of explosive materials can be explained on basis of HSAB theory. Ralph Pearson introduced the HSAB principle in the early 1960s as an attempt to unify...

and base are, with the Brønsted–Lowry theory being a subset of what acids and bases are, and the Arrhenius theory being the most restrictive. The concept...

Marcus theory — Lewis theory (successor to Brønsted–Lowry acid–base theory) — HSAB theory — Debye–Hückel theory — Thermodynamic theory of polymer elasticity...

Brønsted–Lowry acid. The classification into hard and soft acids and bases (HSAB theory) followed in 1963. The strength of Lewis acid-base interactions, as measured...

choice of reactants is guided by a solubility chart or lattice energy. HSAB theory can also be used to predict the products of a metathesis reaction. Salt...

at least two properties must be considered. For Pearson qualitative HSAB theory, the two properties are hardness and strength, while for Drago's quantitative...

Acid Base (HSAB) theory, the bare hydron is an infinitely hard Lewis acid. The hydron plays a central role in Brønsted–Lowry acid–base theory: a species...

strength at least two properties must be considered. For the qualitative HSAB theory the two properties are hardness and strength while for the quantitative...

assumptions of frontier molecular orbital theory (i.e., theory of HOMO–LUMO interactions) and hard soft acid base (HSAB) theory. Conceptually, it highlights the...

referred to as a Lewis base. As a refinement of acid-base interactions, the HSAB theory takes into account polarizability and size of ions. Subdivisions of inorganic...

phosphines than with amines. Later, Pearson proposed the theory of hard and soft acids and bases (HSAB theory). In this classification, class A metals are hard...

containing ligating atoms other than the lightest of their Periodic Group." HSAB theory, hard and soft (Lewis) acids and bases Weisstein, Eric Wolfgang (ed.)...

so strongly with mercury compounds. According to hard/soft acid/base (HSAB) theory, sulfur is a relatively soft (polarizable) atom. This explains the tendency...

reaction. This quantitative model is often discussed with the qualitative HSAB theory, which also seeks to rationalize the behavior of diverse acids and bases...

(ISBN 978-0471035589). A qualitative theory of hard and soft acids and bases (HSAB) was proposed in 1963 in an attempt to unify the theories of reactivity in inorganic...

4-addition is suppressed. The selectivity can be explained in terms of the HSAB theory: carbonyl groups require hard nucleophiles for 1,2-addition. The hardness...

reagents than with sulfonium reagents. One explanation based on the HSAB theory states that it is because sulfoxonium reagents have a less concentrated...

Lewis acids such as I2, phenol, and Al(CH3)3. Ammonia is a hard base (HSAB theory) and its E & C parameters are EB = 2.31 and CB = 2.04. Its relative donor...

at least two properties must be considered. For Pearson's qualitative HSAB theory the two properties are hardness and strength while for Drago's quantitative...

polarisability, allow GaCl3 to behave as a "soft acid" in terms of the HSAB theory. The strength of the bonds between gallium halides and ligands have been...

often stated to be related to the hardness of the element, within the HSAB theory (hard and soft (Lewis) acids and bases), but it has been shown that oxophilicity...

charge, bonded to a small negative ion with a high charge. More generally HSAB theory can be applied, whereby the compounds with the most ionic character are...

strengths) and that two parameters (or two properties) are needed (see HSAB theory and ECW model) to define acid and base strengths and that single parameter...

development of coordination chemistry. Hard metal cations, as classified by HSAB theory, tend to form N-bonded complexes (isothiocyanates), whereas class B or...

O-bonded is an "L-X ligand", akin to bidentate carboxylate. With respect to HSAB theory, the N bonding mode is more common for softer metal centers. The O and...

bonds between the electron pair donors and the hydrogen atoms of water. HSAB theory describes water as both a weak hard acid and a weak hard base, meaning...

oxygen or nitrogen than with second-row sulfur or phosphorus. In terms of HSAB theory Zn2+ is a hard acid. In aqueous solution an octahedral complex, [Zn(H2O)6]2+...

a pseudohalide (X). Carboxylates are classified as hard ligands, in HSAB theory. Structures of Selected Metal Acetates Basic ferric acetate Silver acetate...

the hydroperoxide anion. In 1962, Edwards and Pearson (the latter of HSAB theory) introduced the phrase alpha effect for this anomaly. He offered the...

explain the different behavior of the intermediate. In terms of the HSAB-theory an explanation might be given. In 1975 Masamune calculated in the non-substituted...