• The principle of detailed balance can be used in kinetic systems which are decomposed into elementary processes (collisions, or steps, or elementary reactions)...
    36 KB (5,847 words) - 13:18, 3 September 2024
  • Thumbnail for Kinetic theory of gases
    reversibility), the kinetic theory is also connected to the principle of detailed balance, in terms of the fluctuation-dissipation theorem (for Brownian motion)...
    51 KB (7,763 words) - 21:50, 14 September 2024
  • Thumbnail for Kirchhoff's law of thermal radiation
    (around 470 nm), which is why it looks green. By the principle of detailed balance, it is also a poor emitter of green light. In other words, if a material...
    27 KB (3,710 words) - 21:06, 7 July 2024
  • account for this. Hořava originally imposed the theory to satisfy the detailed balance condition which considerably reduces the number of terms in the action...
    5 KB (592 words) - 01:28, 25 May 2024
  • predicting the behavior of systems that obey detailed balance. Given that a system obeys detailed balance, the theorem is a proof that thermodynamic fluctuations...
    27 KB (4,179 words) - 13:36, 29 August 2024
  • Thumbnail for Einstein coefficients
    cannot be affected by the presence or absence of other excited atoms. Detailed balance (valid only at equilibrium) requires that the change in time of the...
    32 KB (4,646 words) - 01:25, 27 April 2024
  • are somewhere between detailed balance and global balance equations. Any solution π {\displaystyle \pi } to the local balance equations is always a solution...
    8 KB (924 words) - 22:23, 1 November 2023
  • Thumbnail for T-symmetry
    microscopic equations implies two important laws: the principle of detailed balance and the Onsager reciprocal relations. T-symmetry of the microscopic...
    31 KB (4,234 words) - 03:54, 23 March 2024
  • Thumbnail for Perovskite solar cell
    33%. Values of the detailed balance limit are available in tabulated form and a MATLAB program for implementing the detailed balance model has been written...
    185 KB (20,955 words) - 19:36, 6 September 2024
  • According to Boltzmann, this microreversibility implies the principle of detailed balance for collisions: at the equilibrium ensemble each collision is equilibrated...
    9 KB (1,157 words) - 07:53, 17 December 2022
  • Thumbnail for Metropolis–Hastings algorithm
    {\displaystyle \pi (x)} . A sufficient but not necessary condition is detailed balance, which requires that each transition x → x ′ {\displaystyle x\to x'}...
    30 KB (4,535 words) - 20:02, 13 June 2024
  • Thumbnail for Shockley–Queisser limit
    In physics, the radiative efficiency limit (also known as the detailed balance limit, Shockley–Queisser limit, Shockley Queisser Efficiency Limit or SQ...
    44 KB (6,215 words) - 05:26, 24 March 2024
  • is an alternative to Metropolis–Hastings, which doesn't satisfy the detailed balance condition. Barker's algorithm does converge to the target distribution...
    16 KB (1,831 words) - 19:14, 30 August 2024
  • Thumbnail for Grigoriy Yablonsky
    Gorban, Yablonsky developed the theory of chemical thermodynamics and detailed balance in the limit of irreversible reactions. A simple scheme for the nonlinear...
    21 KB (2,363 words) - 03:15, 14 August 2024
  • forward and backward reactions are equal, a principle called detailed balance. Detailed balance is a property of the stoichiometric matrix N i j {\displaystyle...
    44 KB (7,596 words) - 01:53, 28 July 2024
  • A_{kk}P_{k}=-\sum _{\ell \neq k}(A_{\ell k}P_{k}).} The master equation exhibits detailed balance if each of the terms of the summation disappears separately at equilibrium—i...
    13 KB (1,870 words) - 21:43, 14 June 2024
  • Thumbnail for Discrete-time Markov chain
    and all states i and j. This condition is known as the detailed balance condition (or local balance equation). Considering a fixed arbitrary time n and using...
    25 KB (4,252 words) - 01:57, 27 June 2024
  • Thumbnail for Solar-cell efficiency
    ISSN 2542-4351. S2CID 247778421. Shockley William; Queisser Hans J (1961). "Detailed Balance Limit of Efficiency of p-n Junction Solar Cells". Journal of Applied...
    49 KB (5,937 words) - 11:05, 9 August 2024
  • Physical Review.[citation needed] In 1952 he proved the principle of semi-detailed balance for kinetics without microscopic reversibility. In 1953 he and the...
    11 KB (1,093 words) - 04:12, 9 August 2024
  • Thumbnail for Onsager reciprocal relations
    kinetics, the Onsager relations are closely connected to the principle of detailed balance and follow from them in the linear approximation near equilibrium....
    17 KB (2,568 words) - 19:29, 8 June 2024
  • same distribution, as long as the algorithm satisfies ergodicity and detailed balance. In both algorithms, for any change in energy, p ( Δ E ) ≠ 0 {\displaystyle...
    5 KB (752 words) - 00:47, 13 August 2024
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    defined for any Markov processes with reversible dynamics and the detailed balance property. In Boltzmann's 1896 Lectures on Gas Theory, he showed that...
    108 KB (13,957 words) - 13:14, 1 September 2024
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    }}{ds}}=\kappa _{\nu }\rho (B_{\nu }-I_{\nu }).} The principle of detailed balance states that, at thermodynamic equilibrium, each elementary process...
    141 KB (18,060 words) - 20:19, 28 August 2024
  • Thumbnail for Solar cell
    theoretical limit for an IB device with one midgap energy level using detailed balance. They assumed no carriers were collected at the IB and that the device...
    150 KB (17,048 words) - 03:32, 11 September 2024
  • in state μ. It then uses acceptance probabilities A(μ, ν) so that detailed balance is satisfied. If the new state ν is accepted, then we move to that...
    122 KB (19,712 words) - 16:30, 3 September 2024
  • they would also have to emit them in the right amount to maintain detailed balance. Time-independent solutions to field equations do not emit radiation...
    31 KB (3,980 words) - 14:46, 15 August 2024
  • Thumbnail for Random walk
    reversibility. Roughly speaking, this property, also called the principle of detailed balance, means that the probabilities to traverse a given path in one direction...
    55 KB (7,651 words) - 18:49, 13 September 2024
  • Thumbnail for Quantum dot solar cell
    in part alleviated by using multiple junction implementations). The detailed balance calculation shows that this efficiency can not exceed 33% if one uses...
    30 KB (3,867 words) - 00:12, 10 June 2024
  • (more than a semigroup); this gives rise to the physical principle of detailed balance. However, in the more general formalism of Dirac, the Hamiltonian is...
    27 KB (4,903 words) - 04:26, 29 August 2024
  • only satisfy a basic condition of balance in order for the equilibrium to be properly described, but detailed balance, a stronger condition, is usually...
    4 KB (403 words) - 14:05, 14 January 2024