzed Conjugate Addition of Functionalized Organozinc Reagents to α,β-Unsaturated Ketones: Ethyl 5-(3-oxocyclohexyl)pentanoate"...
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cross-coupling reaction. The reaction couples organic halides or triflates with organozinc compounds, forming carbon-carbon bonds (C-C) in the process. A palladium...
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tetraalkoxides, or mixtures thereof with organolithium, organomagnesium, and organozinc compounds. Such compounds find occasional use as stoichiometric reagents...
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thioesters is the Fukuyama coupling, in which the thioester is coupled with an organozinc halide by a palladium catalyst to give a ketone. Thioesters are common...
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Metalation (category Organometallic chemistry)
Grignard reagents. However, other organometallic compounds — such as organozinc compounds — also experience common use in both laboratory and industrial...
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Mercury (element) (redirect from Mercurial chemistry)
usually two-coordinate and linear geometry. Unlike organocadmium and organozinc compounds, organomercury compounds do not react with water. They usually...
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main group organometallic chemistry (if one considers Zn to be a main group element) involved the synthesis of organozinc compounds diethyl zinc by Frankland...
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Diethylzinc (category Organozinc compounds)
reactive organozinc compound consisting of a zinc center bound to two ethyl groups. This colourless liquid is an important reagent in organic chemistry. It...
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of studies have been disclosed. Mechanistic proposals generally invoke organozinc intermediates, sometimes including zinc carbenoids, either as discrete...
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compounds. In the Fukuyama coupling, ketones form from a thioester and an organozinc compound. By the reaction of an acid chloride with organocadmium compounds...
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place by: hydrolysis of a nitrile to form an amide or a carboxylic acid organozinc nucleophiles in the Blaise reaction alcohols in the Pinner reaction. the...
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Grignard reagent (category Organometallic chemistry)
method to synthesize Grignard reagents involves reaction of Mg with an organozinc compound. This method has been used to make adamantane-based Grignard...
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organocadmium reagent, an ate complex. The same salt effect can be observed with organozinc compounds. Dimethylcadmium has been used to synthesize colloidal nanocrystals...
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Rieke metal (category Reagents for organic chemistry)
corresponding polythiophene. Rieke-Zn also reacts with bromoesters to give organozinc reagents of value for the Reformatsky reaction. Rieke magnesium reacts...
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at elevated temperatures, whereas the corresponding organocadmium and organozinc compounds (and most metal alkyls in general) hydrolyze rapidly. The difference...
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Simmons–Smith reaction is an organic cheletropic reaction involving an organozinc carbenoid that reacts with an alkene (or alkyne) to form a cyclopropane...
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coupling is a coupling reaction taking place between a thioester and an organozinc halide in the presence of a palladium catalyst. The reaction product is...
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Ashley M. (2005-07-01). "Nickel-Catalyzed Electrophilic Amination of Organozinc Halides". Synlett. 2005 (11): 1799–1801. doi:10.1055/s-2005-871567. Quasdorf...
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Na2CO3 → ZnCO3 + 2 NaNO3 Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 455. ISBN 978-0-08-037941-8...
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Zinc dithiophosphate (section Structural chemistry)
(Google Books excerpt). In Leslie R. Rudnick (ed.). Lubricant Additives: Chemistry and Applications. CRC Press. ISBN 9780824747404. T. Ito; T. Igarashi;...
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benzoquinone and bicyclo[2.2.0]hexene. Elimination of H–Br and addition of an organozinc compound installs the alkyl alcohol. A hydrazine-mediated deoxygenation...
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they are often called, are aggregates with the formula [i-PrMgCl·LiCl]2 Organozinc-LiCl complexes Li-Yuan Bao, Robert; Zhao, Rong; Shi, Lei (2015). "Progress...
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1-iodo-3-butene 1 is converted to a cyanozinc cuprate 2 (by transmetalation of the organozinc iodide with copper cyanide) which reacts in the next step with 1-nitrocyclopentene...
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organomanganese compounds can be compared to that of organomagnesium and organozinc compounds. The electronegativity of Mn (1.55) is comparable to that of...
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