The Krische allylation involves the enantioselective iridium-catalyzed addition of an allyl group to an aldehyde or an alcohol, resulting in the formation...
19 KB (2,045 words) - 10:27, 26 September 2024
Allyl group (redirect from Allylation)
include carbonyl allylation with allylmetallic reagents, such as allyltrimethylsilane, or the iridium-catalyzed Krische allylation. Allylation can be effected...
13 KB (1,366 words) - 18:49, 21 June 2024
carbonyl allylations rely on preformed allylmetal reagents, the Krische allylation exploits allyl acetate for enantioselective carbonyl allylation. Selected...
10 KB (1,018 words) - 13:50, 29 August 2023
site-selective conversion of lower alcohols to higher alcohols. The Krische allylation exemplifies the latter class of C-C coupling. Application of these...
9 KB (884 words) - 05:57, 27 May 2024
Kostanecki acylation Kowalski ester homologation Krapcho decarboxylation Krische allylation Kröhnke aldehyde synthesis Kröhnke oxidation Kröhnke pyridine synthesis...
37 KB (3,419 words) - 11:08, 19 October 2024
Organoindium chemistry (redirect from Indium-mediated allylation)
synthesis (such as sialic acids), without using protecting groups. Krische allylation Organogallium Chemistry Organothallium Chemistry Shen, Zhi-Liang;...
9 KB (1,138 words) - 12:08, 30 July 2024
starting material lead to the observed stereoisomer. (12) Krische allylation Carbonyl allylation Gung, B. W. Org. React. 2004, 64, 1-112. doi:10.1002/0471264180...
8 KB (971 words) - 16:58, 24 June 2022
borrowing hydrogen-type enolate alkylations. As exemplified by the Krische allylation, dehydrogenation of alcohol reactants can be balanced by reduction...
14 KB (1,576 words) - 11:14, 26 September 2024
Liu, Peng; Krische, Michael J. (2019-10-04). "Inversion of Enantioselectivity in Allene Gas versus Allyl Acetate Reductive Aldehyde Allylation Guided by...
40 KB (4,305 words) - 04:10, 21 August 2024