• Thumbnail for Collins reagent
    Collins reagent is the complex of chromium(VI) oxide with pyridine in dichloromethane. This metal-pyridine complex, a red solid, is used to oxidize primary...
    5 KB (474 words) - 17:12, 28 November 2022
  • Thumbnail for Reagent
    substance. Examples include the Collins reagent, Fenton's reagent, and Grignard reagents. In analytical chemistry, a reagent is a compound or mixture used...
    7 KB (752 words) - 21:49, 29 February 2024
  • Thumbnail for Jones oxidation
    has subsided because milder, more selective reagents have been developed, e.g. Collins reagent. Jones reagent is a solution prepared by dissolving chromium...
    8 KB (924 words) - 20:13, 17 July 2024
  • This is a list of inorganic and organic reagents commonly used in chemistry. Reagents are "substances or compounds that are added to a system in order...
    15 KB (264 words) - 18:51, 14 August 2022
  • more selective than Collins reagent in oxidations of alcohols. The above reagents represent improvements over the older Jones reagent, a solution of chromium...
    14 KB (1,578 words) - 10:23, 11 August 2024
  • Thumbnail for Collins oxidation
    oxidations by the use of Collins reagent, a complex of chromium(VI) oxide with pyridine in dichloromethane. The mechanism of the Collins oxidation is a relatively...
    5 KB (478 words) - 05:51, 12 March 2023
  • principal reagents are Collins reagent, PDC, and PCC. These reagents represent improvements over inorganic chromium(VI) reagents such as Jones reagent. Cr(VI)-pyridine...
    10 KB (1,163 words) - 15:58, 17 November 2023
  • Benedict's reagent (often called Benedict's qualitative solution or Benedict's solution) is a chemical reagent and complex mixture of sodium carbonate...
    8 KB (912 words) - 11:35, 1 May 2024
  • Thumbnail for Cornforth reagent
    pyridinium chlorochromate and Collins reagent. Because of their toxicity, these reagents are rarely used nowadays. The Cornforth reagent is prepared by slow addition...
    8 KB (766 words) - 13:23, 24 May 2024
  • Thumbnail for Sarett oxidation
    introduction of the Collins oxidation. The active ingredient in both the Sarett reagent is identical to that in the so-called "Collins reagent", i.e. the pyridine...
    8 KB (845 words) - 12:43, 19 December 2023
  • and pyridinium chloride. This reagent converts primary alcohols to the corresponding aldehydes (R–CHO). Collins reagent is an adduct of chromium trioxide...
    15 KB (1,357 words) - 22:57, 23 February 2024
  • Thumbnail for Pyridine
    Pyridine (section Reagents)
    imidazole. Pyridinium chlorochromate, pyridinium dichromate, and the Collins reagent (the complex of chromium(VI) oxide) are used for the oxidation of alcohols...
    76 KB (7,682 words) - 11:46, 30 August 2024
  • Thumbnail for Alcohol (chemistry)
    for the oxidation of secondary alcohols to ketones. These include Collins reagent and Dess-Martin periodinane. The direct oxidation of primary alcohols...
    34 KB (3,818 words) - 08:17, 6 August 2024
  • Claisen rearrangement Claisen–Schmidt condensation Clemmensen reduction Collins reagent Combes quinoline synthesis Conia reaction Conrad–Limpach synthesis...
    38 KB (3,423 words) - 21:05, 20 August 2024
  • Collman's reagent (Na2Fe(CO)4) Collins reagent (CrO3 / py / CH2Cl2) Condy's crystals (KMnO4) Corey–Chaykovsky reagent (O=S(CH2)Me2) Cornforth reagent ([pyH]2[Cr2O7])...
    11 KB (852 words) - 15:53, 23 April 2024
  • Thumbnail for Sodium trifluoromethanesulfinate
    reagent for introducing trifluoromethyl groups onto electron-rich aromatic compounds by Langlois; this reagent is also known as the Langlois reagent....
