Metal acetylacetonates are coordination complexes derived from the acetylacetonate anion (CH 3COCHCOCH− 3) and metal ions, usually transition metals. The...

alkyl). Sodium acetylacetonate, Na(acac), is the precursor to many acetylacetonate complexes. A general method of synthesis is to treat a metal salt with acetylacetone...

early as the 16th century, but it was not until Antonio de Ulloa published a report on a new metal of Colombian origin in 1748 that it began to be investigated...

rise to another more significant chemical product. Since several years metal-organic compounds are widely used as molecular precursors for the chemical...

hdl:1874/20149. S2CID 94240406. Indictor N., Brill W. F. (1965). "Metal Acetylacetonate Catalyzed Epoxidation of Olefins with t-Butyl Hydroperoxide". J...

derivative is titanium isopropoxide, which is a monomer. Titanium bis(acetylacetonate)dichloride results from treatment of titanium tetrachloride with excess...

LiCH3 → Li2[FeCl4] + 0.5 CH3CH3 To a significant extent, iron(III) acetylacetonate and related beta-diketonate complexes are more widely used than FeCl3...

(1997). "Reduction of [NBu4] [AuCl4] to [NBu4] [AuCl2] with Sodium Acetylacetonate". Australian Journal of Chemistry. 50 (7): 775. doi:10.1071/C97029...

weakly (the one trans to the vanadyl center). An example is vanadyl acetylacetonate (V(O)(O2C5H7)2). In this complex, the vanadium is 5-coordinate, distorted...

is a common precursor to other vanadyl derivatives, such as vanadyl acetylacetonate: [V(O)(H2O)4]SO4 + 2 C5H8O2 + Na2CO3 → [V(O)(C5H7O2)2] + Na2SO4 + 5...

(2017). "An Historic and Scientific Study of the Properties of Metal(III) Tris-acetylacetonates". Structural Chemistry. 28: 201–212. doi:10.1007/s11224-016-0864-0...

(2017). "An historic and scientific study of the properties of metal(III) tris-acetylacetonates". Struct Chem. 28: 201–212. doi:10.1007/s11224-016-0864-0....

capable energy storage solutions: demonstration with an iron–chromium acetylacetonate chemistry". Journal of Materials Chemistry A. 5 (26): 13457–13468....

functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one...

3-diketone–containing compound acetylacetone (which forms acetylacetonate complexes with metals), the entire skeleton of curcumin is in resonance with the...

weakly (the one trans to the vanadyl center). An example is vanadyl acetylacetonate (V(O)(O2C5H7)2). In this complex, the vanadium is 5-coordinate, distorted...

André Thomas Cahours at the École Polytechnique. In 1876, he studied acetylacetonates in the laboratory of Cahours. He spent some years travelling to Egypt...

Lipophilic europium complexes often feature acetylacetonate-like ligands, such as EuFOD. Europium metal reacts with all the halogens: 2 Eu + 3 X2 → 2...

from 1,3-ketones can serve as ligand s to form metal acetylacetonate coordination complexes. In the DeMayo reaction 1,3-diketones react with alkenes in...

that the use of lithium derivatives (chloride, acetylacetonates or alcoholates) catalyses the halogen-metal exchange in the preparation of organomagnesians...

Lutetium compounds are compounds formed by the lanthanide metal lutetium (Lu). In these compounds, lutetium generally exhibits the +3 oxidation state...

co-workers used a modified Turkevitch-Frens procedure using sodium acetylacetonate as the reducing agent and sodium citrate as the stabilizer. Another...

PMID 20521290. In this reaction the Grignard reagent combines with iron acetylacetonate and tributylphosphine to give an ill-defined aryliron intermediate...

zinc dithiophosphate and the zinc finger complex (below). The zinc acetylacetonate complex, Zn(acac)2 is interesting. As the ligand is bidentate a tetrahedral...

iron-platinum nanoparticles were coated with sulfur reacted with cadmium acetylacetonate, trioctylphosphineoxide, and hexadecane-1,2-diol at 100 °C to produce...

heated nickel oxalate dihydrate dehydrates at 258° and decomposes to Ni metal over 316 °C. Double oxalate salts where oxalate is a ligand on the nickel...

higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod. Europium(II) oxide can be obtained by the...

a μ2-bridged ligand across two metal atoms. With transition metals and actinides, bridging is likely unless the metal atom is mostly enclosed in a ligand...

A. Chretien; G. Varga (1936). "Le chlorure de manganèse trivalent". Bulletin de la Société Chimique de France (in French) (3): 2385–2394. Nachtigall...