Borane–tetrahydrofuran is an adduct derived from borane and tetrahydrofuran (THF). These solutions, which are colorless, are used for reductions and hydroboration...

air. Solutions containing borane dimethylsulfide and borane–tetrahydrofuran are commercially available; in tetrahydrofuran a stabilising agent is added...

dimerizing instantly to form diborane, B2H6. Its adduct borane–tetrahydrofuran and borane–dimethylsulfide are useful in hydroboration reactions. Greenwood...

complexed borane reagent that is used for hydroborations and reductions. The advantages of BMS over other borane reagents, such as borane-tetrahydrofuran, are...

Tetrahydrofuran (THF), or oxolane, is an organic compound with the formula (CH2)4O. The compound is classified as heterocyclic compound, specifically...

boranes are less common. Tert-butylamine borane (tBuNH2→BH3) Phosphine-borane (R3P→BH3) Borane dimethylsulfide ((CH3)2S→BH3) Borane–tetrahydrofuran (THF→BH3)...

initial adducts proceed rapidly to give other products. For example, borane-tetrahydrofuran, which often behaves equivalently to diborane, degrades to borate...

catalyst is used along with borane-tetrahydrofuran (THF), borane-dimethylsulfide, borane-N,N-diethylaniline, or diborane as the borane source. Enantioselective...

following incomplete listing. Oxidation with iodine in tetrahydrofuran gives borane–tetrahydrofuran, which can reduce carboxylic acids to alcohols. Partial...

5-cyclooctadiene and borane usually in ethereal solvents, for example: The compound is commercially available as a solution in tetrahydrofuran and as a solid...

suppliers. It can be synthesized by combining sodium cyanide and borane tetrahydrofuran. BH3·thf + NaCN → NaBH3CN + thf Since sodium cyanoborohydride is...

lithium borohydride (LiBH4) as a catalyst (or reaction of borane–tetrahydrofuran or borane–(dimethyl sulfide) in the presence of sodium borohydride):...

synthesized via hydroboration of 2,3- and 2,5-dihydrofuran employing various borane reagents and chiral 3-hydroxytetrahydrofurans have also been prepared by...

distances are all 2.142 Å. Upon reacting tris(silox)Ta with excess borane–tetrahydrofuran (BH3·THF), tris(silox)·BH3 is obtained: IR spectrum of tris(silox)·BH3...

(CH3CH2)3B or (C2H5)3B, abbreviated Et3B. It is soluble in organic solvents tetrahydrofuran and hexane. Triethylborane is prepared by the reaction of trimethyl...

as lithium aluminium hydride, or with NaBH4 and I2 (forming the borane–tetrahydrofuran complex). In both cases the valinol produced can be subsequently...

on hydroboration employed diborane as a source of BH3. Usually however, borane dimethylsulfide complex BH3S(CH3)2 (BMS) is used instead. It can be obtained...

formation of adducts between the Lewis acid borane and the oxygen atom in the Lewis bases, tetrahydrofuran (THF): BH3·O(CH2)4 or diethyl ether: BH3·O(CH3CH2)2...

the reaction is as follows: Tetrahydrofuran (THF) is the archetypal solvent used for hydroboration. In the first step, borane (BH3) adds to the double bond...

trifluoride, i.e. borane diethyl etherate (BF3·O(CH2CH3)2). Ethers also coordinate to the Mg center in Grignard reagents. Tetrahydrofuran is more basic than...

normally handled as solutions in solvents such as diethyl ether or tetrahydrofuran using air-free techniques. Grignard reagents are complex with the magnesium...

61 p. 4472 (1996) The Rapido Reaction of Carboxylic Acids with Borane-Tetrahydrofuran. A Remarkably Convenient Procedure for the Selective Conversion...

composed of Na+ and H− ions, in contrast to molecular hydrides such as borane, silane, germane, ammonia, and methane. It is an ionic material that is...

tri-tert-butoxyaluminium hydride in tetrahydrofuran followed by hydroboration with borane in THF yields the borane 5 (only one substituent displayed for...

Curran (November 2007). "Manipulation of a Schlenk Line: Preparation of Tetrahydrofuran Complexes of Transition-Metal Chlorides" (abstract page). Journal of...

amine boranes and their derivatives. Ignition of the amine borane(s) forms boron nitride (BN) and hydrogen gas. In addition to ammonia borane (H3BNH3)...

methanol, ethanol, propanol, isopropanol, acetone, glycerol, 1,4-dioxane, tetrahydrofuran, sulfolane, acetaldehyde, dimethylformamide, dimethoxyethane, dimethyl...

produced as gaseous products. When Cp2Zr(CH3)2 reacts with borane dissolved in tetrahydrofuran, a borohydro group inserts into the zirconium carbon bond...

group 13 hydrides. In solution—typically in ethereal solvents such tetrahydrofuran or diethyl ether—aluminium hydride forms complexes with Lewis bases...

1000 bar. In 1994, Tsuneto et al. used lithium electrodeposition in tetrahydrofuran to synthesize ammonia at more moderate pressures with reasonable Faradaic...