Hydrogen-bond catalysis is a type of organocatalysis that relies on use of hydrogen bonding interactions to accelerate and control organic reactions....

In chemistry, homogeneous catalysis is catalysis where the catalyst is in same phase as reactants, principally by a soluble catalyst in a solution. In...

step v = 2k1[NO]2[O2]. An example of heterogeneous catalysis is the reaction of oxygen and hydrogen on the surface of titanium dioxide (TiO2, or titania)...

oxidizer in rocketry. Hydrogen peroxide is a reactive oxygen species and the simplest peroxide, a compound having an oxygen–oxygen single bond. It decomposes...

squaramide catalysis describes the use of squaramides to accelerate and stereochemically alter organic transformations. The effects arise through hydrogen-bonding...

see the article on hydrogen bond catalysis.) The concept of utilizing the counteranion as the source of chirality in catalysis was first proposed by...

as hydrogen and carbon dioxide. Other possible applications of MOFs are in gas purification, in gas separation, in water remediation, in catalysis, as...

σ-Bond Complexes", Kluwer Academic/Plenum Publishers: New York, 2001 Gallezot, Pierre. "Hydrogenation – Heterogeneous" in Encyclopedia of Catalysis, Volume...

another, or the same, molecular entity. Like a hydrogen bond, the result is not a formal chemical bond, but rather a strong electrostatic attraction....

mechanics through the exploration of its energetics and chemical bonding. Hydrogen gas was first produced artificially in the early 16th century by reacting...

Low-barrier hydrogen bonds have been proposed to be relevant to enzyme catalysis in two types of circumstance. Firstly, a low-barrier hydrogen bond in a charge...

table, PnB catalysis may be appealing due to a balance between steric repulsion and polarisability factors. As for halogen and chalocogen bonding interactions...

strong hydrogen bond), and such effects do not contribute significantly to catalysis. A metal ion in the active site participates in catalysis by coordinating...

catalysis is catalysis where the phase of catalysts differs from that of the reagents or products. The process contrasts with homogeneous catalysis where...

groups or hydrogen atoms. The amide group is called a peptide bond when it is part of the main chain of a protein, and an isopeptide bond when it occurs...

0240. Hartwig, John (2010). Organotransition Metal Chemistry: From Bonding to Catalysis. New York: University Science Books. p. 1160. ISBN 978-1-938787-15-7...

formonitrile. Hydrogen cyanide is a linear molecule, with a triple bond between carbon and nitrogen. The tautomer of HCN is HNC, hydrogen isocyanide.[citation...

entails the net addition of a formyl group (−CHO) and a hydrogen atom to a carbon-carbon double bond. This process has undergone continuous growth since its...

In organic chemistry, Lewis acid catalysis is the use of metal-based Lewis acids as catalysts for organic reactions. The acids act as an electron pair...

Hashiguchi (2001-11-01). "Metal−Ligand Bifunctional Catalysis: A Nonclassical Mechanism for Asymmetric Hydrogen Transfer between Alcohols and Carbonyl Compounds"...

some experiments with muons incident on a hydrogen bubble chamber at Berkeley in 1956, observed muon-catalysis of exothermic p–d, proton and deuteron, nuclear...

A glycosidic bond or glycosidic linkage is a type of ether bond that joins a carbohydrate (sugar) molecule to another group, which may or may not be another...

relative to the open, linear bond. While the closed C-H-C bond has not been isolated or studied, it is well established that hydrogen-bridged metals prefer the...

agostic interactions are stronger than most hydrogen bonds. Agostic bonds sometimes play a role in catalysis by increasing 'rigidity' in transition states...

suggesting that there is hardly any backbonding to the silicon from hydrogen on a dangling bond. It also appeared that the Si-Si and Si-H bonds are about equally...

crystal engineering, self-assembly, catalysis, transport, sensing, templation, and drug design. Chalcogen bonding is comparable to other forms of σ-hole...

mimicking reactive intermediates in gold catalysis. While these complexes are sometimes depicted with a Au-C double bond, representing the sigma donation of...

Amine-thiourea Catalysts Based on Saccharides. Organocatalysis Hydrogen-bond catalysis Squaramide catalysis Christian M. Kleiner, Peter R. Schreiner (2006). "Hydrophobic...

the development of the Jacobsen epoxidation and other work in selective catalysis. Jacobsen was born on February 22, 1960, in New York City. Jacobsen attended...

and organic substrates. Oxidation catalysis is conducted by both heterogeneous catalysis and homogeneous catalysis. In the heterogeneous processes, gaseous...