In organic chemistry, the Hammett equation describes a linear free-energy relationship relating reaction rates and equilibrium constants for many reactions...
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the Hammett equation. While the Hammett equation accounts for how field, inductive, and resonance effects influence reaction rates, the Taft equation also...
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as the Henderson–Hasselbalch equation are no longer valid due to the variations of the activity coefficients. The Hammett acidity function is used in fields...
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Yukawa–Tsuno equation, first developed in 1959, is a linear free-energy relationship in physical organic chemistry. It is a modified version of the Hammett equation...
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respect to Y, the measure of ionizing power of the solvent. The Hammett equation (Equation 1) provides the relationship between the substituent on the benzene...
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Louis Plack Hammett (April 7, 1894 – February 9, 1987) was an American physical chemist. He is known for the Hammett equation, which relates reaction...
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This alkoxy group has the formula R−O−CH3. On a benzene ring, the Hammett equation classifies a methoxy substituent at the para position as an electron-donating...
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effects on a reaction equilibrium or rate using the Hammett equation (1): Hammett developed this equation from equilibrium constants from the dissociation...
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chemical bond. In organic chemistry, σ symbolizes the sigma constant of Hammett equation. In alchemy, Σ was sometimes used to represent sugar. In computer science...
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constants and equilibrium constant is known as the Winstein-Holness equation. The Curtin–Hammett principle applies to systems in which different products are...
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(ρ) Resistivity (ρ) Rho meson (ρ+, ρ−, ρ0) General quantum states Hammett Equation, ρ is used to represent the reaction constant, this is independent...
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Dashiell Hammett Hammett Prize Hammett, Georgia, a community in the United States Hammett acidity function Hammett equation, based on the Hammett substituent...
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include inductive effects, mesomeric effects, and hydrogen bonding. Hammett type equations have frequently been applied to the estimation of pKa. The quantitative...
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Octanol-water partition coefficient (section Equations)
relationships (QSAR) or linear free energy relationships (LFER) such as the Hammett equation. A variant of the UNIFAC system can also be used to estimate octanol-water...
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articles published between 1962 and 2009 in addition to other materials. Hammett equation Craig plot David Weininger Coats, Eugene; Seydel, Joachim; Leo, Albert...
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[citation needed] Mehta's 1952 dissertation was titled I. Use of the Hammett equation in the prediction of product ratios in the Schmidt reaction of unsymmetrical...
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electronic substituent constant for activation of substituted arenes in the Hammett equation σ, a measure of a material's electrical conductivity ability Cross...
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carboxylic group. For benzoic acids, the effect is quantified by the Hammett equation: log K K 0 = σ ρ {\displaystyle \log {\frac {K}{K_{0}}}=\sigma \rho...
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effect. Inductive effects can be expressed quantitatively through the Hammett equation, which describes the relationship between reaction rates and equilibrium...
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over vitrimer-like mechanics – tuneable dynamic motifs based on the Hammett equation in polyimine materials". Chemical Science. 12 (1): 293–302. doi:10...
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plotting the sigma constants of the Hammett equation versus hydrophobicity plotting the steric terms of the Taft equation against hydrophobicity Quantitative...
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relationships that have been used to quantify these effects, of which the Hammett equation is the best known. Kabachnik Parameters are group electronegativities...
35 KB (4,360 words) - 15:05, 21 October 2024
over vitrimer-like mechanics – tuneable dynamic motifs based on the Hammett equation in polyimine materials". Chemical Science. 12 (1): 293–302. doi:10...
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catalysis equation Hammett equation Taft equation Swain–Lupton equation Grunwald–Winstein equation Yukawa–Tsuno equation Edwards equation Marcus equation Bell–Evans–Polanyi...
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as 1 for methyl bromide). This equation was modeled after the Hammett equation. However, both the Swain–Scott equation and the Brønsted relationship make...
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over vitrimer-like mechanics – tuneable dynamic motifs based on the Hammett equation in polyimine materials". Chemical Science. 12 (1): 293–302. doi:10...
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It can be found in the pollen of Pinus densiflora. The Hammett equation describes a linear free-energy relationship relating reaction rates...
20 KB (1,925 words) - 13:57, 21 August 2024
higher alkanes. A still very interesting application is the Hammett equation, Taft equation and pKa prediction methods. The biological activity of molecules...
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substituent constants are similar in principle to σ values from the Hammett equation, as an increasing value corresponds to a greater electron-withdrawing...
38 KB (4,250 words) - 13:50, 4 October 2024
over vitrimer-like mechanics – tuneable dynamic motifs based on the Hammett equation in polyimine materials". Chemical Science. 12 (1): 293–302. doi:10...
8 KB (888 words) - 00:51, 26 June 2024