An insertion reaction is a chemical reaction where one chemical entity (a molecule or molecular fragment) interposes itself into an existing bond of typically...
17 KB (1,867 words) - 15:30, 17 May 2024
insertion is a type of reaction wherein two ligands on a metal complex combine. It is a subset of reactions that very closely resembles the insertion...
19 KB (2,262 words) - 20:28, 22 July 2024
medicine, see ICD-10-PCS Insertion loss, in electronics Insertion reaction, a chemical reaction in which one chemical entity interposes itself into an...
951 bytes (147 words) - 18:52, 7 November 2023
Aryne (section Bond-insertion reactions of arynes)
total synthesis of taiwanins C. The first example of aryne σ-bond insertion reaction is the synthesis of melleine in 1973. If benzyne is 1,2-didehydrobenzene...
28 KB (3,128 words) - 04:03, 9 November 2024
≤ 2. Alkoxide ligands are often nucleophilic. They often undergo insertion reactions with unsaturated substrates such as carbon dioxide and isocyanates...
10 KB (907 words) - 14:05, 2 April 2024
V-C σ bond in trimesitylvanadium is so reactive that it undergoes insertion reaction of several molecules. Rozzoli et al. investigated the reactivity of...
14 KB (1,343 words) - 09:03, 13 July 2024
Carbene C−H insertion in organic chemistry concerns the insertion reaction of a carbene into a carbon–hydrogen bond. This organic reaction is of some importance...
4 KB (501 words) - 13:50, 15 April 2024
Ring expansion and contraction (redirect from Ring contraction reaction)
ring onto an outside group already appended to the ring (a migration/insertion), opening of a bicycle to a single larger ring, or coupling a ring closing...
15 KB (1,718 words) - 07:21, 28 October 2024
fac-isomer of [Ir(CO)2(CH3)I3]−. This oxidative addition reaction involves the formal insertion of the iridium(I) centre into the carbon-iodine bond of...
3 KB (377 words) - 19:26, 6 November 2024
reactions, polymerization reactions, insertion reactions, ring-opening reactions and ring-closing reactions. Organic reactions can also be classified by...
14 KB (1,182 words) - 20:28, 22 July 2024
Nierenstein reaction is an organic reaction describing the conversion of an acid chloride into a haloketone with diazomethane. It is an insertion reaction in that...
4 KB (335 words) - 22:31, 27 September 2024
Insertion element (also known as an IS, an insertion sequence element, or an IS element) is a short DNA sequence that acts as a simple transposable element...
5 KB (636 words) - 10:44, 31 October 2024
Larock indole synthesis (category Ring forming reactions)
The Larock indole synthesis is a heteroannulation reaction that uses palladium as a catalyst to synthesize indoles from an ortho-iodoaniline and a disubstituted...
10 KB (1,203 words) - 03:15, 2 September 2023
numerous insertion reactions of C=C bonds of 1-alkene molecules into the Zr–C bond in the ion: Many thousands of alkene insertion reactions occur at each...
17 KB (1,843 words) - 11:43, 22 September 2024
Intrauterine device (redirect from Insertion of intrauterine contraceptive device)
altogether. However, women can have daily spotting for several months after insertion, and it can take up to three months for there to be a 90% decrease in...
58 KB (6,327 words) - 07:24, 21 November 2024
Stannylene (section Insertion reaction)
alkyl halides, enones, dienes) in an oxidative addition (or insertion) fashion. The reaction between stannylene and 9,10-phenanthrolinedione produces an...
13 KB (1,329 words) - 05:06, 8 February 2024
Hydrophosphination (category Addition reactions)
other hydrofunctionalizations, the rate and regiochemistry of the insertion reaction is influenced by the catalyst. Catalysts take many forms, but most...
20 KB (2,002 words) - 20:15, 6 February 2024
Curtius rearrangement (redirect from Curtius reaction)
together, due to the absence of any nitrene insertion or addition byproducts observed or isolated in the reaction. Thermodynamic calculations also support...
16 KB (1,749 words) - 14:30, 26 September 2024
Regioselectivity (redirect from Regioselective reaction)
specific reactions such as addition to pi ligands. Selectivity also occurs in carbene insertions, for example in the Baeyer-Villiger reaction. In this...
4 KB (438 words) - 16:21, 5 October 2023
intermediate that is commonly proposed for carbonyl addition reactions. Carbene Insertion reaction Nef, J. U. (1892). "Ueber das zweiwerthige Kohlenstoffatom"...
3 KB (281 words) - 08:40, 19 June 2023
diazomethane insertion reaction dehydrohalogenation reaction with DMF Luche reduction to alcohol with sodium borohydride elimination reaction with Burgess...
13 KB (1,221 words) - 02:19, 16 May 2024
The Pauson–Khand (PK) reaction is a chemical reaction, described as a [2+2+1] cycloaddition. In it, an alkyne, an alkene, and carbon monoxide combine...
31 KB (2,916 words) - 14:14, 26 September 2024
radical SAM enzyme NifB has been recognized to catalyze a carbon insertion reaction, leading to formation of a Mo/homocitrate-free precursor of M-cluster...
55 KB (6,104 words) - 00:18, 16 September 2024
The polymerase chain reaction (PCR) is a method widely used to make millions to billions of copies of a specific DNA sample rapidly, allowing scientists...
89 KB (11,135 words) - 05:58, 8 November 2024
Organometallic chemistry (redirect from Organometallic reaction)
important reactions: associative and dissociative substitution oxidative addition and reductive elimination transmetalation migratory insertion β-hydride...
31 KB (3,157 words) - 20:03, 24 September 2024
Alkaline earth metal (section Compounds and reactions)
NaOH + 2H2O → Na[Be(OH)3] + H2 Reaction with alkyl halides Magnesium reacts with alkyl halides via an insertion reaction to generate Grignard reagents...
72 KB (7,287 words) - 13:53, 17 November 2024
Joseph M.; Brookhart, Maurice (2000). "Kinetic Studies of Migratory Insertion Reactions at the (1,3-Bis(diphenylphosphino)propane)Pd(II) Center and Their...
7 KB (731 words) - 16:39, 15 October 2023
Stille-carbonylative cross-coupling reaction, which introduces the carbonyl group via carbon monoxide insertion. Allylic, benzylic, and propargylic halides...
47 KB (5,491 words) - 13:23, 22 February 2024
The Bamford–Stevens reaction is a chemical reaction whereby treatment of tosylhydrazones with strong base gives alkenes. It is named for the British chemist...
14 KB (1,481 words) - 16:52, 26 October 2023