• In organic chemistry, a cyclophane is a hydrocarbon consisting of an aromatic unit (typically a benzene ring) and a chain that forms a bridge between two...
    17 KB (1,857 words) - 21:31, 5 September 2024
  • Thumbnail for Catenane
    Catenane (category Cyclophanes)
    ether cyclophane based on para phenylene or naphthalene. X-ray diffraction shows that due to pi-pi interactions the aromatic group of the cyclophane is held...
    13 KB (1,377 words) - 00:03, 11 October 2024
  • Thumbnail for (2.2)Paracyclophane
    (2.2)Paracyclophane (category Cyclophanes)
    [2.2]Paracyclophane is a cyclophane that is applied in bio- and materials science. It was first synthesized by Brown and Farthing in 1949 by pyrolyzing...
    4 KB (236 words) - 14:52, 7 September 2024
  • Thumbnail for Superphane
    Superphane (category Cyclophanes)
    Superphane is a 6-fold bridged cyclophane with all arene positions in the benzene dimer taken up by ethylene spacers. The compound has been of some scientific...
    5 KB (478 words) - 17:16, 22 January 2023
  • Thumbnail for Xylylene
    p-Xylylene dimerizes with moderate efficiency to give p-cyclophane: Further heating of the p-cyclophane gives poly(para-xylylene). o-Xylylenes (o-quinodimethanes)...
    8 KB (834 words) - 21:36, 29 December 2023
  • Thumbnail for Cation–π interaction
    involved looking at the interactions of charged, nitrogenous molecules in cyclophane host–guest chemistry. It was found that even when anionic solubilizing...
    35 KB (4,104 words) - 14:03, 23 August 2024
  • include tetrahedranes, propellanes, cubane-type clusters, fenestranes and cyclophanes. March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure...
    2 KB (224 words) - 10:09, 6 June 2023
  • Figure 4. Cyclophane anthracene adduct...
    6 KB (782 words) - 13:31, 22 September 2024
  • Thumbnail for Meta-selective C–H functionalization
    or para- C-H functionalization does not work because the corresponding cyclophane-like cyclic pre-transition state is highly strained. Thus, while ortho-selectivity...
    17 KB (1,947 words) - 20:49, 22 July 2024
  • Thumbnail for Parylene
    during the coating process by evaporating the cyclic dimer [2.2]para-cyclophane at a relatively low temperature, then decomposing the vapor at 450–700 °C...
    39 KB (4,773 words) - 00:29, 19 March 2024
  • Staab (1978). "Versuche zur Darstellung zwitterionischer Donor-Acceptor-Cyclophane: Die diastereomeren 12,15-Bis(dimethylamino) - [2](2,5) - p...
    5 KB (465 words) - 17:27, 18 February 2024
  • (superatoms) of a simplified skeleton by multiatomic structures". Whilst the cyclophane name describes only a limited number of sub-structures of benzene rings...
    3 KB (323 words) - 20:56, 19 October 2023
  • Thumbnail for Molecular shuttle
    wire are bulky triisopropylsilyl groups. The bead is a tetracationic cyclophane based on two bipyridine groups and two para-phenylene groups. The bead...
    2 KB (233 words) - 20:21, 13 February 2024
  • Cylindrocyclophanes (category Cyclophanes)
    Cylindrocyclophanes are a class of cyclophane, a group of aromatic hydrocarbons composed of two benzene rings attached in a unique structure. Cylindrocyclophanes...
    10 KB (1,067 words) - 12:05, 23 July 2022
  • Thumbnail for Lythranidine
    Lythranidine (category Cyclophanes)
    first isolated from the plant Lythrum anceps. It contains a 17-membered cyclophane ring. Several laboratory syntheses have been reported. Fujita, E; Fuji...
    4 KB (166 words) - 21:03, 11 July 2024
  • Thumbnail for Tubocurarine chloride
    Tubocurarine chloride (category Cyclophanes)
    Tubocurarine (also known as d-tubocurarine or DTC) is a toxic benzylisoquinoline alkaloid historically known for its use as an arrow poison. In the mid-1900s...
