Organocopper chemistry is the study of the physical properties, reactions, and synthesis of organocopper compounds, which are organometallic compounds...

Reactions of Copper Ions (Cu²⁺)". Chemistry LibreTexts. 3 April 2018. Retrieved 27 May 2024. "Modern Organocopper Chemistry" Norbert Krause, Ed., Wiley-VCH...

organocobalt chemistry, organonickel chemistry, organocopper chemistry, organozinc chemistry, organogallium chemistry, organogermanium chemistry, organoarsenic...

bond are known as organocopper compounds. They are very reactive towards oxygen to form copper(I) oxide and have many uses in chemistry. They are synthesized...

today in organic synthesis: This finding led to the development of organocopper chemistry. For example, CuCl reacts with methyllithium (CH3Li) to form "Gilman...

groups do not transfer, only the R group does. Cuprate (chemistry) J. F. Normant (1972). "Organocopper(I) Compounds and Organocuprates in Synthesis". Synthesis...

Organosilver chemistry is the study of organometallic compounds containing a carbon to silver chemical bond. The theme is less developed than organocopper chemistry...

(2008) Inorganic Chemistry (3rd ed.), Pearson: Prentice Hall. ISBN 978-0-13-175553-6. Dieter, R. K. In Modern Organocopper Chemistry; Krause, N., Ed.;...

Professor of Chemistry at Johns Hopkins University in Baltimore, Maryland. Posner is known for his pioneering research in organocopper chemistry, including...

addition of lithium anion. Compound 2 is then transformed using organocopper chemistry to yield Compound 3 with good stereoselectivity of about 98%. Typically...

of organocopper reagents involve species containing copper-carbon bonds acting as nucleophiles in the presence of organic electrophiles. Organocopper reagents...

results in defluorination to generate F− and difluorocarbene (CF2). Some organocopper and organocadmium compounds have been developed as trifluoromethylation...

2R'COCl → 2R'COR + CdCl 2 Such reagents have largely been supplanted by organocopper compounds, which are much less toxic. Cadmium chloride is also used for...

coordination complexes, and anionic organocopper compounds, reflecting the diverse roles of copper in chemistry. The term is mainly used in three contexts:...

"Transmetalation reactions producing organocopper compounds". In Rappoport, Z.; Marek, I. (eds.). The Chemistry of Organocopper Compounds. Vol. 1. John Wiley...

coupling). Alkylation of acid chloride with organocadmium compounds or organocopper compounds. The Dakin–West reaction provides an efficient method for preparation...

{\displaystyle {\ce {R'-X}}} ) to form a new alkane, as well as an ill-defined organocopper species and lithium (pseudo)halide as byproducts. Li+[R–Cu–R]− + R′–X →...

the product and regenerate copper(I). However, evidence for such an organocopper intermediate is weak and mostly circumstantial, and the exact pathway...

The aforementioned complex CuBr(S(CH3)2) is widely used to generate organocopper reagents. Related CuBr complexes are catalysts for atom transfer radical...

enone. Common reactions include nucleophilic conjugate addition with organocopper reagents, Michael reactions and Robinson annulations. Several routes...

organometallic compounds such as Grignard (organomagnesium), organolithium, organocopper, and organosodium reagents. These compounds typically can add to an electron-deficient...

of MeLi with metal halides. Especially important are the formation of organocopper compounds (Gilman reagents), of which the most useful is lithium dimethylcuprate...

Ph.D. in Chemistry from MIT in 1967 under the direction of George M. Whitesides. His thesis title was "Thermal decomposition of organocopper(I) compounds"...

is rarely observed. The reaction likely involves the formation of an organocopper compound (RCuX) which reacts with the other aryl reactant in a nucleophilic...

often used to prepare other organometallic compounds by transmetalation. Organocopper, organotin, organosilicon, organoboron, organophosphorus, organocerium...

Its chemical formula is C 6H 5Cu. Phenylcopper was the first known organocopper compound and was first prepared in 1923 from phenylmagnesium iodide and...

1846, independently to Schönbein, and with the synthesis of the first organocopper compound copper(I) acetylide Cu2C2 in 1859. Böttger was born in Aschersleben...

Naohiko; Nakamura, Eiichi (11 April 2012). "Mechanisms of Nucleophilic Organocopper(I) Reactions". Chemical Reviews. 112 (4): 2339–2372. doi:10.1021/cr200241f...

"Transmetalation reactions producing organocopper compounds". In Rappoport, Z.; Marek, I. (eds.). The Chemistry of Organocopper Compounds. Vol. 1. John Wiley...

the copper(III) complex. The last step, a reductive elimination of an organocopper(III) intermediate to regenerate the Cu(I) catalyst and form the product...