A metal-phosphine complex is a coordination complex containing one or more phosphine ligands. Almost always, the phosphine is an organophosphine of the...

enzymes. Metal carbon dioxide complex – carbon dioxide bonding to metalsPages displaying wikidata descriptions as a fallback Metal phosphine complex – class...

comparing the structures of pairs of metal-phosphine complexes that differ only by one electron. Oxidation of R3P–M complexes results in longer M–P bonds and...

Some related compounds such as transition metal hydrides and metal phosphine complexes are often included in discussions of organometallic compounds...

complexes, metal acetylacetonates, and metal phosphine complexes are representative members of this class. Some of metal-organic compounds confer solubility...

turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transition metals (elements like titanium that...

Transition metal complexes of phosphine oxides are coordination complex containing one or more phosphine oxide ligands. Many phosphine oxides exist and...

Bis(triphenylphosphine)platinum chloride is a metal phosphine complex with the formula PtCl2[P(C6H5)3]2. Cis- and trans isomers are known. The cis isomer...

Kohlpaintner, C. W. (2007). "Syntheses of Water-Soluble Phosphines and their Transition Metal Complexes". Inorganic Syntheses. Vol. 32. pp. 8–25. doi:10.1002/9780470132630...

transition metal carbene complex is an organometallic compound featuring a divalent carbon ligand, itself also called a carbene. Carbene complexes have been...

chemist at DuPont. Tolman originally developed the method for phosphine ligands in nickel complexes, determining them from measurements of accurate physical...

Dichlorobis(triphenylphosphine)nickel(II) refers to a pair of metal phosphine complexes with the formula NiCl2[P(C6H5)3]2. The compound exists as two...

n = 0, n = 2, and n = 3 that are often employed as ligands in metal phosphine complexes. Dimethylphenylphosphine is prepared by the reaction of methylmagnesium...

to the phosphine oxide. As a phosphine ligand, it has a wide cone angle of 194°. Consequently, it tends to cyclometalate when treated with metal halides...

lithium perchlorate. Gold phosphine or NHC triflimidates (LAuNTf2, L = R3P or NHC) are isolable though somewhat labile complexes of gold that serve as sources...

L. Casalnuovo, L. N. Ito, B. J. Johnson, L. H. Pignolet "Mixed-Metal-Gold Phosphine Cluster Compounds" Inorganic Syntheses, 1992, Volume 29, Pages 279–298...

Transition-metal allyl complexes are coordination complexes with allyl and its derivatives as ligands. Allyl is the radical with the connectivity CH2CHCH2...

In coordination chemistry, a transition metal NHC complex is a metal complex containing one or more N-heterocyclic carbene ligands. Such compounds are...

complexes have been studied at an accelerating pace since the mid-1970s. Most pincer ligands contain phosphines. Reactions of metal-pincer complexes are...

Secondary (2°) phosphines, with the formula R2PH, are prepared analogously to the primary phosphines. They are also obtained by alkali-metal reductive cleavage...

poor diet and can cause heart disease. Metal ions are often used for diagnostic medical imaging. Metal complexes can be used either for radioisotope imaging...

reaction of Vaska's complex analogs with the parent phosphine generate the following transition-metal phosphido complex. Alkali metal phosphides sometimes...

surface. A particularly important segment of covalent hydrides are complex metal hydrides, powerful soluble hydrides commonly used in synthetic procedures...

n = 0, n = 1, and n = 3 that are often employed as ligands in metal phosphine complexes. Methyldiphenylphosphine is prepared by reaction of chlorodiphenylphosphine...

ligands to form phosphinimide complexes which are highly active catalysts in some olefin polymerization reactions. Phosphine imides can be isolated as intermediates...

silver, copper, rhodium, and ruthenium, among other transition metals. Dialkylbiaryl phosphine ligands were first described by Stephen L. Buchwald in 1998...

provides to the metal that to which it is bound. Being a relatively compact phosphine, several can bind to a single transition metal, as illustrated by...

rearrangement, intramolecular nucleophilic addition of the new alkyl phosphine to the carbocation, and oxidation of the resulting phosphetanium with...

organic synthesis. HMPA is the oxide of tris(dimethylamino)phosphine, P(NMe2)3. Like other phosphine oxides (such as triphenylphosphine oxide), the molecule...

Homogeneous catalysts are often chelated complexes. A representative example is the use of BINAP (a bidentate phosphine) in Noyori asymmetric hydrogenation...