    4 KB (290 words) - 14:52, 24 January 2024
  • Thumbnail for Transition metal pyridine complexes
    solvents, and susceptible to alkylation by organolithium and Grignard reagents. Thus CoCl2(py)4 has proven very useful in organocobalt chemistry and NiCl2(py)4...
    21 KB (1,958 words) - 11:36, 21 July 2024
  • Dess-Martin periodinane, 2-Iodoxybenzoic acid) chromium reagents (e.g., Pyridinium chlorochromate, Collins reagent) ruthenium oxides (e.g., Tetrapropylammonium perruthenate)...
    6 KB (729 words) - 16:41, 12 June 2023
  • Thumbnail for Alpha-Pyrrolidinopentiophenone
    rats. α-PVP gives no reaction with the Marquis reagent. It gives a grey/black reaction with the Mecke reagent. α-PVP may be quantified in blood, plasma or...
    20 KB (1,745 words) - 22:56, 15 August 2024
  • Spanidin The BOC derivative of 4-aminobutanol is oxidized with Collins reagent to afford the aldehyde. Condensation with the ylide obtained from reaction...
    8 KB (757 words) - 02:14, 9 December 2020
  • Thumbnail for Methanesulfonyl azide
    Methanesulfonyl azide is the azide of methanesulfonic acid. It is used as a reagent for the production of diazo compounds. Methanesulfonyl azide can be prepared...
    6 KB (532 words) - 01:01, 21 August 2024
  • Thumbnail for Catalysis
    as such, it is not really a catalyst, but a reagent. For example, osmium tetroxide (OsO4) is a good reagent for dihydroxylation, but it is highly toxic...
    46 KB (5,233 words) - 21:48, 27 July 2024
  • Thumbnail for Xylenol orange
    Xylenol orange (category Analytical reagents)
    Xylenol orange is an organic reagent, most commonly used as a tetrasodium salt as an indicator for metal titrations. When used for metal titrations, it...
    4 KB (216 words) - 17:37, 19 February 2024
  • Thumbnail for TNT
    compound with the formula C6H2(NO2)3CH3. TNT is occasionally used as a reagent in chemical synthesis, but it is best known as an explosive material with...
    38 KB (4,088 words) - 15:52, 28 August 2024
  • Thumbnail for Microbacterium
    Microbacteriaceae. Microbacteria are common contaminants of laboratory reagents, which can lead to their being misrepresented in microbiome data. Microbacterium...
    15 KB (1,091 words) - 18:40, 3 December 2023
  • Thumbnail for Gymnopus dryophilus
    crowded. The spore powder is white; the buff spores do not react in Melzer's reagent. The bald stem ranges from 2–8 cm (3⁄4–3+1⁄8 in) long by 3–6 mm 3–6 mm...
    7 KB (768 words) - 11:43, 27 July 2024
  • Thumbnail for Amide
    amides do not react usefully with carbon nucleophiles. Instead, Grignard reagents and organolithiums deprotonate an amide N-H bond. Tertiary amides do not...
    24 KB (2,322 words) - 18:40, 26 August 2024
  • eco-friendly, and practical to use with a variety of water-soluble reagents. A wide variety of reagents can be used for the Suzuki coupling, e.g., aryl or vinyl...
    34 KB (3,842 words) - 03:10, 9 August 2024
  • Thumbnail for Doxycycline
    members of the tetracycline class of antibiotics are often used as research reagents in in vitro and in vivo biomedical research experiments involving bacteria...
    96 KB (9,316 words) - 11:25, 30 August 2024
  • Thumbnail for Quinoline
    ISSN 0039-7881. Sherman, Angela R.; Caron, Antoine; Collins, Shawn K. (2001). "Quinoline". Encyclopedia of Reagents for Organic Synthesis. pp. 1–4. doi:10.1002/047084289X...
    15 KB (1,365 words) - 00:56, 30 June 2024