• The Barton decarboxylation is a radical reaction in which a carboxylic acid is converted to a thiohydroxamate ester (commonly referred to as a Barton ester)...
    6 KB (666 words) - 07:07, 9 August 2024
  • Hunsdiecker-Kochi reactions. The Barton decarboxylation is an unusual radical reductive decarboxylation. As described above, most decarboxylations start with a carboxylic...
    12 KB (1,289 words) - 15:17, 27 October 2024
  • Harold Richard Barton and Stuart W. McCombie. This deoxygenation reaction is a radical substitution. In the related Barton decarboxylation the reactant...
    8 KB (749 words) - 06:50, 9 September 2024
  • Thumbnail for Derek Barton
    chemistry such as the Barton reaction, the Barton decarboxylation, and the Barton-McCombie deoxygenation. The newly built Barton Science Centre at Tonbridge...
    11 KB (859 words) - 12:36, 22 September 2024
  • lithium acetate when performed with micellular surfactants. Barton decarboxylation Barton–McCombie deoxygenation Li, J. J. (2014-01-30). "Hunsdiecker–Borodin...
    15 KB (1,389 words) - 17:36, 26 September 2024
  • nearly quantitatively by photochemical decarboxylation of the thiohydroxamate ester (the Barton decarboxylation). The synthesis of the octaphenyl derivative...
    19 KB (1,786 words) - 21:27, 19 October 2024
  • Thumbnail for Organotin chemistry
    in radical chemistry (e.g. radical cyclizations, Barton–McCombie deoxygenation, Barton decarboxylation, etc.). An organotin compound is commercially applied...
    24 KB (2,623 words) - 18:21, 19 September 2024
  • reaction Barton decarboxylation Barton reaction Barton–Kellogg reaction Barton–McCombie reaction, Barton deoxygenation Barton-Zard Synthesis Barton vinyl...
    37 KB (3,419 words) - 11:08, 19 October 2024
  • radical chemistry and was responsible for the development of the Barton decarboxylation reaction, for which he was awarded the degree of Docteur es Sciences...
    7 KB (663 words) - 15:25, 27 September 2024
  • Thumbnail for 4,7-Dihydroisoindole
    tosylacetylene which includes Diels-Alder reaction, Barton-Zard synthesis and thermal decarboxylation was reported. Though it was expected that under acidic...
    4 KB (379 words) - 21:43, 26 July 2023
  • Thumbnail for Enterochromaffin cell
    non-rate limiting L-amino acid decarboxylase converts 5-HTP to 5-HT by decarboxylation. Following synthesis, 5-HT is then stored in vesicles by vesicular...
    16 KB (1,999 words) - 04:15, 29 October 2024
  • chemistry used to form azoles. One synthetic route to pyrrole involves the decarboxylation of ammonium mucate, the ammonium salt of mucic acid. The salt is typically...
    33 KB (3,142 words) - 17:38, 21 February 2024
  • instance the Norrish reaction, the Hunsdiecker reaction and certain decarboxylations. For fragmentations taking place in mass spectrometry see mass spectrum...
    5 KB (677 words) - 00:02, 31 January 2024
  • Thumbnail for Jasmonic acid
    can also be conjugated to amino acids in some biological contexts. Decarboxylation affords the related fragrance jasmone. Demole, E.; Lederer, E.; Mercier...
    12 KB (1,157 words) - 02:17, 23 October 2024
  • Thumbnail for Chloroplast
    to form the majority of the lipid is from acetyl-CoA, which is the decarboxylation product of pyruvate. Pyruvate may enter the plastid from the cytosol...
    189 KB (19,141 words) - 15:05, 28 October 2024
  • and chemicals. Partial deoxygenation is effected by dehydration and decarboxylation. Oxygen groups can also be removed by the reductive coupling of ketones...
    6 KB (582 words) - 19:37, 27 February 2024
  • Thumbnail for Dihydrolipoyl transacetylase
    The pyruvate dehydrogenase complex is responsible for the pyruvate decarboxylation step that links glycolysis to the citric acid cycle. This involves...
    21 KB (2,487 words) - 00:19, 8 June 2024
  • Thumbnail for Vinyl iodide functional group
    to decompose to alkene and iodide. The Baker group have shown using decarboxylation, elimination can occur. List of functional groups Group contribution...
    28 KB (3,003 words) - 02:54, 18 December 2023
  • Thumbnail for Enzyme inhibitor
    can catalyse the decarboxylation of DFMO instead of ornithine (see the "DFMO inhibitor mechanism" diagram). However, this decarboxylation reaction is followed...
    104 KB (11,579 words) - 19:29, 18 September 2024
  • Thumbnail for Ronald Breslow
    site of reactivity of thiamin diphosphate in enzymes that promote the decarboxylation of pyruvate – based on his pioneering use of proton NMR with small...
    19 KB (2,073 words) - 08:52, 13 September 2024
  • Thumbnail for Serine C-palmitoyltransferase
    intermediate that attacks the incoming thioester substrate. Following decarboxylation and lysine attack, the product 3-keto-dihydrosphingosine is released...
    18 KB (1,755 words) - 20:13, 16 October 2024