Transition metal nitrile complexes are coordination compounds containing nitrile ligands. Because nitriles are weakly basic, the nitrile ligands in these...

known to add to alkynes in carbocyanation: Nitriles are precursors to transition metal nitrile complexes, which are reagents and catalysts. Examples...

Transition metal isocyanide complexes are coordination compounds containing isocyanide ligands. Because isocyanides are relatively basic, but also good...

Transition metal carbyne complexes are organometallic compounds with a triple bond between carbon and the transition metal. This triple bond consists of...

free electron pair at the nitrogen atom, which can form many transition metal nitrile complexes. Being weakly basic, it is an easily displaceable ligand....

synthesis of other copper complexes. The cation [Cu(CH3CN)4]+ is a well-known example of a transition metal nitrile complex. As confirmed by X-ray crystallographic...

Most other transition metal tetrafluoroborates only exist as solvates of water, alcohols, ethers, or nitriles. Transition metal nitrile complexes, e.g. [Cu(NCMe)4]BF4...

polymers feature Fe-CN-M linkages. Transition metal nitrile complexes – coordination compounds containing nitrile ligands (coordinating via N) Sharpe...

com/MEMCyanideTreatment.pdf Sharpe, A. G. The Chemistry of Cyano Complexes of the Transition Metals; Academic Press: London, 1976[page needed] Holleman, A. F...

reaction requires metal catalysts. Mechanistic studies show that the conversion proceeds via the intermediacy of metal alkylidyne complexes. The reaction...

Metal nitrido complexes are coordination compounds and metal clusters that contain an atom of nitrogen bound only to transition metals. These compounds...

covalent organolithium complexes. Regardless, these organolithium compounds are reactive toward various electrophiles. Although nitrile anions are functionally...

Transition metal complexes of phosphine oxides are coordination complex containing one or more phosphine oxide ligands. Many phosphine oxides exist and...

soluble transition-metal complexes are more commonly used today. Sensitizers absorb light to give redox-active excited states. For many metal-based sensitizers...

coordination complexes that activate both the unsaturated substrate and the H2. Most typically, these complexes contain platinum group metals, especially...

followed by methanolysis. Benzonitrile forms coordination complexes with transition metals that are both soluble in organic solvents and conveniently...

necessary, without the inevitable oxidation (breaking down) of everything. Transition metal ions, due to their multiple oxidation states, were the only elements...

Fosbenner, Stephanie M. (2009). "Synthesis and Characterization of Transition-Metal Complexes Containing 1,1'-Bis(diphenylphosphino)ferrocene". J. Chem. Educ...

MOFs increased their functionality by reacting organic units and metal-organic complexes with linkers. (4) Multifunctional MOFs incorporated multiple functionalities...

stable ruthenium-carbenoid complexes and rhodium metallocarbenes, involves an initial formation of a metal-carbenoid complex from the diazo compound. Elimination...

used to make nitriles. Nitrogenase: enzymes used by organisms to fix nitrogen Transition metal dinitrogen complex Metal nitrido complex Chalkley, Matthew...

stable chelate complexes with polyvalent ions (in particular the water hardening agents Ca2+ and Mg2+, as well as transition and heavy metal ions such as...

are provided below. Ion-paired combinations of early and late transition metal complexes can simultaneously interact with a substrate as both Lewis acid...

temperature, but it will nevertheless react with lithium metal and some transition metal complexes. This is due to its bonding, which is unique among the...

white, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. Silver is found...

field of enantioselective reduction have focused on the development of transition metal catalyzed reactions, which employ cheap reductants such as hydrogen...

Lead Complexes with Relevance for Biological Systems". In Astrid S, Helmut S, Sigel RK (eds.). Lead: Its Effects on Environment and Health. Metal Ions...

tetrazident complexing agent (abbreviated as "tren"), which forms stable chelates, particularly with divalent and trivalent transition metal ions. Nitrilotriacetonitrile...

dinitrogen complex to be discovered was [Ru(NH3)5(N2)]2+ (see figure at right), and soon many other such complexes were discovered. These complexes, in which...

The Letts nitrile synthesis is a chemical reaction of aromatic carboxylic acids with metal thiocyanates to form nitriles. The reaction includes the loss...