In chemistry, acylation is a broad class of chemical reactions in which an acyl group (R−C=O) is added to a substrate. The compound providing the acyl...

Friedel–Crafts reactions are of two main types: alkylation reactions and acylation reactions. Both proceed by electrophilic aromatic substitution. In commercial...

S-Acylation is the process of chemically linking a molecule to another molecule via a thioester bond. Protein S-acylation is a sub-type of S-acylation where...

The Kostanecki acylation is a method used in organic synthesis to form chromones or coumarins by acylation of O-hydroxyaryl ketones with aliphatic acid...

electrophiles, which results in the formation of 1,3-diketones (Stork acylation). It is also effective for activated sp3 alkyl electrophiles, including...

quickly to prevent isomerisation. HATU is commonly encountered in amine acylation reactions (i.e., amide formation). Such reactions are typically performed...

based synthesis, the preferred route to wholly aromatic polyesters. In acylation, the acid begins as an acyl chloride, and thus the polycondensation proceeds...

is present in C3adesArg form. C3adesArg is more commonly named ASP or acylation-stimulating-protein due to its marked stimulating action on triacylglycerol...

Aniline (from Portuguese anil 'indigo shrub', and -ine indicating a derived substance) is an organic compound with the formula C6H5NH2. Consisting of a...

ketones, such as those formed in a Friedel-Crafts acylation. The two-step sequence of Friedel-Crafts acylation followed by Clemmensen reduction constitutes...

alkylation). Analogously, this reaction can be used as an effective means of acylation. A variety of alkylating and acylating agents including benzylic, allylic...

In chemistry, amines (/əˈmiːn, ˈæmiːn/, UK also /ˈeɪmiːn/) are compounds and functional groups that contain a basic nitrogen atom with a lone pair. Formally...

AlCl3 is a common Lewis-acid catalyst for Friedel-Crafts reactions, both acylations and alkylations. Important products are detergents and ethylbenzene. These...

The N-terminus (also known as the amino-terminus, NH2-terminus, N-terminal end or amine-terminus) is the start of a protein or polypeptide, referring to...

aromatic sulfonation and acylation and alkylating Friedel-Crafts reactions. It further consists of alkylation and acylation. In electrophilic substitution...

Candida antarctica lipase can be used to catalyze the regioselective acylation of flavonoids. Phytochemical List of antioxidants in food List of phytochemicals...

resolution acylation of amines. With 10 mol% (-)-PPY* in chloroform at –50 °C, good to very good selectivities were observed in the acylation of amines...

3-position.[citation needed] Acylation generally occurs at the 2-position, through the use of various methods. Acylation with acid anhydrides and acid...

1139/G10-063. PMID 20962881. Magee T, Seabra MC (April 2005). "Fatty acylation and prenylation of proteins: what's hot in fat". Current Opinion in Cell...

(eukaryotic) and aIF5A (archaeal) (see above). acylation, e.g. O-acylation (esters), N-acylation (amides), S-acylation (thioesters) acetylation, the addition...

demonstrated catalytic properties in alkylation, isomerization, oligomerization, acylation, ketalization, esterification, hydrolysis of sugars and ethers, and oxidation...

promote reactions of carboxylic acids, including Friedel-Crafts acylation and acylation of other unsaturated compounds. Other electrophilic aromatic substitution...

prepared by one of three methods: amide bond formation, N-alkylation and C-acylation. Most commonly 2,5-diketopiperazines are generated by cyclisation of dipeptides...

chemist, mostly known for developing the Friedel–Crafts alkylation and acylation reactions with Charles Friedel in 1876. James Crafts, the son of Royal...

alternative industrial synthesis developed at Celanese involves firstly direct acylation of phenol with acetic anhydride in the presence of hydrogen fluoride to...

Aminoacylation is the process of adding an aminoacyl group to a compound. Acylation tRNA aminoacylation Transfer RNA-like structures Jafarnejad, Seyed Mehdi;...

intermediate). Bases, such as pyridine or N,N-dimethylformamide, catalyze acylations. These reagents activate the acyl chloride via a nucleophilic catalysis...

the ring. Many groups can be attached to the ring, via halogenation, acylation, sulfonation, and related processes. Phenol is so strongly activated that...

Similarly, the Friedel-Crafts acylation is a related example of electrophilic aromatic substitution. The reaction involves the acylation of benzene (or many other...

Meldrum's acid at this position, through reactions such as alkylation and acylation. For example, deprotonation and reaction with a simple alkyl halide (R−Cl)...