• In organic chemistry, the Hammett equation describes a linear free-energy relationship relating reaction rates and equilibrium constants for many reactions...
    34 KB (4,056 words) - 20:34, 22 July 2024
  • the Hammett equation. While the Hammett equation accounts for how field, inductive, and resonance effects influence reaction rates, the Taft equation also...
    14 KB (1,888 words) - 11:44, 23 November 2023
  • as the Henderson–Hasselbalch equation are no longer valid due to the variations of the activity coefficients. The Hammett acidity function is used in fields...
    7 KB (871 words) - 21:29, 11 September 2024
  • Yukawa–Tsuno equation, first developed in 1959, is a linear free-energy relationship in physical organic chemistry. It is a modified version of the Hammett equation...
    6 KB (916 words) - 03:05, 16 June 2023
  • respect to Y, the measure of ionizing power of the solvent. The Hammett equation (Equation 1) provides the relationship between the substituent on the benzene...
    7 KB (746 words) - 19:01, 2 April 2023
  • Louis Plack Hammett (April 7, 1894 – February 9, 1987) was an American physical chemist. He is known for the Hammett equation, which relates reaction...
    4 KB (227 words) - 12:33, 15 May 2024
  • Thumbnail for Methoxy group
    This alkoxy group has the formula R−O−CH3. On a benzene ring, the Hammett equation classifies a methoxy substituent at the para position as an electron-donating...
    4 KB (413 words) - 18:03, 21 June 2024
  • effects on a reaction equilibrium or rate using the Hammett equation (1): Hammett developed this equation from equilibrium constants from the dissociation...
    11 KB (1,276 words) - 10:34, 17 May 2024
  • chemical bond. In organic chemistry, σ symbolizes the sigma constant of Hammett equation. In alchemy, Σ was sometimes used to represent sugar. In computer science...
    16 KB (2,095 words) - 21:20, 14 November 2024
  • constants and equilibrium constant is known as the Winstein-Holness equation. The Curtin–Hammett principle applies to systems in which different products are...
    29 KB (3,757 words) - 04:10, 15 November 2024
  • (ρ) Resistivity (ρ) Rho meson (ρ+, ρ−, ρ0) General quantum states Hammett Equation, ρ is used to represent the reaction constant, this is independent...
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  • Dashiell Hammett Hammett Prize Hammett, Georgia, a community in the United States Hammett acidity function Hammett equation, based on the Hammett substituent...
    1 KB (197 words) - 04:08, 5 October 2020
  • include inductive effects, mesomeric effects, and hydrogen bonding. Hammett type equations have frequently been applied to the estimation of pKa. The quantitative...
    103 KB (11,513 words) - 22:40, 15 October 2024
  • relationships (QSAR) or linear free energy relationships (LFER) such as the Hammett equation. A variant of the UNIFAC system can also be used to estimate octanol-water...
    12 KB (1,459 words) - 02:40, 10 May 2024
  • articles published between 1962 and 2009 in addition to other materials. Hammett equation Craig plot David Weininger Coats, Eugene; Seydel, Joachim; Leo, Albert...
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  • Thumbnail for Nariman Mehta
    [citation needed] Mehta's 1952 dissertation was titled I. Use of the Hammett equation in the prediction of product ratios in the Schmidt reaction of unsymmetrical...
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  • electronic substituent constant for activation of substituted arenes in the Hammett equation σ, a measure of a material's electrical conductivity ability Cross...
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  • carboxylic group. For benzoic acids, the effect is quantified by the Hammett equation: log ⁡ K K 0 = σ ρ {\displaystyle \log {\frac {K}{K_{0}}}=\sigma \rho...
    5 KB (509 words) - 11:32, 8 November 2024
  • effect. Inductive effects can be expressed quantitatively through the Hammett equation, which describes the relationship between reaction rates and equilibrium...
    10 KB (1,258 words) - 14:05, 18 November 2024
  • Thumbnail for Imine
    over vitrimer-like mechanics – tuneable dynamic motifs based on the Hammett equation in polyimine materials". Chemical Science. 12 (1): 293–302. doi:10...
    24 KB (2,710 words) - 22:36, 16 November 2024
  • Thumbnail for Craig plot
    plotting the sigma constants of the Hammett equation versus hydrophobicity plotting the steric terms of the Taft equation against hydrophobicity Quantitative...
    1 KB (110 words) - 09:35, 23 January 2024
  • relationships that have been used to quantify these effects, of which the Hammett equation is the best known. Kabachnik Parameters are group electronegativities...
    35 KB (4,360 words) - 15:05, 21 October 2024
  • Thumbnail for 4,4'-Oxydianiline
    over vitrimer-like mechanics – tuneable dynamic motifs based on the Hammett equation in polyimine materials". Chemical Science. 12 (1): 293–302. doi:10...
    5 KB (319 words) - 15:18, 26 April 2022
  • catalysis equation Hammett equation Taft equation Swain–Lupton equation Grunwald–Winstein equation Yukawa–Tsuno equation Edwards equation Marcus equation Bell–Evans–Polanyi...
    6 KB (774 words) - 17:33, 29 March 2024
  • as 1 for methyl bromide). This equation was modeled after the Hammett equation. However, both the Swain–Scott equation and the Brønsted relationship make...
    10 KB (1,372 words) - 13:19, 31 May 2023
  • Thumbnail for Terephthalaldehyde
    over vitrimer-like mechanics – tuneable dynamic motifs based on the Hammett equation in polyimine materials". Chemical Science. 12 (1): 293–302. doi:10...
    6 KB (563 words) - 12:18, 29 April 2024
  • Thumbnail for 4-Hydroxybenzoic acid
    It can be found in the pollen of Pinus densiflora. The Hammett equation describes a linear free-energy relationship relating reaction rates...
    20 KB (1,925 words) - 13:57, 21 August 2024
  • higher alkanes. A still very interesting application is the Hammett equation, Taft equation and pKa prediction methods. The biological activity of molecules...
    43 KB (4,323 words) - 15:18, 19 May 2024
  • Thumbnail for Bent's rule
    substituent constants are similar in principle to σ values from the Hammett equation, as an increasing value corresponds to a greater electron-withdrawing...
    38 KB (4,250 words) - 13:50, 4 October 2024
  • over vitrimer-like mechanics – tuneable dynamic motifs based on the Hammett equation in polyimine materials". Chemical Science. 12 (1): 293–302. doi:10...
    8 KB (888 words) - 00:51, 26 June 2024