(Cyclopentadienyl)titanium trichloride is an organotitanium compound with the formula (C5H5)TiCl3. It is a moisture sensitive orange solid. The compound...
4 KB (365 words) - 20:11, 6 August 2024
the polymerization of alkenes. (Cyclopentadienyl)titanium trichloride "Trichloro(pentamethylcyclopentadienyl)titanium(IV) 446289". Sigma-Aldrich. King...
3 KB (200 words) - 23:34, 20 February 2023
dissolves in the presence of basic ligands to give adducts. (Cyclopentadienyl)titanium trichloride, which exists as a monomer. Engelhardt, L. M.; Papasergio...
2 KB (171 words) - 15:50, 26 December 2023
organometallic chemistry of titanium typically starts from TiCl4. An important reaction involves sodium cyclopentadienyl to give titanocene dichloride...
19 KB (1,732 words) - 00:16, 20 June 2024
chemistry but still prominent are many derivatives of (cyclopentadienyl)titanium trichloride, (C5H5)TiCl3. This piano-stool complex is obtained by the...
18 KB (1,866 words) - 09:45, 4 November 2023
Titanocene dichloride (redirect from Dichloridobis(η5-cyclopentadienyl)titanium)
Bis(η5-Cyclopentadienyl) Titanium(IV), Zirconium(IV), Molybdenum(IV), and Tungsten(IV)". Cyclometallapolysulfanes (and Selanes) of Bis(η5-Cyclopentadienyl)...
21 KB (1,771 words) - 20:25, 6 August 2024
the reaction of titanium tetrachloride with LiCp*. An intermediate in this synthesis is (pentamethylcyclopentadienyl)titanium trichloride. Reduction of...
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C4H9Li → Cp*Li + C4H10 Synthesis of (pentamethylcyclopentadienyl)titanium trichloride: Cp*Li + TiCl4 → Cp*TiCl3 + LiCl Synthesis of (pentamethylcyclopentadienyl)iron...
11 KB (841 words) - 13:04, 24 August 2024
C10H10Ti [Ti(η5-C5H5)2Cl2] is properly named dichloridobis(η5-cyclopentadienyl)titanium NOT titanocene dichloride In polynuclear compounds with metal-metal...
37 KB (3,872 words) - 07:12, 10 May 2024
polymerized the 7-oxo norbornene derivative using ruthenium trichloride, osmium trichloride as well as tungsten alkylidenes. They identified a Ru(II) carbene...
39 KB (4,096 words) - 05:27, 16 January 2024
Magnesocene (category Cyclopentadienyl complexes)
Magnesocene, also known as bis(cyclopentadienyl)magnesium(II) and sometimes abbreviated as MgCp2, is an organometallic compound with the formula Mg(η5-C5H5)2...
14 KB (1,600 words) - 20:49, 14 November 2023
carbon monoxide, phosphorus trifluoride, phosphine, and phosphorus trichloride to make adducts like (BF2)3B•AsH3, (BF2)3B•CO, (BF2)3B•PF3, (BF2)3B•PH3...
14 KB (1,433 words) - 10:51, 23 March 2024
cyclopentadienide in diethyl ether to form the trigonal planar gallium cyclopentadienyl complex GaCp3. Gallium(I) forms complexes with arene ligands such as...
74 KB (8,763 words) - 18:59, 30 October 2024
organized in pairs, as seen also for molybdenum trichloride. TcBr3 does not adopt the structure of either trichloride phase. Instead it has the structure of molybdenum...
83 KB (9,002 words) - 03:36, 25 October 2024
organized in pairs, as seen also for molybdenum trichloride. TcBr3 does not adopt the structure of either trichloride phase. Instead it has the structure of molybdenum...
69 KB (7,701 words) - 06:02, 28 October 2024
including many nitrates, nitrites, cyanides, thiocyanates, metal cyclopentadienyl complexes and metal bis(trimethylsilyl)amides. Most ammonium salts...
139 KB (14,938 words) - 16:08, 30 October 2024
and does not form the TlF− 4 complex anion in aqueous solution. The trichloride and tribromide disproportionate just above room temperature to give the...
52 KB (5,787 words) - 22:55, 29 September 2024
Berkelium forms a trigonal (η5–C5H5)3Bk metallocene complex with three cyclopentadienyl rings, which can be synthesized by reacting berkelium(III) chloride...
61 KB (7,479 words) - 15:54, 31 August 2024
Richard (1971). "Crystal structures of americium trichloride hexahydrate and berkelium trichloride hexahydrate". Inorganic Chemistry. 10: 147. doi:10...
77 KB (9,268 words) - 15:13, 11 October 2024
silver perbromate AgCl silver chloride 7783-90-6 AgCl3Cu2 dicopper silver trichloride 69569-03-5 AgClO3 silver chlorate 7783-92-8 AgClO4 silver perchlorate...
183 KB (107 words) - 22:11, 6 September 2024
of oxidation states can be expanded via the use of sterically bulky cyclopentadienyl ligands, in this way many lanthanides can be isolated as Ln(II) compounds...
107 KB (10,324 words) - 11:27, 28 October 2024
hexamethylbenzene with a superelectrophilic mixture of methyl chloride and aluminum trichloride (a source of Meδ⊕Cl---δ⊖AlCl3) gives heptamethylbenzenium cation, one...
41 KB (4,014 words) - 00:47, 5 May 2024
of Glasses, Elsevier, Oxford, ISBN 0-08-043958-6 Rausch MD 1960, 'Cyclopentadienyl Compounds of Metals and Metalloids', Journal of Chemical Education...
246 KB (27,797 words) - 13:04, 27 August 2024
Lucas, C. R.; Labinger, J. A.; Schwartz, J. (1990). "Dichlorobis(η 5 -Cyclopentadienyl) Niobium(IV)". In Angelici, Robert J. (ed.). Inorganic Syntheses. Vol...
80 KB (8,565 words) - 09:59, 26 October 2024
(III) oxidation states. Fe[N(SiMe3)2]3 can be prepared by treating iron trichloride with lithium bis(trimethylsilyl)amide and is paramagnetic as the high...
31 KB (3,034 words) - 14:29, 20 September 2024