Allyl chloride is the organic compound with the formula CH2=CHCH2Cl. This colorless liquid is insoluble in water but soluble in common organic solvents...
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or of everyday importance, for example, allyl chloride. Allylation is any chemical reaction that adds an allyl group to a substrate. A site adjacent to...
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allyl chloride route is that it does not generate salt. Also avoiding chloride-containing intermediates is the "acetoxylation" of propylene to allyl acetate:...
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alkylating agent. Allyl bromide is more reactive but more expensive than allyl chloride, and these considerations guide its use. Allyl bromide is produced...
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the adduct of cycloheptatriene and dimethyl acetylenedicarboxylate. Allyl chloride undergoes dehydrohalogenation upon treatment with the base sodium amide...
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extender in food packaging.: 118–120 Allyl isothiocyanate is produced commercially by the reaction of allyl chloride and potassium thiocyanate: CH2=CHCH2Cl...
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Epichlorohydrin (redirect from Glycidyl chloride)
and elastomers. Epichlorohydrin is traditionally manufactured from allyl chloride in two steps, beginning with the addition of hypochlorous acid, which...
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and a green chemical. Allyl alcohol is also produced primarily from allyl chloride, but production via the hydrolysis of allyl acetate route avoids the...
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breath" is attributed to its presence. It is prepared by the reaction of allyl chloride with sodium hydroxide and methanethiol. CH2=CHCH2Cl + NaOH (aq) + CH3SH...
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lacrymator. It is an alkylating agent that is used in organic synthesis. Allyl chloride Propargyl Propargyl alcohol *Merck Index, 11th Edition, 7820 M. Olomucki...
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Allyl halides are organic halides containing an allyl group. Allyl halides include: Allyl chloride Allyl bromide Allyl iodide Allyl fluoride [Wikidata]...
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Vinyl chloride is an organochloride with the formula H2C=CHCl. It is also called vinyl chloride monomer (VCM) or chloroethene. This colorless compound...
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Chlorine (section Hydrogen chloride)
methylene chloride, chloroform, vinylidene chloride, trichloroethylene, perchloroethylene, allyl chloride, epichlorohydrin, chlorobenzene, dichlorobenzenes...
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prepared by reduction of chromic chloride by lithium aluminium hydride to which was added benzaldehyde and allyl chloride: Compared to Grignard reactions...
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tetrachloropalladate (prepared from palladium(II) chloride and sodium chloride), and allyl chloride. 2 Na2PdCl4 + 2 CH2=CHCH2Cl + 2 CO + 2 H2O...
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Allylamine (redirect from Allyl amine)
are produced by the treating allyl chloride with ammonia followed by distillation. Or by the reaction of allyl chloride with hexamine. Pure samples can...
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hexadienoic acids, which are available via a nickel-catalyzed reaction of allyl chloride, acetylene, and carbon monoxide. The route used commercially, however...
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PolyDADMAC (redirect from Polydiallyldimethylammonium chloride)
Calgon Corp. The monomer DADMAC is formed by reacting two equivalents of allyl chloride with dimethylamine. PolyDADMAC is then synthesized by radical polymerization...
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with allyl and other ligands. Examples include (η3-allyl)Mn(CO)4 and CpPd(allyl). bis(allyl)nickel bis(allyl)palladium bis(allyl)platinum tris(allyl)chromium...
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before decomposition into free iodine becomes apparent. Allyl Allyl alcohol Allyl bromide Allyl chloride Bertleff, Werner (2000). "Carbonylation". Ullmann's...
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ethers – from the condensation of glycols acrylic acid acrylic polymers allyl chloride epichlorohydrin – chloro-oxirane; used in epoxy resin formation epoxy...
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reactions. One example is the Friedel–Crafts alkylation of benzene by allyl chloride to yield beta chloropropylbenzene which is then reacted with ammonia...
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colorless liquid, produced by free-radical addition of hydrogen bromide to allyl chloride. It is used as an alkylating agent to install the –(CH2)3Cl and –(CH2)3–...
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colorless liquid and a lacrymator. Its properties are similar to those of allyl chloride. It is a strong alkylating agent used to install isobutenyl groups....
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precursors to fatty amine derivatives. Related free radical additions to allyl chloride and styrene give 1-bromo-3-chloropropane and phenylethylbromide, respectively...
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phenyllithium should be free of lithium halides. The corresponding reaction of allyl chloride and phenyllithium main affords cyclopropylbenzene. Methylcyclopropene...
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Allylmagnesium bromide (redirect from Allyl magnesium bromide)
hexadiene. Allyl chloride can also be used in place of the bromide to give allylmagnesium chloride. These reagents are used to prepare metal allyl complexes...
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ethylene chloride 83.7 70.5 63 chloroform 61.1 59.4 93 1.403 carbon tetrachloride 76.8 65.1 84.2 1.377 allyl chloride 45.7 44 95 n-propyl chloride 46.7 45...
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vinylogous: In allyl compounds, where the next carbon is saturated but substituted once, allylic rearrangement and related reactions are observed. Allyl Grignard...
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Triallylamine (and mono- and diallyl amines) is produced by the treating allyl chloride with ammonia. Allylamines have particularly weak α-CH bonds, being near...
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