In chemistry, a dihydrogen bond is a kind of hydrogen bond, an interaction between a metal hydride bond and an OH or NH group or other proton donor. With...

assembly is bent. The hydrogen bond can be compared with the closely related dihydrogen bond, which is also an intermolecular bonding interaction involving hydrogen...

minus one (as in dihydrogen, H2, with only one sigma bond, or ammonia, NH3, with 3 sigma bonds). There is no more than 1 sigma bond between any two atoms...

Dihydrogen phosphate is an inorganic ion with the formula [H2PO4]−. Phosphates occur widely in natural systems. These sodium phosphates are artificially...

a 1-electron bond is found in the dihydrogen cation, H+ 2. One-electron bonds often have about half the bond energy of a 2-electron bond, and are therefore...

A chemical bond is the association of atoms or ions to form molecules, crystals, and other structures. The bond may result from the electrostatic force...

example, the molecular orbital function for dihydrogen is an equal mixture of the covalent and ionic valence bond structures and so predicts incorrectly that...

1Σg+ for dihydrogen. Sometimes, the letter n is used to designate a non-bonding orbital. For a stable bond, the bond order defined as   bond order = (...

nitrate anion (NO−3), the bond order for each bond between nitrogen and oxygen is 4/3 (or 1.333333...). Bonding in dihydrogen cation H+2 can be described...

of the bond between the hydrogen and deuterium in HD complexes. For example, JHD is 43.2 Hz in HD but 33.5 Hz in W(HD)(CO)3(PiPr3)2. Dihydrogen complexes...

2-Norbornyl cation. Three-center four-electron bond 2-Norbornyl cation Dihydrogen complex I. Mayer (1989). "Bond orders in three-centre bonds: an analytical...

The dihydrogen cation or hydrogen molecular ion is a cation (positive ion) with formula H+ 2. It consists of two hydrogen nuclei (protons), each sharing...

Å, which can be compared with the H−H bonding distance of 0.74 Å. This interaction is called a dihydrogen bond. The original crystallographic analysis...

orbitals. When creating the molecule dihydrogen, the individual valence orbitals, 1s, either: merge in phase to get bonding orbitals, where the electron density...

capable of bonding with positively polarized hydrogen centres. This interaction, called dihydrogen bonding, is similar to hydrogen bonding, which exists...

ionic compounds (which water is not). Water portal Chemical bonding of water Dihydrogen monoxide parody Double distilled water Electromagnetic absorption...

10-Methacryloyloxydecyl dihydrogen phosphate (10-MDP, MDP Monomer) is a chemical compound used in dental adhesive materials. This organophosphate monomer...

(respectively 1.43 and 1.23 Å). The unusual C-O bond lengths are attributed to delocalized π bonding in the molecule's center and extraordinarily strong...

Trioxidane (systematically named dihydrogen trioxide,), also called hydrogen trioxide is an inorganic compound with the chemical formula H[O] 3H (can be...

is a gas of diatomic molecules with the formula H2, sometimes called dihydrogen, but more commonly called hydrogen gas, molecular hydrogen or simply hydrogen...

1016/s0065-3055(05)53006-5. ISBN 9780120311538. Kubas, G. J. (2001). Metal Dihydrogen and σ-Bond Complexes. New York: Kluwer Academic. ISBN 978-0-306-46465-2. Braga...

tautomer with the non-classical dihydrogen complexes containing a M-(η2-H2) group. Borderline hydrides exist with a bond character somewhere between the...

Waals interactions, an effect of the large electron clouds of polonium. Dihydrogen dichalcogenides have the chemical formula H2X2, and are generally less...

Disodium pyrophosphate is prepared by thermal condensation of sodium dihydrogen phosphate or by partial deprotonation of pyrophosphoric acid. Pyrophosphates...

Ductility in Organic Plastic Crystals: Role of Molecular Shape and Dihydrogen Bonding Interactions in Aminoboranes". Angewandte Chemie International Edition...

(A=3, N=0) (the common one). [DH2]+ = [2H1H2]+ (A=4, N=1) (deuterium dihydrogen cation). [D2H]+ = [2H21H]+ (A=5, N=2) (dideuterium hydrogen cation). D+3...

phosphate esters, e.g. triphenyl phosphate (O=P(−O−C6H5)3) and methyl dihydrogen phosphate (O=P(−O−CH3)(−OH)2) Pyrophosphoric (diphosphoric) acid forms...

hydroborated and then the resulting vinylborane-based FLP can then activate dihydrogen. A protodeborylation step releases the cis-alkene product, which is obtained...

above reaction is thermodynamically favored due to the high bond enthalpy of the Si–F bond in the side product. Protonation using simply fluoroantimonic...

complex. Formation of a trigonal bipyramidal dihydrogen intermediate is followed by cleavage of the H–H bond, due to electron back donation into the H–H...