Oxalyl chloride is an organic chemical compound with the formula Cl−C(=O)−C(=O)−Cl. This colorless, sharp-smelling liquid, the diacyl chloride of oxalic...

the liberated chloride, forming the acid anhydride and releasing regenerated molecule of DMF. Relative to thionyl chloride, oxalyl chloride is more expensive...

(m.p. 52.5 to 53.5 °C, 126.5 to 128.3 °F). It forms an acid chloride called oxalyl chloride. Transition metal oxalate complexes are numerous, e.g. the...

alcohol (−OH) is oxidized to an aldehyde (−CH=O) or ketone (>C=O) using oxalyl chloride, dimethyl sulfoxide (DMSO) and an organic base, such as triethylamine...

thionyl chloride could be used to make acid anhydrides and acyl chlorides from carboxylic acids and to make alkyl chlorides from alcohols. Oxalyl chloride Phosphorus...

chlorinating agents including oxalyl chloride and thionyl chloride. This compound undergoes the reactions common for acid chlorides. For example, it reacts...

the Ohio River. Carbonyl bromide Carbonyl fluoride Oxalyl chloride Thiophosgene Thionyl chloride Perfluoroisobutene Bis(trifluoromethyl) disulfide Merck...

biradical intermediate. It is an intermediate in a reaction (between oxalyl chloride and hydrogen peroxide in ethyl acetate, accumulating in solution at...

precautions. A laboratory-safe variation masks the phosgene as oxalyl chloride. Also, oxalyl chloride can be used to form acyl isocyanates from primary amides...

chlorides, it can be generated from the parent acid and standard chlorinating agents such as phosphorus pentachloride, thionyl chloride, and oxalyl chloride...

activator for the Pummerer rearrangement. It can be used in place of oxalyl chloride in the Swern oxidation, allowing temperatures up to −30 °C. With sodium...

can however be prepared from dimethyl sulfoxide by treatment with oxalyl chloride. Alkali metal thiosulfonates are the conjugate base of thiosulfuric...

vinylene carbonate, which is used in polymers and in organic synthesis. Oxalyl chloride is produced commercially from ethylene carbonate. Photochlorination...

Paolo Strazzolini and others synthesized this compound by reacting oxalyl chloride (COCl)2 or the bromide (COBr)2 with a suspension of silver oxalate...

encountered synthetic routes are through the reaction of indole with oxalyl chloride followed by reaction with dimethylamine and reduction of the carbonyl...

decomposition of certain oxalates and certain chemoluminescent reactions of oxalyl chloride. 1,2-dioxetanedione α-acetolactone Paolo Strazzolini; Alberto Gambi;...

colorless liquid is prepared by reaction of sodium fluoride with oxalyl chloride. Oxalyl fluoride is being investigated for use in etching as a replacement...

synthesized by reacting 2-carbopentoxy-3,5,6-trichlorophenol with oxalyl chloride. When mixed with hydrogen peroxide in an organic solvent (diethyl phthalate...

heterocycles. Cyanuric chloride can also be used as an alternative to oxalyl chloride in the Swern oxidation. Thiazyl chloride trimer – structural analogue...

Malaysia Airlines A330-300 suffered structural damage due to leaking oxalyl chloride, a corrosive chemical substance that had been improperly labeled before...

photochlorination of ethylene carbonate. It has been used as precursor for oxalyl chloride. Tetrachloroethylene carbonate acts as a Lewis base and it forms a...

ISBN 0911910123 Allen, C. F. H.; Byers Jr., J. R.; Humphlett, W. J. (1963). "Oleoyl chloride". Organic Syntheses; Collected Volumes, vol. 4, p. 739.; Rutenberg, M....

thionyl chloride to the corresponding acyl chloride. The tendency towards DMCC formation depends on the chlorination reagent (thionyl chloride > oxalyl chloride...

prepared from tetramethylurea using a chlorinating agent such as oxalyl chloride, thionyl chloride or phosphorus oxychloride followed by salt exchange. TCFH...

iodine and triethylamine, oxidation by silver oxide, oxidation by oxalyl chloride, or even electrochemical oxidation on a platinum-titanium anode. Diazirines...

proceeds (in the variant with trifluoroacetic anhydride instead of oxalyl chloride) with a yield of 73%. Under UV irradiation, ketones react with vinylene...

isatins. In this case primary or secondary arylamines are condensed with oxalyl chloride to form a chlorooxalylanilide intermediate which can then cyclize in...

1968. It was obtained by reacting tetrahydroxy-1,4-benzoquinone with oxalyl chloride in tetrahydrofuran. It is a yellow solid that can be crystallized as...

iodosyl-based oxidants have been developed, e.g. IBX. Swern oxidation uses oxalyl chloride, dimethylsulfoxide, and an organic base, such as triethylamine. The...

procedure. First, 4-hydroxyindole is Friedel-Crafts-acylated with oxalyl chloride in position 3. The compound is further reacted with dimethylamine,...