Metal nitrosyl complexes are complexes that contain nitric oxide, NO, bonded to a transition metal. Many kinds of nitrosyl complexes are known, which vary...

Nitric oxide can serve as a ligand forming metal nitrosyl complexes or just metal nitrosyls. These complexes can be viewed as adducts of NO+, NO−, or some...

nitrito complexes by base-hydrolysis of electrophilic metal nitrosyls. Nitro complexes also catalyze the oxidation of alkenes. Metal nitrito complexes figure...

turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transition metals (elements like titanium that...

N-methoxydiazeniumdiolate. Nitric oxide reacts with transition metals to give complexes called metal nitrosyls. The most common bonding mode of nitric oxide is the...

form homoleptic and mixed ligand complexes that are analogous to the metal carbonyls.[citation needed] Metal nitrosyls, compounds featuring NO ligands...

In coordination chemistry, metal ammine complexes are metal complexes containing at least one ammonia (NH3) ligand. "Ammine" is spelled this way for historical...

Metal nitrido complexes are coordination compounds and metal clusters that contain an atom of nitrogen bound only to transition metals. These compounds...

chloride is used to prepare metal nitrosyl complexes. With molybdenum hexacarbonyl, NOCl gives the dinitrosyldichloride complex: Mo(CO)6 + 2 NOCl → MoCl2(NO)2...

NOBF4 reacts with some metal carbonyl complexes to yield related metal nitrosyl complexes. In some cases, [NO]+ does not bind the metal nucleophile but acts...

The related pentamethylcyclopentadienyl complex (C5(CH3)5)NiNO is also known. Cyclopentadienyl nickel nitrosyl was the subject of several patents as a...

part of cell signalling. Coordination of NO to transition metals to give metal nitrosyl complexes is also referred to as nitrosylation. Nitrosation Mannick...

the simplest metal nitrosyls. It is highly toxic, reminiscent of the same property for nickel tetracarbonyl. Cobalt tricarbonyl nitrosyl is prepared by...

SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metal nitrosyl complexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...

dioxide and with halogens to give nitrosyl halides. It also reacts with transition metal compounds to give nitrosyl complexes, most of which are deeply coloured...

the reaction of nitrous acid (HNO2) and secondary amines, although other nitrosyl sources (e.g. N 2O 4, NOCl, RONO) have the same effect: HONO + R2NH → R2N-NO...

classes of protein. Nitric oxide to a transition metal ion like iron or copper, forming metal nitrosyl complexes. Typical cases involve the nitrosylation of...

wide variety of coordination complexes by binding to metal ions in several ways. Two examples are the red nitrito complex [Co(NH3)5(ONO)]2+ is metastable...

redox reaction of nitrosonium and the metal can give rise to nitrogen oxide which forms strong metal nitrosyl complexes; nitronium ions (NO2+) are similarly...

(2002). "Photoinduced Linkage Isomers of Transition-Metal Nitrosyl Compounds and Related Complexes". Chemical Reviews. 102 (4): 861–883. doi:10.1021/cr000031c...

PETN—"around 50 times less than was used—would be enough to blast a hole in a metal plate twice the thickness of an aircraft's skin". In contrast, according...

thiolate ligands are cysteinyl residues or glutathione. These metal nitrosyl complexes have attracted much attention because they serve as biochemical...

SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metal nitrosyl complexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...

can be used to oxidize several transition metal and main group element complexes. The first metal nitrosyl cation was prepared using the PFAA's [Al(Opftb)4]−...

SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metal nitrosyl complexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...

functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one...

Transition metal sulfate complexes or sulfato complexes are coordination complexes with one or more sulfate ligands. Sulfate binds to metals through one...

SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metal nitrosyl complexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...

Nitrosonium tetrafluoroborate, also called nitrosyl tetrafluoroborate, is a chemical compound with the chemical formula NOBF4. This colourless solid is...

salt is the inorganic compound with the formula K2[Fe2S2(NO)4]. This metal nitrosyl was first described by Zacharie Roussin in 1858, making it one of the...