• An insertion reaction is a chemical reaction where one chemical entity (a molecule or molecular fragment) interposes itself into an existing bond of typically...
    17 KB (1,867 words) - 15:30, 17 May 2024
  • insertion is a type of reaction wherein two ligands on a metal complex combine. It is a subset of reactions that very closely resembles the insertion...
    19 KB (2,262 words) - 20:28, 22 July 2024
  • medicine, see ICD-10-PCS Insertion loss, in electronics Insertion reaction, a chemical reaction in which one chemical entity interposes itself into an...
    951 bytes (147 words) - 18:52, 7 November 2023
  • total synthesis of taiwanins C. The first example of aryne σ-bond insertion reaction is the synthesis of melleine in 1973. If benzyne is 1,2-didehydrobenzene...
    28 KB (3,128 words) - 04:03, 9 November 2024
  • Thumbnail for Transition metal alkoxide complex
    ≤ 2. Alkoxide ligands are often nucleophilic. They often undergo insertion reactions with unsaturated substrates such as carbon dioxide and isocyanates...
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  • Thumbnail for Trimesitylvanadium
    V-C σ bond in trimesitylvanadium is so reactive that it undergoes insertion reaction of several molecules. Rozzoli et al. investigated the reactivity of...
    14 KB (1,343 words) - 09:03, 13 July 2024
  • Thumbnail for Carbene C−H insertion
    Carbene C−H insertion in organic chemistry concerns the insertion reaction of a carbene into a carbon–hydrogen bond. This organic reaction is of some importance...
    4 KB (501 words) - 13:50, 15 April 2024
  • Thumbnail for Ring expansion and contraction
    ring onto an outside group already appended to the ring (a migration/insertion), opening of a bicycle to a single larger ring, or coupling a ring closing...
    15 KB (1,718 words) - 07:21, 28 October 2024
  • Thumbnail for Cativa process
    fac-isomer of [Ir(CO)2(CH3)I3]−. This oxidative addition reaction involves the formal insertion of the iridium(I) centre into the carbon-iodine bond of...
    3 KB (377 words) - 19:26, 6 November 2024
  • Thumbnail for Organic reaction
    reactions, polymerization reactions, insertion reactions, ring-opening reactions and ring-closing reactions. Organic reactions can also be classified by...
    14 KB (1,182 words) - 20:28, 22 July 2024
  • Nitrene (section Reactions)
    carbamate with potassium persulfate, gives an insertion reaction into the palladium to nitrogen bond of the reaction product of palladium(II) acetate with 2-phenylpyridine...
    11 KB (1,286 words) - 23:57, 31 May 2024
  • Thumbnail for Nierenstein reaction
    Nierenstein reaction is an organic reaction describing the conversion of an acid chloride into a haloketone with diazomethane. It is an insertion reaction in that...
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  • Thumbnail for Insertion sequence
    Insertion element (also known as an IS, an insertion sequence element, or an IS element) is a short DNA sequence that acts as a simple transposable element...
    5 KB (636 words) - 10:44, 31 October 2024
  • Larock indole synthesis (category Ring forming reactions)
    The Larock indole synthesis is a heteroannulation reaction that uses palladium as a catalyst to synthesize indoles from an ortho-iodoaniline and a disubstituted...
    10 KB (1,203 words) - 03:15, 2 September 2023
  • numerous insertion reactions of C=C bonds of 1-alkene molecules into the Zr–C bond in the ion: Many thousands of alkene insertion reactions occur at each...
    17 KB (1,843 words) - 11:43, 22 September 2024
  • Thumbnail for Intrauterine device
    altogether. However, women can have daily spotting for several months after insertion, and it can take up to three months for there to be a 90% decrease in...
    58 KB (6,327 words) - 07:24, 21 November 2024
  • Thumbnail for Stannylene
    alkyl halides, enones, dienes) in an oxidative addition (or insertion) fashion. The reaction between stannylene and 9,10-phenanthrolinedione produces an...
    13 KB (1,329 words) - 05:06, 8 February 2024
  • Hydrophosphination (category Addition reactions)
    other hydrofunctionalizations, the rate and regiochemistry of the insertion reaction is influenced by the catalyst. Catalysts take many forms, but most...
    20 KB (2,002 words) - 20:15, 6 February 2024
  • Thumbnail for Curtius rearrangement
    together, due to the absence of any nitrene insertion or addition byproducts observed or isolated in the reaction. Thermodynamic calculations also support...
    16 KB (1,749 words) - 14:30, 26 September 2024
  • Thumbnail for Regioselectivity
    specific reactions such as addition to pi ligands. Selectivity also occurs in carbene insertions, for example in the Baeyer-Villiger reaction. In this...
    4 KB (438 words) - 16:21, 5 October 2023
  • intermediate that is commonly proposed for carbonyl addition reactions. Carbene Insertion reaction Nef, J. U. (1892). "Ueber das zweiwerthige Kohlenstoffatom"...
    3 KB (281 words) - 08:40, 19 June 2023
  • Thumbnail for Azulene
    diazomethane insertion reaction dehydrohalogenation reaction with DMF Luche reduction to alcohol with sodium borohydride elimination reaction with Burgess...
    13 KB (1,221 words) - 02:19, 16 May 2024
  • Thumbnail for Pauson–Khand reaction
    The Pauson–Khand (PK) reaction is a chemical reaction, described as a [2+2+1] cycloaddition. In it, an alkyne, an alkene, and carbon monoxide combine...
    31 KB (2,916 words) - 14:14, 26 September 2024
  • radical SAM enzyme NifB has been recognized to catalyze a carbon insertion reaction, leading to formation of a Mo/homocitrate-free precursor of M-cluster...
    55 KB (6,104 words) - 00:18, 16 September 2024
  • Thumbnail for Polymerase chain reaction
    The polymerase chain reaction (PCR) is a method widely used to make millions to billions of copies of a specific DNA sample rapidly, allowing scientists...
    89 KB (11,135 words) - 05:58, 8 November 2024
  • Thumbnail for Organometallic chemistry
    important reactions: associative and dissociative substitution oxidative addition and reductive elimination transmetalation migratory insertion β-hydride...
    31 KB (3,157 words) - 20:03, 24 September 2024
  • Thumbnail for Alkaline earth metal
    NaOH + 2H2O → Na[Be(OH)3] + H2 Reaction with alkyl halides Magnesium reacts with alkyl halides via an insertion reaction to generate Grignard reagents...
    72 KB (7,287 words) - 13:53, 17 November 2024
  • Joseph M.; Brookhart, Maurice (2000). "Kinetic Studies of Migratory Insertion Reactions at the (1,3-Bis(diphenylphosphino)propane)Pd(II) Center and Their...
    7 KB (731 words) - 16:39, 15 October 2023
  • Stille-carbonylative cross-coupling reaction, which introduces the carbonyl group via carbon monoxide insertion. Allylic, benzylic, and propargylic halides...
    47 KB (5,491 words) - 13:23, 22 February 2024
  • Thumbnail for Bamford–Stevens reaction
    The Bamford–Stevens reaction is a chemical reaction whereby treatment of tosylhydrazones with strong base gives alkenes. It is named for the British chemist...
    14 KB (1,481 words) - 16:52, 26 October 2023