Cyclopentadienyl magnesium bromide is a chemical compound with the molecular formula C5H5MgBr. The molecule consists of a magnesium atom bonded to a bromine...

chloride, and they are more soluble in relevant solvents. Cyclopentadienyl magnesium bromide undergoes a complex reaction with iron(III) chloride, resulting...

cyclopentadiene (C5H6). To that end, they reacted the Grignard compound cyclopentadienyl magnesium bromide in diethyl ether with ferric chloride as an oxidizer. However...

Zirconocene dibromide was prepared in 1953 by a reaction of the cyclopentadienyl magnesium bromide and zirconium(IV) chloride. In 1966, the dihydride Cp2ZrH2...

of magnesium have been produced in the form of Rieke magnesium. Examples of Grignard reagents are phenylmagnesium bromide and ethylmagnesium bromide. These...

presumed to be an intermediate formed in situ. Alternatively, cyclopentadienyl magnesium bromide could be reacted with osmium(IV) chloride, though this has...

named -um. Examples are tropylium and triphenylmethyl cations and the cyclopentadienyl anion. Haloalkanes are a class of molecule that is defined by a carbon–halogen...

bromides are produced by the action of aluminium bromide, hydrogen bromide, carbon tetrabromide, or a mixture of hydrogen bromide and thionyl bromide...

ethanidohydridoberyllium [Mg(η5-C5H5)2] named bis(η5-cyclopentadienyl)magnesium, or bis(η5-cyclopentadienido)magnesium Na(CHCH2) sodium ethenide (compositional name)...

synthesis, methyl bromide is treated with a suspension of lithium in diethyl ether. 2 Li + MeBr → LiMe + LiBr The lithium bromide forms a complex with...

16 and 18, respectively. Bis(allyl)nickel is prepared from allyl magnesium bromide and nickel chloride. Nickelocene NiCp2 with +2 Ni oxidation state...

number MgBr2 magnesium bromide 7789-48-2 Mg(BrO)2 magnesium hypobromite Mg(BrO2)2 magnesium bromite Mg(BrO3)2 magnesium bromate Mg(BrO4)2 magnesium perbromate...

flammable liquids with low melting points. Like indium, thallium cyclopentadienyl compounds contain thallium(I), in contrast to gallium(III). Thallium...

typically starts from TiCl4. An important reaction involves sodium cyclopentadienyl to give titanocene dichloride, TiCl2(C5H5)2. This compound and many...

clusters. Most of the work on organothorium compounds has focused on the cyclopentadienyl complexes and cyclooctatetraenyls. Like many of the early and middle...

1002/9780470132463.ch25. ISBN 9780470132463. Lucas, C. R. (1977). "Bis(η 5 -Cyclopentadienyl) [Tetrahydroborato(1−)]Titanium". Inorganic Syntheses. Vol. 17. p. 93...

oxidation state of 0 in one structure and −1 in the other. For the cyclopentadienyl anion C 5H− 5, the oxidation state of C is −1 + −⁠1/5⁠ = −⁠6/5⁠. The...

geometry. Most of the work on organothorium compounds has focused on the cyclopentadienyls and cyclooctatetraenyls. Like many of the early and middle actinides...

Berkelium forms a trigonal (η5–C5H5)3Bk metallocene complex with three cyclopentadienyl rings, which can be synthesized by reacting berkelium(III) chloride...

cycloaddition proceeds at ambient conditions with CoCp2(cod) (Cp = cyclopentadienyl, cod = 1,5-cyclooctadiene) as a catalyst, and can be performed even...

including many nitrates, nitrites, cyanides, thiocyanates, metal cyclopentadienyl complexes and metal bis(trimethylsilyl)amides. Most ammonium salts...

organoneptunium compounds are the cyclopentadienyl and cyclooctatetraenyl compounds and their derivatives. The trivalent cyclopentadienyl compound Np(C5H5)3·THF...

cyclooctatetraene ligands, with the chemical formula (η8-C8H8)2Am. A cyclopentadienyl complex is also known that is likely to be stoichiometrically AmCp3...

cyclopentadienide, NaC5H5, an important precursor to many transition metal cyclopentadienyl derivatives.: 265  Similarly, the alkali metals react with cyclooctatetraene...

state. Divalent (Tb2+) complexes are also known, usually with bulky cyclopentadienyl-type ligands. A few coordination compounds containing terbium in its...

limited. The best characterized organolanthanum compounds are the cyclopentadienyl complex La(C 5H 5) 3, which is produced by reacting anhydrous LaCl...

as lutetium (Lu). Moreover, Cp is frequently used today to mean the cyclopentadienyl ligand (C5H5). Primarily because cassiopeium (Cp) was (until 1949)...

polymeric, consisting of zigzag chains of alternating indium atoms and cyclopentadienyl complexes. Perhaps the best-known organoindium compound is trimethylindium...

complex KAm(COT)2 can be prepared by reacting K2COT and AmI3 in THF. A cyclopentadienyl complex is also known that is likely to be stoichiometrically AmCp3...

Prominent members of this class are complexes with CO, arene, and cyclopentadienyl ligands. The binary carbonyl Tc2(CO)10 is a white volatile solid. In...