    19 KB (2,043 words) - 16:59, 9 September 2023
  • Thumbnail for Supramolecular chemistry
    therefore convenient for use in supramolecular systems. More complex cyclophanes, and cryptands can be synthesised to provide more tailored recognition...
    34 KB (3,703 words) - 14:02, 21 October 2024
  • Thumbnail for Fraser Stoddart
    distinctive colouring has led to coining the term 'little blue box' for cyclophane, an important π-acceptor used to synthesize mechanically bonded structures...
    40 KB (3,227 words) - 00:49, 14 August 2024
  • Thumbnail for Seyferth–Gilbert homologation
    1021/jo501803f Lidija Bondarenko; Ina Dix; Heino Hinrichs; Henning Hopf (2004). "Cyclophanes. Part LII:1 Ethynyl[2.2]paracyclophanes – New Building Blocks for Molecular...
    6 KB (529 words) - 03:16, 22 March 2024
  • Oregon. He is known for his work on aromatic compounds, particularly cyclophanes, and a name reaction, the Boekelheide reaction, is named after him. Boekelheide...
    7 KB (516 words) - 01:10, 16 May 2024
  • Thumbnail for Cyclobis(paraquat-p-phenylene)
    Cyclobis(paraquat-p-phenylene) (category Cyclophanes)
    (formally a derivative of paraquat) belongs to the class of cyclophanes, and consists of aromatic units connected by methylene bridges. It is...
    9 KB (938 words) - 15:02, 7 September 2024
  • Thumbnail for Aromaticity
    Aromatic properties are tested to the limit in a class of compounds called cyclophanes. A special case of aromaticity is found in homoaromaticity where conjugation...
    22 KB (2,764 words) - 20:37, 8 October 2024
  • Thumbnail for Α-Cyclodextrin
    "Surveying macrocyclic chemistry: from flexible crown ethers to rigid cyclophanes". Chemical Society Reviews. 46 (9): 2367–2650. doi:10.1039/c7cs00185a...
    5 KB (372 words) - 23:07, 6 March 2024
  • Thumbnail for Supramolecular catalysis
    PMID 9122156. Diederich, F.; Mattei, P. (1997). "Catalytic Cyclophanes. Part XI. A Flavo-thiazolio-cyclophane as a Biomimetic Catalyst for the Preparative-scale...
    36 KB (3,798 words) - 14:53, 8 October 2024
  • Thumbnail for Macrocycle
    "Surveying macrocyclic chemistry: from flexible crown ethers to rigid cyclophanes". Chemical Society Reviews. 46 (9): 2459–2478. doi:10.1039/c7cs00185a...
    27 KB (3,288 words) - 22:37, 24 August 2024
  • Thumbnail for Stevens rearrangement
    elimination. In one application a double-Stevens rearrangement expands a cyclophane ring. The ylide is prepared in situ by reaction of the diazo compound...
    6 KB (697 words) - 02:43, 6 April 2023
  • Thumbnail for N-Formylpiperidine
     451. Lidija Bondarenko; Ina Dix; Heino Hinrichs; Henning Hopf (2004). "Cyclophanes. Part LII:1 Ethynyl[2.2]paracyclophanes – New Building Blocks for Molecular...
    3 KB (157 words) - 20:03, 27 December 2022
  • Calixarene (category Cyclophanes)
    IUPAC definition calixarenes: Originally macrocyclic compounds capable of assuming a basket (or 'calix') shaped conformation. They are formed from p-hydrocarbyl...
    19 KB (2,105 words) - 07:28, 26 May 2024
  • Thumbnail for Cryptophane
    Cryptophane (category Cyclophanes)
    Cryptophanes are a class of organic supramolecular compounds studied and synthesized primarily for molecular encapsulation and recognition. One possible...
    6 KB (403 words) - 15:34, 11 October 2024
  • Thumbnail for Strychnine total synthesis
    The key step was an inverse electron demand Diels–Alder reaction of cyclophane 1 by heating in N,N-diethylaniline (dinitrogen is expulsed) followed by...
    39 KB (4,087 words) - 03:50, 29 February 2024