Ring-closing metathesis (RCM) is a widely used variation of olefin metathesis in organic chemistry for the synthesis of various unsaturated rings via...

classes of olefin metathesis include: Cross metathesis (CM) Ring-opening metathesis (ROM) Ring-closing metathesis (RCM) Ring-opening metathesis polymerization...

2022-11-17 "Ring Closing Metathesis - an overview | ScienceDirect Topics". www.sciencedirect.com. Retrieved 2022-11-17. "Olefin Metathesis". Chemistry...

catalyzes one enantiomer to perform ring closing metathesis, resulting in an enantiopure alcohol, and an enantiopure closed ring, as shown below. The catalyst...

Paal–Knorr synthesis Pictet–Spengler reaction Pomeranz–Fritsch reaction Ring-closing metathesis Robinson annulation Skraup reaction IUPAC, Compendium of Chemical...

J. P.; Grubbs, R. H. (1999). "Increased Ring Closing Metathesis Activity of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with Imidazolin-2-ylidene...

cyclizations; ring-closing metathesis reactions, which also can be used to accomplish a specific type of polymerization; the Ruzicka large ring synthesis...

equilibrium to products. Alkyne metathesis can be used in ring-closing operations and RCAM stands for ring closing alkyne metathesis. The olfactory molecule civetone...

commercially available (+)-citronellal, and forms the 15-membered ring via ring-closing metathesis: A more recent enantioselective synthesis involves an intramolecular...

complex architectures: Nonconjugated dienes are substrates for ring-closing metathesis reactions. These reactions require a metal catalyst:c The position...

of (−)-muscone from (+)-citronellal. The 15-membered ring is generated by ring-closing metathesis. In stereochemistry, macrocyclic stereocontrol refers...

also be used to synthesize the heterocycle, N-boc-3-pyrroline by ring-closing metathesis using Grubbs' catalyst (bis(tricyclohexylphosphine)benzylidineruthenium...

methine (=CH-) bridges N-substituted pyrrolines can be generated by ring-closing metathesis. Pyrrole, the aromatic analog with two double bonds Pyrrolidine...

applications. Staples synthesized using ring-closing metathesis (RCM) are common. This variation of olefin metathesis and its application to stapled peptides...

silyl ketene acetal intermediate. Ring-closing olefin metathesis has also been used to establish the tetrahydropyridine ring system. Balasubramanian, Marudai...

olefin metathesis. The general scheme is given by scheme 1: When the reaction is intramolecular (in an enyne) it is called ring-closing enyne metathesis or...

reduce the bandwidth of sparse symmetric matrices Ring-closing metathesis, a variation on olefin metathesis Rotor current meter, a mechanical current meter...

Riemschneider thiocarbamate synthesis Riley oxidations Ring closing metathesis Ring opening metathesis Ritter reaction Robinson annulation Robinson–Gabriel...

uses non-natural amino acids to facilitate macrocyclization by ring-closing olefin metathesis. In this case, a stapled BH3 helix was identified which specifically...

and reported in January 2009. One of the synthetic steps is a ring-closing metathesis (RCM) reaction: Stu Borman. "Long-Sought Benzenelike Molecule Created:...

ripostatin A features two concurrent Stille couplings followed by a ring-closing metathesis. The synthesis of lucilactaene features a middle subunit, having...

olefin metathesis. He studied olefin transformations for ring-closing metathesis (RCM), cross-metathesis reaction (CMR), and ring-opening metathesis polymerization...

"Synthesis of Fused Bicyclic Imidazoles by Sequential Van Leusen/Ring-Closing Metathesis Reactions". Org. Lett. 7 (15). American Chemical Society: 3183–3186...

Langemann, K. (1996). "A Concise Total Synthesis of Dactylol via Ring Closing Metathesis" (PDF). J. Org. Chem. 61 (25): 8746–8749. doi:10.1021/jo961600c...

Boiteau JG, Van de Weghe P, Eustache J (August 2001). "A new, ring closing metathesis-based synthesis of (-)-fumagillol". Organic Letters. 3 (17): 2737–2740...

of Zr-catalyzed carbomagnesation and Mo-catalyzed macrocyclic ring closing metathesis in asymmetric synthesis. Enantioselective total synthesis of Sch...

from divinyl ketones, Saegusa–Ito oxidation from cyclopentanones, ring-closing metathesis from the corresponding dienes, oxidation of the corresponding cyclic...

Carbonyl olefin metathesis is a type of metathesis reaction that entails, formally, the redistribution of fragments of an alkene and a carbonyl by the...

California Institute of Technology. At Caltech, Coates worked on ring-closing metathesis reactions to functionalize polyolefins, and supramolecular phenyl-perfluorophenyl...

reaction to couple an aliphatic aldehyde with a cyclic enone. After ring-closing metathesis and alkene reduction, the 1,4-dicarbonyl product was converted...