Claisen (German pronunciation: [ˈʁaɪnɐ ˈklaɪzn̩]; 14 January 1851 – 5 January 1930) was a German chemist best known for his work with condensations of...
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Darzens reaction (redirect from Darzens–Claisen reaction)
The Darzens reaction (also known as the Darzens condensation or glycidic ester condensation) is the chemical reaction of a ketone or aldehyde with an...
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inhibiting the reaction. Benzoin condensation Bouveault–Blanc reduction Claisen condensation Dieckmann condensation Bouveault, L.; Locquin, R. (1905)...
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Dibenzylideneacetone (category CS1 German-language sources (de))
often performed in organic chemistry classes, and is called Claisen-Schmidt condensation. Prolonged exposure to sunlight initiates [2+2] cycloadditions...
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List of organic reactions (category CS1 German-language sources (de))
elimination Ciamician–Dennstedt rearrangement Claisen condensation Claisen rearrangement Claisen–Schmidt condensation Clemmensen reduction Collins reagent Combes...
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Crossed Claisen condensations, in which the enolate and nucleophile are different esters, are also possible. An intramolecular Claisen condensation is called...
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so-called name reactions, such as Knoevenagel condensation, Wittig reaction, Claisen–Schmidt condensation, Schotten–Baumann reaction, and Diels–Alder reaction...
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Ortho ester (category CS1 German-language sources (de))
alkaline conditions) to salts of formic acid and methanol. The Johnson–Claisen rearrangement is the reaction of an allylic alcohol with an ortho ester...
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catalyzes a Claisen condensation with the bound tetraketide. However, since module 4 contains an inactive KR domain, the β-ketone condensation product is...
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starts with a Claisen condensation of vanillin and acetone, producing dehydrozingerone. Afterwards the product reacts in an aldol condensation with hexanal...
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chalcone synthase, undergoing successive condensation reactions and ultimately a ring-closing Claisen condensation to afford naringenin chalcone. The corresponding...
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Aldol reaction (category CS1 German-language sources (de))
Baylis–Hillman reaction Ivanov reaction Reformatsky reaction Claisen-Schmidt condensation It is typically best to minimize heat for this reaction. As removal...
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atom. Enols are commonly used in condensation reactions, including the Claisen condensation and the aldol condensation reactions.[citation needed] Examples...
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(substituted) 1,5-diketones. Classically, 1,3-diketones are prepared by the Claisen condensation of a ketone with an ester. Malonic acid and its esters are the parent...
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second carbon from the carboxylic acid. They generally form by the Claisen condensation. The presence of the keto group at the beta position allows them...
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Ethyl acetate (category Articles with German-language sources (de))
unreactive toward ethanol: CH3CO2C2H5 + NaOH → C2H5OH + CH3CO2Na In the Claisen condensation, anhydrous ethyl acetate and strong bases react to give ethyl acetoacetate:...
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elimination of α-bromo-cyclopentanone using lithium carbonate and Claisen condensation-decarboxylation-isomerization cascades of unsaturated diesters as...
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Phenobarbital (category CS1 German-language sources (de))
phenylacetic acid ethyl ester. Subsequently, this ester undergoes cross Claisen condensation using diethyl oxalate, giving diethyl ester of phenyloxobutandioic...
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diethyl oxalate and 3,3-dimethylpentanoic acid, which reacted by Claisen condensation to yield diketocamphoric acid. Methylation with methyl iodide and...
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bound citryl-coenzyme A intermediate in a 2-step process (aldol-Claisen condensation followed by the hydrolysis of citryl-CoA). Citrate synthase enzymes...
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Mevalonate synthesis begins with the beta-ketothiolase-catalyzed Claisen condensation of two molecules of acetyl-CoA to produce acetoacetyl CoA. The following...
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are generally less severe than with other similar drugs. The Claisen-Schmidt condensation between 3-(methoxymethoxy)benzaldehyde [13709-05-2] (1) and cyclohexanone...
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with 3-bromopropene to produce phenylallyl ether and subsequently its Claisen rearrangement, gives rise to 2-hydroxyphenylacetic acid, which, through...
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The fatty acids are synthesized by a series of decarboxylative Claisen condensation reactions from acetyl-CoA and malonyl-CoA. Following each round of...
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acceptors. Unlike 1,3-dicarbonyls, which are easily accessed through the Claisen condensation, or 1,5-dicarbonyls, which are commonly made using a Michael reaction...
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Griseofulvin (category CS1 German-language sources (de))
cyclization/aromatization, using cyclase/aromatase, respectively, through a Claisen and aldol condensation to form the benzophenone intermediate. The benzophenone intermediate...
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Knorr pyrrole synthesis (category CS1 German-language sources (de))
2-oximinoacetoacetate and 2-methyl-3-oxobutanal, in turn made by the Claisen condensation of 2-butanone with ethyl formate. George Kleinspehn reported that...
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chemical reactions (among which is a rare chemical reaction known as a Claisen condensation), going through four intermediates before resulting in saxitoxin...
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discussed in this article is the simplest member. Bamberger rearrangement Claisen rearrangement Cresol Fries rearrangement Polyphenol "Front Matter". Nomenclature...
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diastereoselectivity. Camphorsultam was used as a chiral auxiliary for the asymmetric Claisen rearrangement. In the presence of butylated hydroxytoluene (BHT) used as...
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