A halogen addition reaction is a simple organic reaction where a halogen molecule is added to the carbon–carbon double bond of an alkene functional group...
7 KB (801 words) - 18:25, 20 April 2021
Halogenation (redirect from Chlorination reaction)
halogenation, and halogen addition reaction. The nature of the substrate determines the pathway. The facility of halogenation is influenced by the halogen. Fluorine...
10 KB (1,112 words) - 15:24, 12 June 2024
like the triiodide ion. Look up halogen in Wiktionary, the free dictionary. Halogen bond Halogen addition reaction Halogen lamp Halogenation Interhalogen...
52 KB (5,499 words) - 06:28, 7 July 2024
Haloalkane (redirect from Halogen derivative)
Alkenes also react with halogens (X2) to form haloalkanes with two neighboring halogen atoms in a halogen addition reaction. Alkynes react similarly...
20 KB (2,413 words) - 13:06, 14 April 2024
Typical electrophilic additions to alkenes with reagents are: Halogen addition reactions: X2 Hydrohalogenations: HX Hydration reactions: H2O Hydrogenations:...
2 KB (243 words) - 11:21, 17 April 2024
Halohydrin (redirect from Halohydrin formation reaction)
electrophilic addition, with the halogen acting as electrophile. In that regard, it resembles the halogen addition reaction and proceeds with anti addition, leaving...
7 KB (835 words) - 23:18, 10 January 2024
Alkene (section Addition to the unsaturated bonds)
Similar to hydrogen, halogens added to double bonds. H2C=CH2 + Br2→H2CBr−CH2Br Halonium ions are intermediates. These reactions do not require catalysts...
48 KB (5,122 words) - 23:58, 18 July 2024
reaction) that involves the exchange of one halogen atom for another. It is an equilibrium reaction, but the reaction can be driven to completion by exploiting...
6 KB (639 words) - 15:57, 4 August 2024
Guerbet reaction Gutknecht pyrazine synthesis Hajos–Parrish–Eder–Sauer–Wiechert reaction Haller–Bauer reaction Haloform reaction Halogen addition reaction Halohydrin...
38 KB (3,429 words) - 09:24, 18 August 2024
The Prins reaction is an organic reaction consisting of an electrophilic addition of an aldehyde or ketone to an alkene or alkyne followed by capture...
9 KB (1,068 words) - 14:13, 9 December 2023
anti addition are used to characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction. The...
8 KB (546 words) - 15:38, 9 August 2024
Bromine (category Halogens)
produced. The reaction passes through a short-lived strongly electrophilic bromonium intermediate. This is an example of a halogen addition reaction. Bromine...
67 KB (7,693 words) - 20:33, 10 August 2024
Electrophile (section Addition of halogens)
occur between alkenes and electrophiles, often halogens as in halogen addition reactions. Common reactions include use of bromine water to titrate against...
19 KB (2,321 words) - 12:01, 2 March 2024
Markovnikov's rule (redirect from Markownikoff addition reaction)
Markovnikov's rule, such as free radical addition. Such reactions are said to be anti-Markovnikov, since the halogen adds to the less substituted carbon,...
9 KB (1,129 words) - 04:58, 22 February 2024
In organic chemistry, free-radical addition is an addition reaction which involves free radicals. Radical additions are known for a variety of unsaturated...
10 KB (893 words) - 21:11, 23 April 2024
oxidative addition step breaks the carbon-halogen bond where the palladium is now bound to both the halogen (X) as well as the R1 group. Oxidative addition proceeds...
34 KB (3,842 words) - 03:10, 9 August 2024
reaction, for example in the reaction of alkanes with halogens. In the first step, light or heat disintegrates the halogen-containing molecules producing...
66 KB (8,031 words) - 09:58, 12 July 2024
the Sandmeyer reaction is supported by the detection of biaryl byproducts. The substitution of the aromatic diazo group with a halogen or pseudohalogen...
16 KB (1,738 words) - 05:14, 17 August 2024
Ketone halogenation (category Halogenation reactions)
halogenation. The reaction may be carried out under either acidic or basic conditions in an aqueous medium with the corresponding elemental halogen. In this way...
7 KB (812 words) - 15:08, 25 October 2023
chemistry, metal–halogen exchange is a fundamental reaction that converts an organic halide into an organometallic product. The reaction commonly involves...
10 KB (1,200 words) - 17:34, 25 September 2023
Hydrohalogenation (redirect from Addition of HX to an alkene)
alkene in an anti-Markovnikov addition fashion. Regiochemistry follows from the reaction mechanism, which exhibits halogen attack on the least-hindered...
6 KB (788 words) - 07:43, 16 November 2023
alkyl, hydroxy, or halogen. More can be found on the substituted compounds page. While it is common to discuss substitution reactions in the context of...
12 KB (1,456 words) - 21:30, 14 April 2024
significantly corrosive. It is produced by the reaction of ethylene gas with bromine, in a classic halogen addition reaction: CH2=CH2 + Br2 → BrCH2–CH2Br Historically...
10 KB (687 words) - 15:19, 2 May 2024
anti diastereoselectivity in halogen addition reactions to alkenes. They correctly argued that if the initial reaction intermediate in bromination is...
9 KB (1,070 words) - 18:06, 5 May 2024
Grignard reagent (redirect from Reactions of Grignard reagents)
compounds are chemical compounds with the general formula R−Mg−X, where X is a halogen and R is an organic group, normally an alkyl or aryl. Two typical examples...
24 KB (2,664 words) - 03:57, 1 August 2024
The Stille reaction is a chemical reaction widely used in organic synthesis. The reaction involves the coupling of two organic groups, one of which is...
47 KB (5,491 words) - 13:23, 22 February 2024
Hydroxyl Groups by Halogens and Other Nucleophiles via Oxyphosphonium Intermediates". Replacement of Alcoholic Hydroxy Groups by Halogens and Other Nucleophiles...
15 KB (1,570 words) - 19:19, 12 August 2024
types of reactions to synthesize new compounds. Carbocations are formed in two major alkene addition reactions. In an HX addition reaction, the pi bond...
14 KB (1,828 words) - 17:06, 8 August 2024
Hydrazone iodination (category Olefination reactions)
radical mechanism. Reaction sequence starting from 1: halogen addition reaction to di-iodide intermediate 2 followed by elimination reaction with loss of Hydrogen...
6 KB (687 words) - 11:56, 12 April 2023
N-Butyllithium (section Halogen–lithium exchange)
fluorides: C4H9Li + RX → C4H9X + RLi (X = Br, I) This lithium–halogen exchange reaction is useful for preparation of several types of RLi compounds, particularly...
18 KB (1,856 words) - 04:22, 24 July 2024